Term
What is the colour of:
VO3- (+5) |
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Definition
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Term
What is the colour of:
VO2+ (+5) |
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Definition
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Term
What is the colour of:
VO2+ (+4) |
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Definition
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Term
What is the colour of:
V3+ (+3) |
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Definition
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Term
What is the colour of:
V 2+ (+2) |
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Definition
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Term
What is the colour of:
Cr2O7 2- (+6) |
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Definition
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Term
What is the colour of:
CrO42- (+6) |
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Definition
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|
Term
What is the colour of:
Cr 3+ |
|
Definition
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Term
What is the colour of:
Cr 2+ |
|
Definition
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|
Term
What is the colour of:
[Cr(H2O)6]3+ |
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Definition
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|
Term
What is the colour of:
[Cr(H2O)3(OH)3] |
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Definition
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Term
What is the colour of:
[Cr(H2O)2(OH)4]- |
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Definition
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|
Term
What is the colour of:
[Cr(NH3)6]3+ |
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Definition
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|
Term
What is the colour of:
MnO4- (+7) |
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Definition
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Term
What is the colour of:
Mn 2+ |
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Definition
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Term
What is the colour of:
Fe 2+ |
|
Definition
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Term
What is the colour of:
Fe 3+ |
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Definition
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Term
What is the colour of:
[Fe(H2O)3(OH)3] |
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Definition
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Term
What is the colour of:
[Fe(H2O)4(OH)2] |
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Definition
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Term
What is the colour of:
FeCO3 |
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Definition
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Term
What is the colour of:
[Co(H2O)6]2+ |
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Definition
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Term
What is the colour of:
CoCO3 |
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Definition
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|
Term
What is the colour of:
[Co(H2O)4(OH)2] |
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Definition
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|
Term
What is the colour of:
[Co(H2O)3(OH)3] |
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Definition
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|
Term
What is the colour of:
[Co(NH3)6]2+ |
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Definition
Pale yellow (precipitate) |
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Term
What is the colour of:
[Co(NH3)6]3+ |
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Definition
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Term
What is the colour of:
CoCl42- |
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Definition
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Term
What is the colour of:
Cu 2+ |
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Definition
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Term
What is the colour of:
Cu+ |
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Definition
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|
Term
What is the colour of:
Cu2O (+1) |
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Definition
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|
Term
What is the colour of:
[Cu(H2O)4(OH)2] |
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Definition
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|
Term
What is the colour of:
[Cu(NH3)4(OH)2] |
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Definition
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Term
What is the colour of:
CuCO3 |
|
Definition
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|
Term
What is the colour of:
CuCl42- |
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Definition
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|
Term
What is the colour of:
[Al(H2O)3(OH)3] |
|
Definition
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Term
What is the colour of:
[Al(OH)4]- |
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Definition
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|
Term
Lattice enthalpy of formation |
|
Definition
Enthalpy change for 1 mol of a molecule from its ions in the gaseous state |
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Term
|
Definition
Enthalpy change when 1 mol of gaseous ions is converted into aqueous ions (or converted to an aqueous solution) |
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|
Term
|
Definition
Only ionic bonds between atoms and ions are perfect spheres |
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Term
|
Definition
Enthalpy change for the formation of 1 mol of gaseous atoms from the element in their standard states |
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Term
Enthalpy of lattice dissociation |
|
Definition
Enthalpy change to separate 1 mol of an ionic lattice into its gaseous ions |
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Term
|
Definition
Enthalpy change when 1 mol of gaseous atoms become negatively charged ions |
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Term
Bond dissociation enthalpy as applied to chlorine |
|
Definition
Enthalpy change to break the bond in 1 mole of chlorine molecules to form 2 moles of gaseous chlorine atoms |
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Term
Why is the enthalpy of atomisation of chlorine is exactly half the bond dissociation enthalpy of chlorine? |
|
Definition
For atomisation, only 1 mole of chlorine atoms, not 2 moles as in bond enthalpy. |
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Term
Why is the lattice dissociation enthalpy of magnesium chloride is greater than that of calcium chloride? |
|
Definition
The magnesium ion is smaller so attraction to the chloride ion stronger |
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Term
Why is the lattice dissociation enthalpy of magnesium oxide is greater than that of magnesium chloride? |
|
Definition
The oxide ion has a greater charge so attracts the magnesium ion more strongly |
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|
Term
how can the quantities of enthalpy change (ΔH), entropy change (ΔS) and temperature (T) be used to predict whether a change is feasible. |
|
Definition
∆G = ∆H – T∆S If ∆G is less than or equal to 0 reaction is feasible |
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|
Term
Explain why the evaporation of water is spontaneous even though this change is endothermic. In your answer, refer to the change in the arrangement of water molecules and the entropy change. |
|
Definition
The molecules become more disordered when water changes from a liquid to a gas therefore the entropy change is positive T∆S>∆H ∆G<0 |
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Term
What would you observe when Silver ions react with Fluoride ions? |
|
Definition
No visible change (no ppt formed). |
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Term
What would you observe when Silver ions react with Chloride ions? |
|
Definition
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|
Term
What would you observe when Silver ions react with Bromide ions? |
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Definition
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|
Term
What would you observe when Silver ions react with iodide ions? |
|
Definition
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|
Term
Is Silver Chloride soluble in ammonia? If yes, what concentration of ammonia is it soluble in? |
|
Definition
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Term
Is Silver Bromide soluble in ammonia? If yes, what concentration of ammonia is it soluble in? |
|
Definition
Yes. Concentrated ammonia. |
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Term
Is Silver Iodide soluble in ammonia? If yes, what concentration of ammonia is it soluble in? |
|
Definition
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|
Term
What reagent would you add to test for Sulphate ions? And what would you observe? |
|
Definition
Barium Chloride. White ppt. |
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|
Term
How would you test for Carbonate ions? What reagents would you use? |
|
Definition
Acid is added to the solution containing carbonate ions. The Carbon Dioxide bubbles that are released is then passed through limewater. The limewater then turns from clear to cloudy. |
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|
Term
How would you test for a primary/secondary alcohol. What would you observe? |
|
Definition
Acidified Potassium Dichromate. Colour change from orange to green. |
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|
Term
How would you test for Aldehydes? What would you observe? |
|
Definition
Tollen's Reagent: Silver mirror formed. Heat with Fehling's Solution: Red ppt. |
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|
Term
How would you test for Ammonia? What would you observe? |
|
Definition
Damp litmus paper. Colour changes to blue (from red). |
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|
Term
How would you test for Carboxylic acids? What would you observe? |
|
Definition
Add Sodium Carbonate solution. Effervescence (of Carbon Dioxide). |
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|
Term
How would you test for Magnesium ions? What would you observe? |
|
Definition
Add Sodium Hydroxide. White ppt |
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|
Term
How would you test for Barium ions? What would you observe? |
|
Definition
Add Sulphuric acid. White ppt. |
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|
Term
How would you test for Ammonium ions? What would you observe? |
|
Definition
Add Sodium hydroxide (To produce ammonia). Then test for ammonia using damp litmus paper. |
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|
Term
What reagent would you add to a solution including halide ions, to distinguish which halide ion it is? |
|
Definition
Add dilute nitric acid, followed by silver nitrate solution. |
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Term
How would you test for Chloride ions (solid)? What would you observe? |
|
Definition
Add concentrated Sulphuric acid. Misty fumes. |
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Term
How would you test for Bromide ions (solid)? What would you observe? |
|
Definition
Add concentrated Sulphuric acid. Orange fumes and a choking gas. |
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Term
How would you test for Iodide ions (solid)? What would you observe? |
|
Definition
Add concentrated Sulphuric acid. Purple fumes, black solid, choking gas and smell of bad eggs. |
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Term
How would you test for Hydroxide ions? What would you observe? |
|
Definition
Add Magnesium chloride solution. White ppt. |
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|
Term
What can be added to sulphate ions to test for them? What would be observed? |
|
Definition
BaCl2 White precipitate formed |
|
|
Term
What can be used to test for ammonia? What would be observed? |
|
Definition
Damp litmus paper Colour change from red to blue |
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|
Term
What precipitate is formed and what is the colour of it when NaOH is added to Iron (II) chloride? |
|
Definition
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|
Term
How could a test to time the colour change of a solution be improved from looking at the solution in a flask? |
|
Definition
-Keep the solution at a constant temp because reaction rate is influenced by temp -Use a colorimeter to monitor colour change which gives a more accurate time of colour change |
|
|
Term
How could H2O2 be separated from Ba(NO3)2? |
|
Definition
By fractional distillation |
|
|
Term
Why would it be better to react sulphuric acid with BaO2 rather than nitric acid? |
|
Definition
BaSO4 is insoluble so easier to separate from H2O2 |
|
|
Term
Why can't infrared spectroscopy be used to identify H2O in a solution of H2O2? |
|
Definition
They both contain an OH group |
|
|
Term
Why does hydrogen peroxide decompose more quickly if it is kept in a clear glass bottle rather than a brown one? |
|
Definition
Decomposition is accelerated by light |
|
|
Term
Even if hydrogen peroxide is corrosive, why does a spillage not have long term effects on the environment? |
|
Definition
Decomposition products are harmless |
|
|
Term
What arrangement, reflux or distillation, should be used for the formation of ethanal and why? |
|
Definition
Distillation If reflux, further oxidation would occur and ethanoic acid would be formed |
|
|
Term
How would you ensure a reading from a pH meter is accurate? |
|
Definition
Collaborate with a solution of a known pH and plot a collaboration curve |
|
|
Term
How could the melting point of asprin be measured? |
|
Definition
Put sample in capillary tube and heat in melting point apparatus |
|
|
Term
Why should a pH meter be collaborated before use? |
|
Definition
pH meter may get less accurate over time |
|
|
Term
What substance is most likely to oxidise Iron (II) ions when Iron (II) sulphate is used as a weed killer? |
|
Definition
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|
Term
Suggest a value for the pH of a 0.100 mol dm-3 solution of Iron (II) sulphate? |
|
Definition
Anything in the range 4.0 - 6.9 |
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|
Term
What is a chemical hazard when using H2SO4 and what is a safety precaution? |
|
Definition
Acid is corrosive Use gloves or eye protection |
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|
Term
Why is it an advantage to add thiocyanate ions to the iron (III) sulphate solution before measuring percentage absorbance? |
|
Definition
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|
Term
Why is it necessary to maintain a constant temperature in an experiment to measure the equilibrium constant? |
|
Definition
Temperature affects the equilibrium constant |
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|
Term
What is one method for maintaining a constant temperature in an experiment? |
|
Definition
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|
Term
What is observed when 1-chloropropane and ethanoyl chloride are separately added to an aqueous solution of silver nitrate? |
|
Definition
1-chloropropane - no visible change ethanoyl chloride - white precipitate |
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Term
What equation links hydration enthalpy of Mg2+ ions and Cl- ions, lattice enthalpy and enthalpy of solution? |
|
Definition
∆Hsolution = ∆HL + Σ∆Hhyd Mg2+ ions + Σ∆Hhyd Cl– ions |
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Term
Using lattice enthalpy, enthalpy of solution of MgCl2 and hydration of Cl- ions, what is the equation to find the enthalpy of hydration of Mg2+ ions? |
|
Definition
Σ∆Hhyd Mg2+ ions = ∆Hsolution - ∆HL + Σ∆Hhyd Cl– ions |
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|
Term
What is the equation used to calculate standard entropy change? |
|
Definition
∆S = ES Products - ES reactants |
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|
Term
What is the equation to calculate Gibbs free energy? |
|
Definition
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|
Term
What is the overall reaction for the Contact Process that is catalysed by Vanadium oxide? |
|
Definition
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|
Term
What are the two reactions for the Contact Process that is catalysed by Vanadium oxide? |
|
Definition
V2O5 + SO2 → V2O4 + SO3 V2O4 + ½O2 → V2O5 |
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|
Term
What two equations show how the autocatalyst is involved in the oxidation of C2O42– ions by MnO4– ions? |
|
Definition
4Mn2+ + MnO4– + 8H+ → 5Mn3+ + 4H2O 2Mn3+ + C2O42– → 2Mn2+ + 2CO2 |
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|
Term
Reacton for Sodium with Oxygen |
|
Definition
|
|
Term
Reaction for Magnesium with Oxygen |
|
Definition
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|
Term
Reaction for Aluminium with Oxygen |
|
Definition
4Al(s) + 3O2 --> 2Al2O3(s) |
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|
Term
Reaction for Silicon with Oxygen |
|
Definition
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|
Term
Reaction for Phosphorus with Oxygen |
|
Definition
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|
Term
Reaction for Sulfur with Oxygen |
|
Definition
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|
Term
Reaction for Sodium Oxide with water. |
|
Definition
Na2O(s) + H2O --> 2NaOH(aq) |
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|
Term
Reaction for Magnesium Oxide with water. |
|
Definition
MgO(s) + H2O --> Mg(OH)2(s) --> Mg(OH)2 (aq) |
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|
Term
Reaction for Phosphorus Oxide with water. |
|
Definition
P4O10 + 6H2O --> 4H3PO4(aq) |
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|
Term
Reaction for Sulfur Dioxide with water |
|
Definition
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|
Term
Reaction for Sulfur Trioxide with water |
|
Definition
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|
Term
What would be observed when Sodium burns in oxygen? |
|
Definition
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|
Term
What would be observed when Magnesium burns in oxygen? |
|
Definition
white flame / white light solid / powder / smoke / ash / white fumes |
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|
Term
What would be observed when Aluminium burns in oxygen? |
|
Definition
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|
Term
What would be observed when Silicon burns in oxygen? |
|
Definition
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|
Term
What would be observed when Phosphorus burns in oxygen? |
|
Definition
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|
Term
What would be observed when Sulphur burns in oxygen? |
|
Definition
blue flame fumes or misty or pungent/choking/smelly gas |
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|
Term
What is the equation for the reaction that takes place when Sodium burns in oxygen? |
|
Definition
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|
Term
What is the equation for the reaction that takes place when Magnesium burns in oxygen? |
|
Definition
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|
Term
What is the equation for the reaction that takes place when Aluminium burns in oxygen? |
|
Definition
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|
Term
What is the equation for the reaction that takes place when Silicon burns in oxygen? |
|
Definition
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|
Term
What is the equation for the reaction that takes place when Phosphorus burns in oxygen? |
|
Definition
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|
Term
What is the equation for the reaction that takes place when Sulphur burns in oxygen? |
|
Definition
|
|
Term
What is the bonding in Sodium oxide? |
|
Definition
|
|
Term
What is the bonding in Magnesium oxide? |
|
Definition
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|
Term
What is the bonding in Aluminium oxide? |
|
Definition
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|
Term
What is the bonding in Silicon oxide? |
|
Definition
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|
Term
What is the bonding in Phosphorus oxide? |
|
Definition
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|
Term
What is the bonding in Sulphur dioxide? |
|
Definition
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|
Term
What are the properties of Sodium? |
|
Definition
Soft, silver, shiny Conducts electricity |
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|
Term
What are the properties of Magnesium? |
|
Definition
Soft, silver, shiny Conducts electricity |
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|
Term
What are the properties of Aluminium? |
|
Definition
Easily malleable, silver, shiny Conducts electricity |
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|
Term
What are the properties of Silicon? |
|
Definition
Hard, grey-blue solid Partial conductor of electricity (check this) |
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|
Term
What are the properties of Phosphorus? |
|
Definition
Red or white solid, low melting and boiling point Doesn't conduct electricity |
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|
Term
What are the properties of Sulphur? |
|
Definition
Yellow solid, low melting and boiling point Doesn't conduct electricity |
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|
Term
What are the properties of Chlorine? |
|
Definition
Green gas, low melting and boiling point Doesn't conduct electricity |
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|
Term
What are the properties of Argon? |
|
Definition
Colourless, odourless gas Unreactive |
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|
Term
What are the observations when Sodium reacts with water? |
|
Definition
Violent reaction Hydrogen released |
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|
Term
What are the observations when Magnesium reacts with water? |
|
Definition
Slow reaction Hydrogen released |
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|
Term
What are the observations when Magnesium reacts with steam? |
|
Definition
Fast reaction Hydrogen released |
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|
Term
What are the observations when Chlorine reacts with water? |
|
Definition
Chlorine dissolves Hydrochloric acid formed Chloric acid formed |
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|
Term
What is the equation for the reaction of Sodium with water? |
|
Definition
2Na(s) + 2H2O(l) -> 2NaOH(aq) + H2(g) |
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|
Term
What is the equation for the reaction of magnesium with water? |
|
Definition
Mg(s) + 2H2O(l) -> Mg(OH)2(aq) + H2(g) |
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|
Term
What is the equation for the reaction of magnesium with steam? |
|
Definition
Mg(s) + H2O(g) -> MgO(s) + H2(g) |
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|
Term
What is the equation for the reaction of Chlorine with water? |
|
Definition
Cl2(aq) + H2O(l) <=> HClO(aq) + HCl(aq) |
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|
Term
What are the properties of sodium oxide? |
|
Definition
White High melting point (1548K) |
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|
Term
What are the properties of the magnesium oxide? |
|
Definition
White High melting point (3125K) |
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|
Term
What are the properties of the Aluminium oxide? |
|
Definition
White High melting point (2345K) |
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|
Term
What are the properties of the Silicon oxide? |
|
Definition
White High melting point (1883K) |
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|
Term
What are the properties of the Phosphorus oxide? |
|
Definition
|
|
Term
What are the properties of the Sulphur oxide? |
|
Definition
Low melting point (200 for SO2, 290K for SO3) |
|
|
Term
What is the structure of the sodium oxide? |
|
Definition
|
|
Term
What is the structure of the magnesium oxide? |
|
Definition
|
|
Term
What is the structure of the aluminium oxide? |
|
Definition
|
|
Term
What is the structure of the silicon oxide? |
|
Definition
Giant covalent / Macromolecular |
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|
Term
What is the structure of the phosphorus oxide? |
|
Definition
|
|
Term
What is the structure of the sulphur oxide? |
|
Definition
|
|
Term
What is observed when the sodium oxide is reacted with water? |
|
Definition
Strongly alkaline solution formed pH 13-14 |
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|
Term
What is observed when the magnesium oxide is reacted with water? |
|
Definition
Weakly alkaline solution formed pH 10 |
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|
Term
What is observed when the aluminium oxide is reacted with water? |
|
Definition
|
|
Term
What is observed when the silicon oxide is reacted with water? |
|
Definition
|
|
Term
What is observed when the phosphorus oxide is reacted with water? |
|
Definition
Strongly acidic solution produced pH 0-1 |
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|
Term
What is observed when sulphur dioxide is reacted with water? |
|
Definition
Acidic solution produced pH 2-3 |
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|
Term
What is observed when sulphur trioxide is reacted with water? |
|
Definition
White foggy droplets of acid form pH 0-1 |
|
|
Term
What is the equation for reaction of water with the sodium oxide? |
|
Definition
|
|
Term
What is the equation/s for reaction of water with the magnesium oxide? |
|
Definition
MgO + H2O -> Mg(OH)2
Mg(OH)2 -> Mg2+ + 2OH- |
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|
Term
What is the equation for reaction of water with the Aluminium oxide? |
|
Definition
|
|
Term
What is the equation for reaction of water with the silicon oxide? |
|
Definition
|
|
Term
What is the equation for reaction of water with the phosphorus oxide? |
|
Definition
|
|
Term
What is the equation/s for reaction of water with sulphur dioxide? |
|
Definition
SO2 + H2O -> H2SO3 H2SO3 -> H+ + HSO3- |
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|
Term
What is the equation/s for reaction of water with sulphur trioxide? |
|
Definition
SO3 + H2O -> H2SO4 H2SO4 -> H+ + HSO4- |
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|
Term
What is the equation for the reaction that occurs when sodium oxide reacts with hydrochloric acid? |
|
Definition
Na2O + 2HCl -> 2NaCl + H2O |
|
|
Term
What is the equation for the reaction that occurs when magnesium oxide reacts with sulphuric acid? |
|
Definition
MgO + H2SO4 -> MgSO4 + H2O |
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|
Term
What is the equation for the reaction that occurs when aluminium oxide reacts with sulphuric acid? |
|
Definition
Al2O3 + 3H2SO4 -> Al2(SO4)3 + 3H2O |
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|
Term
What is the equation for the reaction that occurs when aluminium oxide reacts with hot, concentrated sodium hydroxide (and water)? |
|
Definition
Al2O3 + 2NaOH + 3H2O -> 2NaAl(OH)4 |
|
|
Term
What is the equation for the reaction that occurs when aluminium oxide reacts with hydrochloric acid? |
|
Definition
Al2O3 + 6H+ -> 2Al3+ + 3H2O |
|
|
Term
What is the equation for the reaction that occurs when aluminium oxide reacts with sodium hydroxide? |
|
Definition
Al2O3 + 2OH– + 3H2O -> 2Al(OH)4– |
|
|
Term
What is the equation for the reaction that occurs when silicon oxide reacts with hot, concentrated sodium hydroxide? |
|
Definition
SiO2 + 2NaOH -> Na2SiO3 + H20 |
|
|
Term
What is the equation for the reaction that occurs when phosphorus oxide reacts with hot, concentrated sodium hydroxide? |
|
Definition
12NaOH + P4O10 -> 4Na3PO4 + 6H2O |
|
|
Term
What is the equation/s for the reaction that occurs when sulphur dioxide reacts with sodium hydroxide? |
|
Definition
SO2 + NaOH -> NaHSO3 NaHSO3 + NaOH -> Na2SO3 + H2O |
|
|
Term
What can be added to sulphate ions to test for them? What would be observed? |
|
Definition
BaCl2 White precipitate formed |
|
|
Term
What can be used to test for ammonia? What would be observed? |
|
Definition
Damp litmus paper Colour change from red to blue |
|
|
Term
What precipitate is formed and what is the colour of it when NaOH is added to Iron (II) chloride? |
|
Definition
|
|
Term
How could a test to time the colour change of a solution be improved from looking at the solution in a flask? |
|
Definition
-Keep the solution at a constant temp because reaction rate is influenced by temp -Use a colorimeter to monitor colour change which gives a more accurate time of colour change |
|
|
Term
How could H2O2 be separated from Ba(NO3)2? |
|
Definition
By fractional distillation |
|
|
Term
Why would it be better to react sulphuric acid with BaO2 rather than nitric acid? |
|
Definition
BaSO4 is insoluble so easier to separate from H2O2 |
|
|
Term
Why can't infrared spectroscopy be used to identify H2O in a solution of H2O2? |
|
Definition
They both contain an OH group |
|
|
Term
Why does hydrogen peroxide decompose more quickly if it is kept in a clear glass bottle rather than a brown one? |
|
Definition
Decomposition is accelerated by light |
|
|
Term
Even if hydrogen peroxide is corrosive, why does a spillage not have long term effects on the environment? |
|
Definition
Decomposition products are harmless |
|
|
Term
What arrangement, reflux or distillation, should be used for the formation of ethanal and why? |
|
Definition
Distillation If reflux, further oxidation would occur and ethanoic acid would be formed |
|
|
Term
How would you ensure a reading from a pH meter is accurate? |
|
Definition
Collaborate with a solution of a known pH and plot a collaboration curve |
|
|
Term
How could the melting point of asprin be measured? |
|
Definition
Put sample in capillary tube and heat in melting point apparatus |
|
|
Term
Why should a pH meter be collaborated before use? |
|
Definition
pH meter may get less accurate over time |
|
|
Term
What substance is most likely to oxidise Iron (II) ions when Iron (II) sulphate is used as a weed killer? |
|
Definition
|
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Term
Suggest a value for the pH of a 0.100 mol dm-3 solution of Iron (II) sulphate? |
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Definition
Anything in the range 4.0 - 6.9 |
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Term
What is a chemical hazard when using H2SO4 and what is a safety precaution? |
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Definition
Acid is corrosive Use gloves or eye protection |
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Term
Why is it an advantage to add thiocyanate ions to the iron (III) sulphate solution before measuring percentage absorbance? |
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Definition
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Term
Why is it necessary to maintain a constant temperature in an experiment to measure the equilibrium constant? |
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Definition
Temperature affects the equilibrium constant |
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Term
What is one method for maintaining a constant temperature in an experiment? |
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Definition
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Term
What is observed when 1-chloropropane and ethanoyl chloride are separately added to an aqueous solution of silver nitrate? |
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Definition
1-chloropropane - no visible change ethanoyl chloride - white precipitate |
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