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Equilibrium
Chem B
24
Chemistry
Undergraduate 2
10/01/2008

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Term
Heat of Fusion (enthalpy of Fusion)
Definition
The heat needed for the melting of a solid.

Latent heat of fusion=(Heat supplied for melting of whole amount of Iodine taken)/(amount of Iodine taken)
Term
Calculating Delta fus or Delta vap
Definition
AMTg(1mole/molecular wieght)(Heat of Fusion or Vap/1)=Ans Kj
Term
Calculating g's of Liquid from g's of solid and heat of fusion and vap
Definition
Step 1: G's sold(1 mole/Molecular wieght)(Heat of Fusion/1Mole)=Heat in Kj (absolute)
Step 2: Heat Kj(1 mole/Heat of vap)(Molecular weight/1 mole=Grams Liquid
Term
Antilogarithms(antiln)
Definition
e^x
Term
Relating vapor pressure and temperature changes (Clausius-Clapeyron Equation)
Definition
P1/P2=DeltH(vap)/R(gas Constant-8.31 J/K*Mol)(1/T1-1/T2)
Term
Henry's law
Definition
Solubility of a gas is directly proportional to the partial pressure of the gas above the solution.

S=KhP (s=Solubility (mass solute/volume solvent), Kh=Henry's constant for the gas, P=Partial Pressure)
Term
Mass % of solute
Definition
the percentage by mass of solute contained in a solution.

Mass Percentage of soute=mass solute/mass solution*100
Term
Molality (molar concentration)
Definition
The moles of solute dissolved in one liter or 1 Kg of solution

Moles Solute/Kg of solution=molality in moles
Term
Mole Fraction - Molar Fraction
Definition
a unit of concentration, defined to be equal to the number of moles of a component divided by the total number of moles of a solution.
Term
Electromagnetic Radiation
Definition
A form of energy that has two basic characteristics: Wavelength and Frequency
Term
Wavelength
Definition
The distance between two adjacent peaks of a wave. Units of distance.
Term
Frequency
Definition
The number of wavelenghts of a wave of energy that passa point per unit time. Measured in "per second" or hertz.
Term
The electromagnetic spectrum
Definition
consists of a range of frequencies or wavelenght of electromagnetic radiation
Term
Solute
Definition
THhe component of a solution that is in the smaller amount (Unless gas or solid in liquid)
Term
Solvent
Definition
Greater amount in solution
Term
Colligative properties
Definition
Properties of a solution that depend on the concentration of solute molecules or ions in a solution, not on the chemical identity of a solution.
Term
Soluble in water
Definition
1. All salts containing Group 1A(Li, Na, K, Rb, Cs) and Ammonium Cations (NH4)
2. All salts containing nitrate (NO3), acetate (CH3CO2) and pechlorate (ClO4) anions
3. All salts containing Halide IOns (Cl, Br, I) except those of Cu, Sr, Ba, Pb
4. All salts containing sulfate (SO4) anions except those of Ca, Sr, Ba, Pb.
Term
Insoluble in Water
Definition
All salts containing hydroxide anion )OH) except those of group 1a, and Sr and Ba.
2. All salts containing sulfide anions (S) except those of group 1A, Group IIA, and ammonium cations.
3. All salts containing carbonate (CO3) Phosphate (PO4), arsenate (AsO4), chromate (CrO4), and iodate (IO3) anions except those of group 1A and ammonium.
Term
Temperature and solubility
Definition
Gas-as temp increases, solubility of gases decrease
Liquids-in general, as temp increase, sol increases----Many exeptions.
Term
Molarity
Definition
Moles solute/liters solution
Term
Equilibrium constant(Keq)
Definition
Keq=C^c*D^d/A^a*B^b (Big letters in Moles/Liter)

This is assuming reaction aA+bB<->cC+dD
Term
Ideal gas law and equilibrium constant
Definition
Kp=Ke(RT)deltan (change in the number of moles=moles of product-moles of reactant
Term
Le Chatliers principle
Definition
When a system in chemical equilibrium is disturbed by a change in temp, pres, ot concentration, the system shifts in a way that tends to counteract the change.

If reactants or pooducts are added or subtracted, then the equilibrium willl shift to satisfy K
Term
Law of mass action
Definition
Reaction will always want to be at equilibrium
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