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Environmental Chemistry
Topic E: IB Chem SL
11
Chemistry
12th Grade
04/20/2011

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Cards

Term
What are the main air pollutants?
Definition
Carbon monoxide (CO)
Oxides of nitrogen
Oxides of sulfur
Particulates
Volatile organic compounds (VOCs)
Term
Main sources of carbon monoxide
Definition
Incomplete oxidation of methane (CH4 + 1.5O2 --> CO + 2H2O)

Incomplete combustion of fossil fuels (C8H18 + 8.5O2 --> 8CO + 9H2O)
Term
Main sources of oxides of nitrogen
Definition
electrical storms;
biological processes.

high temperatures inside internal combustion engines (N2 + O2 --> 2NO)
Term
Main sources of oxides of sulfur
Definition
oxidation of H2S produced by volcanoes;
decay of organic matter;
SO2 can be oxidized in air to form SO3.

combustion of sulfur-containing coal;
smelting of sulfide ores
(S + O2 --> SO2)
Term
Main sources of particulates
Definition
soot;
ash;
dust;
abestos;
sand;
smoke;
pollen;
bacterial and fungal spores.

burning of fossil fuels (mainly coal and diesel).
Term
Main sources of volatile organic compounds (VOCs)
Definition
plants (ex. rice)
--> emit unsaturated hydrocarbons called terpenes.

unburned/partially burned gasoline;
other fuels/solvents.
Term
Methods of air pollution reduction.
Definition
Thermal exhaust reactor
Lean burn engines
Catalytic converter
Sulfur dioxide
Electrostatic precipitation
Term
Thermal exhaust reactor
Definition
Exhaust from car engine and its heat reacts with air

carbon monoxide --> carbon dioxide
unburned hydrocarbons combust

2CO(g) + O2(g) --> 2CO2(g)
Term
Lean burn engines
Definition
Adjust carburettor to alter air:fuel ratio.
Higher ratio, less CO emitted.
--> more heat, more NOx produced.
Term
Catalytic converter
Definition
Hot exhaust gas pass through platinum, rhodium, or palladium.
--> oxidize CO
--> oxidize VOCs
--> catalyze reaction between CO and NO
2CO(g) + 2NO(g) --> 2CO2(g) + N2(g)
Term
What is acid deposition; outline its origins.
Definition
Process where acidic particles, gases, and precipitation leave the atmosphere.
Acid rain = less than pH 5.6


Rainwater is already acidic with dissolved CO2.
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