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Entropy and Free Energy
vocab and main ideas -18.4
17
Chemistry
11th Grade
05/15/2009

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Term
the energy available to do work
Definition
Free energy
Term
a reaction that favors the formation of products at the specified conditions
Definition
spontanteous reaction
Term
what do spontaneous reactions produce and release at equilibrium?
Definition
produce substantial amounts of products and release free energy
Term
what does spontaneity depend on?
Definition
spontaneity depends on enthalpy and entropy changes
Term
(S) a measure of the disorder of a system; systems tend to go from a state of order (low entropy) to a state of maximum disorder (high entropy)
Definition
entropy
Term
it is a natural tendency of systems to move in the direction of maximum chaos or disorder
Definition
law of disorder
Term
what does an increase in entropy favor?
Definition
the spontaneous chemical reaction
Term
what does a decrease in entropy favor?
Definition
the nonspontaneous reaction
Term
what determines whether a reaction is spontaneous (in terms of entropy changes)
Definition
the size and direction of enthalpy changes and entropy changes together
Term
(delta G) the maximum amount of energy that can be coupled to another process to do useful work
Definition
Gibbs free-energy change
Term
when is the delta G value negative?
Definition
in spontanteous processes (system loses free energy)
Term
is free energy always efficently used?
Definition
no
Term
spontaneous reactions occur....
Definition
naturally
Term
which has a larger amount of product...a spontaneous or nonspontaneous reaction?
Definition
spontaneous
Term
lack of enthalpy leads to...
Definition
a higher entropy
Term
an increase in entropy...
Definition
favors spontaneous reactions
Term
a decrease in entropy leads to...
Definition
nonspontaneous reactions
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