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ECHEM Chapter 10
Terms, Def and Theory
27
Chemistry
Undergraduate 4
12/08/2013

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Term
Define Aerosol
Definition
Colloidal sized atmospheric particle
Term
Describe colloide
Definition
1 to 1x10-3 μm in diameter
Term
How are aerosols characterized?
Definition
Characterized by the way they are formed.
Term
What are the 7 types of atmospheric particles?
Definition
1) aerosol
2) Condensation aerosol
3) dispersion aerosol
4) Fog
5) Haze
6) Mists
7) Smoke
Term
Define Condensation aerosol
Definition
Formed by condensation of vapors or reaction of gases
Term
Define dispersion aerosol
Definition
Formed by grinding of solids, atomization of liquids or dispersion of dusts.
Term
Define Fog
Definition
Term denoting high level of water droplets
Term
Define Haze
Definition
Denotes decreased visibility due to the presence of particles
Term
Define Mists
Definition
Liquid particles
Term
Define Smoke
Definition
Particles formed by incomplete combustion of fuel
Term
What are the effects of particles?
Definition
1) Reduced visibility
2) Provide an active surface for chemical reactions
3) Effect weather and air pollution
4) Nucleation body
5) Respiratory Irritation
Term
What are the particle restrictions set in place by the 1978 clean air act?
Definition
Restriction on particulate matter <10μm or <2.5μm in diameter(more recent)
Term
What detrimental health effect do particle of <10μm or <2.5μm in diameter have?
Definition
Particulate build up in cilia making it harder to keep lungs clean.
Term

Define radioactive particles

(with respect to atmospheric particles)

Definition
Daughter products of Radon
Term
What are the problems in connections with radon?
Definition
Radioactivity originating from uranium mine tailings that have been used in some areas as back fill, soil conditioner and a base for building foundations.
Term
What are the decay products of the 2 isotopes of radon and what is there half life.
Definition

222Rn->218Po+42He2+ (t1/2=3.8days)

220Rn->216Po+42He2+ (t1/2=5.4secs)

Term
Describe Polonium (Po)
Definition
Non-gaseous particle that will adhere to an atmospheric particle. This can then get stuck in your lungs a decay 7 more times to lead.
Term
Describe 85Kr
Definition

-Radioactive noble gas

-t1/2=10.3yrs

-non-regulated

-released in nuclear reactors and fuel reprocessing

-biota cannot concentrate this chemically unreactive element

Term
What are the 5 ways to control particulate emission
Definition
1)Sedimentation chamber
2)Inertial mechanism
3)Fabric filters
4)Venturi scrubbers
5)Electrostatic precipitators
Term
Describe sedimentation chamber
Definition

-Low collection efficiency, particularly for small particles

-Particles removed from stream of gas by gravitational settling over time

-Spontaneous coagulation of particles overtime, thus making them larger, enhances gravitational settling

Term
Describe inertial mechanisms
Definition
-good for heavy particles
-particle of high inertial mass cannot turn corners rapidly and collide w/ container walls and are removed when they fall to the bottom of the container. Cleaner air then leaves through another port.
Term
Describe Fabric filters (bag house)
Definition
1) Gas flows into bag house and particulate in the gas clogs the fabric walls. Walls bow out.
2)Pressure reversed w/ vacuum, bowing wall in.
3)Alternate positive and negative pressure flaps particulate free from bag
4)Cleaner gas passes through fabric of bag
Term
Describe venturi scrubbers
Definition
-any aerosol that is water soluble is effectively scrubbed
1)Pass gas through a device with a converging section(throat)
2)Inject liquid at right angle into throat, which breaks into droplets
3)Droplets scavenge particles in gas(warm section)
4)Stream enters reduced pressure area leading to expanding and therefore cooling.
5)Cooling leads to condensation, and particles are collected in condensed liquid
Term
Describe electrostatic precipitator
Definition
Effective for ionizable and polar particles
1) pass gas through electric field
2)particles obtain charge from negative discharge electrode
3)Charged particles are attracted to ground(positive) walls and later removed
Term
What two vapor forms of mercury might be found in the atmosphere?
Definition
Hg(s) and (CH3)2Hg
Term
Why are aerosols in the 0.1-1.0 micrometer size especially effective in scattering visible light?
Definition
particles have size similar to wavelength of visible light
Term
What are the five major classes of material making up the composition if atmospheric aerosol particles?
Definition
1)Metal oxides and glasses
2)carbonaceous material
3)dissolved ionic species
4)ionic solids
5)water
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