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matter is made of particles that are always in motion |
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-Expansion -Fluidity -Low density -Compressibility -Diffusion -Effusion -Indefinite volume -Indefinite shape |
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Least common state of matter |
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Definite Volume, Indefinite Shape |
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Takes on the shape of container |
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intermolecular forces pull particles together, forming smallest surface; examples – raindrop, paperclip floating |
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when a liquid is attracted to a solid |
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liquid to gas (energy added) at the boiling point, liquid to gas throughout – bubbles, (intermolecular forces broken) |
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Crystalline (1 of 2 types of solid) |
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geometric patterns, definite melting pt |
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Amorphous (2 of 2 types of solid) |
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random arrangement, melts over a range of temperatures |
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high density, incompressible, low rate of diffusion, and definite shape and volume |
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2 opposing changes at equal rates |
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equilibrium systems adjust to stress to attain a new equilibrium ex. Iodine bottle |
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Endothermic Changes of State (energy added) |
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melting, sublimation, vaporization |
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Exothermic Changes of State (energy removed) |
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freezing, deposition, condensation |
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Liquid --> solid (energy removed) |
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Gas --> solid (energy removed) |
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Gas --> liquid (energy removed) |
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Chart Labels Ti Tf Plateau Bp Mp Fp of water |
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-Ti = initial temperature (beginning) -Tf= final temperature (ending) -Plateau = flat part; indicates a change of state. -Bp = boiling point; water – 100 degrees C -Mp = melting point; water – 0 degrees C; pdb 53 degrees C -Fp of water – 0 degrees C; Mp = fp |
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Molar Heat of Vaporization |
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Definition
Energy required to change one mole of liquid to gas at b.p. (energy unit = joule) |
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Examples of Heat of Vaporization |
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Sweating/ air conditioners and refrigerators use energy to change liquid to gas. |
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Energy needed to change 1 mole of solid to liquid at m.p. |
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Example of Heat of Fusion |
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Energy is used to change a solid into a liquid – example – ice in drink |
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where critical pressure meets critical temperature |
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where s.p. crosses liquid-gas line |
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where s.p. crosses solid-liquid line |
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only gas present above this temp |
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Phases that are relatively incompressible |
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Phases that diffuse rapidly |
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Has an indefinite shape and a definite volume |
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Has the most distance between particles |
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Para dichlorobenzene in our lab was an example |
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Dry ice and iodine are examples |
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2 than occur at the same temperature |
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