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how to tell if an element is atomic or molecular |
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Atomic = an element that does not exist in nature diatomically molecular = an element that is diatomic in nature (Br, I, N, Cl, H, O, F) |
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how to identify a molecular compound |
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has two or more covalently bonded nonmetals |
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HYDROGEN CARBONATE (BICARBONATE) |
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HYDROGEN SULFITE (BISULFITE) |
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HYDROGEN SULFATE (BISULFATE) |
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how to identify a OXYACID |
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contain hydrogen oxygen and some other nonmetal |
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how to identify hydrocarbon |
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compound containing only carbon and hydrogen |
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how to identify a functionalized hydrocarbon |
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contains on OH functional group |
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mols of substance / liters of soln |
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What are the postulates of John Daltons atomic theory of matter |
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1) all matter is composed of indivisible and indestructible atoms 2) an element is a type of matter composed of only one type of atom 3) a compound or molecule is a type of matter composed of two or more elements chemically combined in fixed proportions 4) A chemical reaction is where a substance is changed into a new substance |
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what are the three temp scales measured relative too |
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Fahrenheit - measured relative to salt water Celsius - measured relative to pure water Kelvin - absolute, measured relative to motion of atoms |
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formula for Celsius to kelvin |
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how to get to Fahrenheit from celcius |
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the law of conservation of matter |
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matter is neither created nor destroyed |
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the law of multiple proportions |
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elements can combine in more than one set of proportions, with each set of proportions corresponding to a diff compound |
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the law of definite proportions |
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all samples of a given compound have the same proportions of their constituent elements |
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what are cathode ray particles and who discovered them |
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electron streams, JJ Thompson |
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what is the definition of wavelength |
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the distance between any adjacent identical points on a wave |
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the first law of thermodynamics |
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says that the total energy in the universe is constant |
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energy is released in a chemical reaction when |
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energy is consumed in during a chemical reaction when |
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fuels always have what type of enthalpy |
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a negative enthalpy, ie negative delta H |
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fuels are endo or exothermic |
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standard state enthalpies are measured at what temp and pressure |
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vertical height of a wave or depth of a trough |
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the number of wave crests that pass a through a stationary point in a given period of time |
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equation to find frequency (V) |
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frequency (v) = speed of light (c)/ wavelength (lambda) |
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unit used to define frequency |
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what is the photoelectric effect |
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the observation that many metals emit electrons when light shines upon them |
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how to measure the energy of a photon |
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energy (E) = h(plancks constant)*v(frequency)/wavelength (lambda) |
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Heisenberg's uncertainty principle |
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the more accurately you know the position of an electron the less accurately you know the position and vice versa |
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principal quantum number (n) represents what |
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size and energy of the orbital (n can be 1-8) |
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angualar momentum quantum number (L)represents what |
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shape of the orbital (n-1) |
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magnetic quantum number (m sub L) represents what |
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orientation in space (-L through +L) |
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minimum energy required to completely remove an electron from a ground state atom In the gas phase |
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every orbital in a subshell must be singly occupied before any one orbital is doubly occupied, all singly occupied must have same spin |
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pauli exclusion principle |
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no two electrons in an atom can have the same four quantum numbers (must have opposite spin) |
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how to know if something will interact with magnet |
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full subshell = wont interact not full subshell = will interact |
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five basic shapes of VSEPR theory |
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linear bent trigonal planar trigonal pyramidal tetrahedral |
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trigonal planar bond angle |
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trigonal pyramidal bond angle |
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how to tell if a molecule is polar by looks |
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central atom has one or more lone pairs = polar |
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how to tell if a molecule is non polar by looks |
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central atom has no lone pairs and all of the outer atoms are identical = non polar |
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second way to tell if a molecule is polar by looks |
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central atom has no lone pairs and the outer atoms are not identical = polar |
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how to tell if something will have a resonance hybrid |
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central atom bonded to more than one oxygen with double or triple bonds it is a tipoff |
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what are the three postulates of kinetic molecular theory |
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1) the size of a particle is negligibly small 2) the avg kinetic energy of a particle is proportional to them temp in K 3) the collisions between particles and their containers are elastic |
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three types of intermolecular forces |
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dispersion (London forces) Dipole-Dipole forces Hydrogen Bonding |
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dispersion forces exist where |
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dipole-dipole forces exist where |
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hydrogen bonding forces exist where |
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in polar molecules where H atoms are bonded to FON, super dipole force |
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how to change from liquid to gas |
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increase heat or reduce pressure |
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gasses are least ideal when |
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high pressure and low temp |
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a molecules weight relates to dispersion forces how |
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the heavier the molecule the higher the dispersion forces |
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how does boiling point relate to intermolecular forces |
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higher boiling point = stronger IMF |
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how do IMF relate to viscosity |
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high IMF = high viscosity |
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boiling occurs when the pressure of the vapor... |
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when the pressure of the vapor equals the pressure being exerted from surroundings |
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