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Chemistry Glencoe Ch. 4, 5, 6
Flashcards to help me study for my chemistry final in Proctor
86
Chemistry
10th Grade
12/08/2014

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Term
Democritus
Definition
-person that created the term, "atom"
-1st to propose matter was not infinitely divisible
believed atoms couldnt be created, destroyed, or further divided
-atoms solid, homogeneous, indestructible, vary in size and shape
Term
Dalton
Definition
-person that said atoms of element = identical, in chem. reaction, atoms are separated, combined, and rearranged
-atoms cant be created, divided, destroyed
-diff. atoms combine in simple whole-number ratios to form compounds
Term
Crookes
Definition
-person that accidentally discovered "cathode ray"
-studied typical tube used by researches studying relationship between mass and charge
-led to invention of television
Term
cathode
Definition
electrode connected to negative terminal of battery
Term
anode
Definition
electrode connected to positive terminal of battery
Term
cathode ray
Definition
ray of radiation originated from the cathode end of tube
Term
stream of charged particles
Definition
Scientists were convinced that cathode rays were actually a ______ ___ _______ ___________.
Term
Negative charge
Definition
particles of cathode rays carried a what charge?
Term
Thomson
Definition
-person that began series of cathode ray tube experiments to determine charge-to-mass ratio of charged particle
-concluded DALTON WAS WRONG
-identified the electron(first subatomic particle)
Term
Millikan
Definition
-person to determine charge of electron
Term
1/840
Definition
The mass of an electron is what fraction the mass of a hydrogen atom?
Term
Plum Pudding Model/Chocolate-Chip Cookie Dough Model

chocolate chips = electrons
dough=uniformly distributed positive charge
Definition
-consisted of spherically shaped atom composed of uniformly distributed positive charge within which the individual negatively charged electrons resided
Term
Rutherford
Definition
-person that studied how positively charged alpha particles interacted with solid matter
-see if alpha particles would be deflected as they passed through a thin of foil of gold
- calculated that atom consisted mostly of empty space through which electrons move, concluded there was a tiny, dense region, called the nucleus-centrally located within atom that contained all of an atom's positive charge and virtually all of its mass
- concluded nucleus contained positively charged particles (protons)
Term
Gold Foil Experiment
Definition
- narrow beam of alpha particles-aimed at thin sheet of gold foil, zinc sulfide coated screen surrounding gold foil produced flash of light whenever struck by alpha particle
- few of alpha particles were deflected at very large angles, several deflected straight back toward source
-because nucleus occupies such a small space and contains most of an atom's mass, it is incredibly dense
- electrons move rapidly through empty space
Term
10,000 times the diameter
Definition
An atom's diameter is ______ times the diameter of a nucleus
Term
Chadwick
Definition
showed nucleus contained another subatomic particle (neutral-neutron)
Term
Neutron
Definition
- has mass nearly equal to proton, carries no electrical charge
Term
Atoms
Definition
spherically shaped, electrons held within by their attraction to the positively charged nucleus
Term
neutral neutrons and positively charged protons, also contains all of atom's positive charge and more than 99.97% of its mass
Definition
The nucleus is composed of what?
Term
Quarks
Definition
Protons and neutrons are made up of particles known as what?
Term
Moseley
Definition
-person that discovered that the number of protons and electrons in an atom must be equal because all atoms are neutral.
- Once you know atomic #, you know # of protons and electrons
Term
Isotopes
Definition
atoms with same number of protons but different numbered of neutrons, differ in mass, same chemical behavior
Term
Mass Number
Definition
represents sum of number of protons and neutrons in nucleus
Term
Mass number - atomic number
Definition
How do you calculate the number of neutrons an atom has?
Term
1/1840
Definition
The mass of an electron is what fraction of a proton or neutron?
Term
carbon-12 atom
Definition
What chosen atomic standard do scientists use to measure mass of an atom?
Term
Atomic Mass Unit (AMU)
Definition
defined as 1/12 mass of carbon-12 atom
Term
Atomic Mass
Definition
the weighted average mass of the isotopes of that element
Term
Nuclear reactions
Definition
involve an atom of one element changing into an atom of another element
-change occurs in nucleus
Term
Radioactivity
Definition
some substances spontaneously emitted radiation in process
Term
Radiation
Definition
rays and particles emitted by radioactive material
Term
because nuclei are unstable
Definition
Why do radioactive atoms emit radiation?
Term
Radioactive Decay
Definition
-unstable nuclei lose energy by emitting radiation in a spontaneous process
- unstable atoms undergo this until they form stable nonradioactive atoms, often of different elements
Term
Alpha Radiation
Definition
negatively charged plate, made up of alpha particles, each containing two protons and two neutrons, thus has a 2+ charge
-opposite electrical charges attract
Term
Beta Radiation
Definition
-consists of fast moving electrons
- 1- charge
Term
Gamma Radiation
Definition
high-energy radiation that possess no mass, no electrical charge- gamma rays not deflected by electric or magnetic fields
Term
electromagnetic radiation
Definition
form of energy that exhibits wavelike behavior as it travels through space
Term
visible light, from the sun, microwaves, x-rays, waves that carry radio and television programs to your home
Definition
List examples of electromagnetic radiation.
Term
Wavelength
Definition
shortest distance between equivalent points on continuous wave
- measured from crest to crest, or from trough to trough
-expressed in m, cm, or nanometers
Term
Frequency
Definition
number of waves that pass a given point per second
-one hertz (Hz)
- SI unit of frequency = one wave per second
Term
Amplitude
Definition
the wave's height from the origin to a crest or from the origin to a trough
Term
same, differ
Definition
The speed of electromagnetic waves is the _____, but may _____ in wavelengths and frequencies.....inversely related, as one increases, the other decreases
Term
Electromagnetic spectrum
Definition
encompasses all forms of electromagnetic radiation, with only difference in types of radiation being their frequencies and wavelengths
Term
The Quantum Concept
Definition
states that different colors correspond to different frequencies and wavelengths
Term
Max Planck
Definition
- person that began searching for explanation as he studied light emitted from heated objectes
-started QUANTA
Term
Quantum
Definition
minimum amount of energy that can be gained or lost by an atom
- led scientists to believe that energy could be absorbed and emitted in continually varying quantities, with no minimum limit to the amount
Term
Planck's Constant E quantum
Definition
hv value of 6.626 x 10-36 J s, where J is the symbol for juole, the SI unit of energy. Looking at the equation, energy of radiation increases as the radiation's frequency, v, increases. Equation explains why violet light has greater energy than red light
Term
Photoelectric effect
Definition
Photoelectrons are emitted from a metal's surface when light of a certain frequency shines on the surface. Photoelectric cells in calculators and many other devices convert the energy of incident light into electrical energy.
Term
Photon
Definition
a particle of electromagnetic radiation with no mass that carries a quantum of energy
Term
Atomic emission spectrum
Definition

the set of frequencies of the electromagnetic waves emitted by atoms of the element, not a continuous range of colors

- each elements' is unique and can be used to determine if that element is part of an unknown compound

Term
Ground state
Definition
the lowest allowable energy state of an atom
Term
Excited state
Definition
when atom gains energy
Term
Bohr's model
Definition

- suggested single electron in hydrogen atom moves around nucleus in only certain allowed circular orbits

-smaller electron's orbit= lower atom's energy state/level

- assigned a quantum number, n to each orbit and even calculated orbit's radius

-ground state in n=1 orbit, when energy is added from outside source,electron moves to a higher-energy orbit (n=2), such transition raises atom to excited state

-electron can drop from higher-energy orbit to lower-energy orbit

Term
De Broglie equation
Definition
predicts that all moving particles have wave characteristics
Term
Heisenberg uncertainty principle
Definition
states that it is fundamentally impossible to know precisely both the velocity and position of a particle at the same time
Term
Schrodinger
Definition
-person that furthered wave-particle theory proposed be de Broglie, formed equation that treated hydrogen atom's electron as a wave
Term
Quantum mechanical model of the atom
Definition
atomic model in which electrons are treated as waves
Term
atomic orbital
Definition

a three-dimensional region around nucleus

-describes electron's probable location

Term
Principal quantum numbers
Definition

indicate relative sizes and energies of atomic orbitals

- as n increases, orbital becomes larger, electron spends more time farther from nucleus

-as atom's energy level increases, n specifies atom's major energy levels- principal energy levels

Term

shapes of atom's orbitals:

 

S= sphere

P= perpendicular

D= 5 orbitals

F= 7 orbitals

Definition
Energy sublevels are labeled s, p, d, or f according to what?
Term
Electron configuration
Definition
arrangement of electrons in an atom
Term
Aufbau Principle
Definition

states that each electron occupies the lowest energy orbital available

-your step in determining an element's ground-state electron configuration is learning the sequence of atomic orbitals from lowest energy to highest energy...

 

In order of increasing energy, sequence of energy sublevels within a principal energy level is s, p, d, f

Term
Pauli exclusion principle
Definition

states that a max of two electrons may occupy a single atomic orbital, but only if the electrons ave opposite spins

 

-arrow up represents electron spinning in one direction, arrow pointing down represents it spinning in opposite direction

Term
Hund's Rule
Definition
states that single electrons with the same spin must occupy each equal-energy orbital before additional electrons with opposite spins can occupy the same orbitals
Term
valence electrons
Definition
defined as electrons in the atom's outermost orbitals
Term
John Newlands
Definition
person that named "periodic relationship"
Term
Mendeleev
Definition
person that arranged according to atomic mass (wasnt correct though)
Term
Moseley
Definition
Who discovered to arrange the periodic table by protons?
Term
Metals
Definition
shiny, good conductors of heat and electricity, malleable, ductile
Term
Alkali and alkaline earth metals
Definition

chemically reactive...

 

Term
Alkali
Definition
Which is more reactive? alkali or alkaline earth metals?
Term
Lanthanide and Actinide
Definition
What are the two sets of inner transition metals?
Term
Nonmetals
Definition
generally gases or brittle, dull looking solids, poor conductors
Term
Bromine
Definition
Name the only nonmetal that's a liquid at room temperature
Term
Halogens
Definition
7A - highly reactive
Term
Noble gases
Definition
8A - extremely unreactive
Term
Metalloids
Definition
semimetals
Term

s-block: 1A, 2A

p-block: 3A-8A

d-block: transition metals and is largest of blocks

f-block: inner transition metals

Definition

Where on the periodic table are these located?

s-block?

p-block?

d-block?

f-block?

Term

Within periods - decrease in atomic radii moving left-to-right

Within groups- atomic radii increase as you move down, nuclear charge increases, and electrons added to higher principal energy levels

Definition
State the periodic trends for Atomic Radius
Term
Ion
Definition
atom or a bonded group of atoms that has a positive or negative charge
Term

Within periods:  positive ions decrease left-to-right

Within groups: down- higher principal energy levels

Definition
State the periodic trends for Ionic Radius
Term
Ionization energy
Definition
the energy required to remove an electron from a gaseous atom
Term

Within periods: increase left-to-right

Within groups: decrease as you move down

Definition
State the periodic trends for Ionization energy.
Term
Octet Rule
Definition

states that atoms tend to gain, lose, or share electrons in order to acquire a full set of eight valence electrons

- elements on left side of table tend to lose electrons and form positive ions

Term
Electronegativity
Definition
indicated relative ability of its atoms to attract electrons in a chemical bond
Term

Within periods: increases as you move left-to-right

Within groups: decrease as you move down

Definition
State the periodic trends for Electronegativity
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