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Chemistry for Living
Exam Two
36
Chemistry
Not Applicable
01/18/2005

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Term
Fossil fuels
Definition
coal, natural gas, and oil; they are non-renewable sources that will eventually run out
Term
renewable sources
Definition
wind, solar power, water, grain (corn), mixtrure of gas and alcohol (ie--Brazil uses sugar cane and turns it into alcohol for fuel
Term
joule
Definition
unit for energy
Term
Law of the Conservation of Energy (or) The First Law of Thermodynamics
Definition
all energy must be conserved (it can not be created or destroyed) **an exception to this law is nuclear reactions which cause a change in matter
Term
Combustion Reaction
Definition
one of the most common energy generated reactions; any fuel (ex--hydrocarbon) will burn in the presence of oxygen. the product will always be CO2 + H2O;
CH4 + O2--->CO2 + H2O; this reaction generates heat, thus it is an exothermic reaction (endothermic reactions absorb heat)
Term
activation energy
Definition
used to start a reaction
Term
exothermic reaction
Definition
more energy is on the reactant side; the rest of energy on the product side is converted to something else (but not less); it involves the breaking and reforming of bonds which release energy (breaks it up) and converts to heat (energy decreases)
Term
endothermic reaction
Definition
energy is gained; heat is absorbed
Term
How to affect reaction rate
Definition
*increase or decrease the concentration of reactants *use a catalyst which wioll increase the rate of reaction by decreasing activation energy *increase temperature which = an increase in the rate of reaction (molecules will bump into each other more quickly)
Term
What happens when you add a catalyst to an exothermic reaction?
Definition
less activation energy is needed; the reaction is sped up (reaction rate increases)
Term
Water on the Earth is made up of...
Definition
97.4%=Oceans * 2.59%=ice caps, glaciers, ground water * >.1% is lakes, rivers, the atmosphere
Term
solvent
Definition
has the ability to dissolve something else (ex of a solvent is water, H2O
Term
solute
Definition
something that can be easily dissolved by water (ie-lemonade mix)
Term
Dilution
Definition
by dilution, H2O reduces the concentrations of pollutants to safe levels and/or by carrying them away
Term
Unique Properties of H2O
Definition
*very high specific heat (can hold a lot of heat and carry it away to something else) *expands when it freezes *ability to evaporate (vapor/gas) *ability to be displaced *is more dense in liquid form *great solvent *neutral pH *used as a standard *is a liquid instead of a gas at room temp. (low molecular weight--18).
Term
nonpolar covalent bonds
Definition
when there is an equal sharing of electrons (ie--Cl2)
Term
polar covalent bonds
Definition
when a shared pair is drawn to one atom more than the other (unequal sharing of electrons)
Term
electronegativity
Definition
the attraction for a shared pair of electrons; it increases from left to right in a row on the periodic table, and from bottom to top in a column, it increases--ie F (fluorine) is the most electronegative element.
Term
shared electrons
Definition
electrons furthest away from the nucleus are the ones being shared
Term
Fluorine v. Iodine
Definition
F--has fewer electrons, so nucleus attracts own electrons as wel as electrons of other atoms; I--has more electrons which shield positivity of the nucleus for any other electrons
Term
(water) Purity
Definition
*measuring concentration--% refers to parts per 100 (pph); ppm=parts per million; ppb=parts ber billion
Term
M=molarity
Definition
moles of solution
Term
Avogadro's #
Definition
is equal to 6.023x10^23 atoms or molecules;
Term
molar mass (molecular weight)
Definition
1 mole=avogadro's #=molar mass
(ie: CO2-->molar mass=44g=6.02x10^23 molecules of CO2=1 mole of CO2)
Term
Find the molarity of 10g of CO2
Definition
10g of CO2 x 1 mole/44g=___moles
Term
H bonding
Definition
though it is only 1/10 as strong as other bonds, it is a weak bond, but it causes water molecules to stick together;
Term
ionic bond
Definition
when there is a transfer of electrons (ie NaCl--Na is +1 and Cl is -1);
Term
cations
Definition
positive charge (metals)
Term
anions
Definition
negative charge (nonmetals)
Term
ionic compound
Definition
made up of a metal and nonmetal; it must be neutral
Term
polyatomic ions
Definition
more than one atom joined to another atom w/ a charge (ie--NaOH; (NH4)3PO4
Term
what happens when NaCl is dissolved in water?
Definition
positive parts of H2O (H) surround Cl and negative parts of H2O (O) surround Na; *water is a polar covalent molecule that associates itself with these ions*
Term
ionic and water
Definition
ionic compounds WILL dissolve in water (ie--NaCl)
Term
like dissolves like
Definition
NH3 is a polar bond and polar molecule, and so is H2O, therefore it will dissolve b/c polar dissolves polar; anything like water will dissolve in it--water and something nonpolar will not dissolve (ie-water and oil)
Term
why does water dissolve sugar?
Definition
b/c sugar is made of C12, H22, and O11; hydrogen bonds will be formed and thus O on H2O will attract to H on the sugar molecule and H on H2O will attract to O on sugar molecule.
Term
concentration
Definition
it is the ratio of ingredient to water or solute to solvent; can be expressed in ppm, ppb, % (parts per hundred); most commonly used in lab is molarity which is moles per Liter.
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