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Chemistry Final Exam Dr. Whitcomb
Exam 1 Questions Ch 1,4,11,12
53
Chemistry
Undergraduate 1
12/09/2010

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Term
The total maximum number of electrons in the 3p orbitals is 6. T or F
Definition
True
Term
A 3p orbital is larger than a 2 p orbital. T or F
Definition
True
Term
The Greek symbol used in chemistry notation for 'partial" or "slightly" is δ. T or F
Definition
True
Term
Different wavelengths of light carry different amount of energy. T or F
Definition
True
Term
A polar covalent bond is more ionic than an ionic bond. T or F
Definition
False
Term
Electronegativities generally decrease from left to right in the Periodic Table. T or F
Definition
False
Electronegativities increase from left to right on the Periodic Table.
Term
Water is an example of a polar molecule. T or F
Definition
True
Term
Phosphorous normally can be expected to form 3 bond with other elements. T or F
Definition
True
Term
The abbreviation for wavelength is the Greek letter ν. T or F
Definition
False.
λ = wavelength
Term
Calcium has 4 electrons in its 4s orbital
Definition
False.
An s orbital only supports up to 2 electrons
Term
Silicon is an example of a "d-block" element. T or F
Definition
False.
It's in the p-block.
Term
The ionization energy for phosphorous is higher than for sodium. T or F
Definition
True.
P WANTS electrons. Na isn't really that interested in more electrons.
Term
The octet rule must be satisfied for all the element in C2O4H2. T or F
Definition
False.
H follows the duet rule, not the octet rule.
Term
H2O2 is an example of a diatomic molecule. T or F
Definition
False. Diatomic molecules: H2, N2, O2, F2, Cl2, Br2, and I2.
Term
Triple bonds contain a total of 6 electrons. T or F
Definition
True
Term
The reaction between Na0 and H2O should be similar to K0 and H2O. T or F
Definition
True
Term
The net charge of an ionic compound must be zero. T or F
Definition
True
Term
Li+ has the same properties as He. T or F
Definition
False???
Term
NH4Cl sublimed in the Separation of Mixtures laboratory. T or F
Definition
True
Term
The number of valence electrons = Z minus the number of core electrons. T or F
Definition
True
Term
Electronegativities: H = 2.1, Be = 1.5, N = 3.0, F = 4.0, O = 3.5

The correct dipole moment arrow for a Be-N bond is:

a. ←+
b. +→
c. ↑
d. ↓
e. no arrow, there is no dipole
Definition
b. +→
Because N (3.0) has a higher electronegativity than Be (1.5).
Term
KBr is:
a: a ternary compound
b: an element
c: a diatomic molecule
d: a globular cluster
e: an ionic compound
Definition
e. an ionic compound
Term
N2 is: a. a binary compound b. an element c. a diatomic molecule d. a polar molecule e. an ion
Definition
c. a diatomic molecule
Term
Metallic gold is:
a. a binary compound
b. an element
c. a diatomic molecule
d. a metalloid
e. an ion
Definition
b. an element
Term
Electronegativities: H = 2.1, Be = 1.5, N = 3.0, F = 4.0, O = 3.5

The type of bond in Be-Be is:
a. ionic
b. polar covalent
c. covalent
d. polar ionic
e. unstable
Definition
c. covalent
Be = 1.5
1.5 - 1.5 = 0.0
Term
Electronegativities: H = 2.1, Be = 1.5, N = 3.0, F = 4.0, O = 3.5

The type of bond in C-F is:
a. ionic
b. polar covalent
c. covalent
d. polar ionic
e. unstable
Definition
b. polar covalent
C = 2.5 F = 4
4 - 2.5 = 1.5
Term
Electronegativities: H = 2.1, Be = 1.5, N = 3.0, F = 4.0, O = 3.5

The type of bond in Be-F is:
a. ionic
b. polar covalent
c. covalent
d. polar ionic
e. unstable
Definition
a. ionic
Be = 1.5
F = 4.0
4.0 - 1.5 = 2.5
Term
Electronegativities: H = 2.1, Be = 1.5, N = 3.0, F = 4.0, O = 3.5

The correct order of the following bonds from least polar to most polar is:
a. Be-C, Be-N, H-F, O-O
b. H-F, O-O, Be-N, Be-C
c. Be-N, Be-C, O-O, H-F
d. O-O, Be-C, Be-N, H-F
e. O-O, Be-N, H-F, Be-C
Definition
d. O-O, Be-C, Be-N, H-F
O-O 3.5 - 3.5 = 0.0 Least Polar
Be-C 1.5-2.5 = 1.0
Be-N 1.5-3.0 = 1.5
H-F 4.0-2.1 = 1.9 Most Polar
Term
The order of orbital filling begins with:

a. 1s, 2s, 2d, 2p
b. 3s, 2p, 2s, 1s
c. 1s, 2s, 2p, 2d
d. 1s, 2s, 3s, 4s
e. 1s, 2s, 2p, 3s
Definition
e. 1s, 2s, 2p, 3s
Term
H2O has the molecular geometry: a. Trigonal pyramid b. Trigonal Planar c. Bent or V-shaped d. Tetrahedral e. Ternary
Definition
c. Bent or V-shaped
Term
Is it a chemical or physical change? Boiling liquid N2 (like I showed in class)
Definition
Physical
Term
Is it a chemical or physical change?

The copper dome on St. Paul's cathedral turning blue-green
Definition
Chemical
Term
Is it a chemical or physical change?

Gasoline burning when you drive your car
Definition
Chemical
Term
Is it a chemical or physical change?

Formation of cans from molten aluminum
Definition
Physical
Term
Phosphorus electronic configuration
Definition
1s22s22p63s23p2
Term
Phosphorus orbital box diagram
Definition
[↑↓]
[↑↓] [↑↓][↑↓][↑↓]
[↑↓] [↑ ][↑ ][↑ ]
Term
From the Periodic Table, what metalloid as 3d10 electrons and only 4p3 electrons?
Definition
As
Term
The following orbital box diagram for 1s22s22p4 is incorrect: [↑↓] [↑↓] [↑↓][↑↓][ ] What's the correct version?
Definition
[↑↓] [↑↓] [↑↓][↑ ][↑ ]
Term
Name an example of a positively charged ion and it's elemental symbol with the correct charged ion.
Definition
Sodium Na+
Term
Name an example of a negatively charged ion and it's elemental symbol with the correct charged ion.
Definition
Chloride Cl-
Term
Name an example of an alkaline earth metal and it's elemental symbol with the correct charged ion.
Definition
Magnesium Mg+2
Term
Name an example of a halogen and it's elemental symbol with the correct charged ion.
Definition
Bromine Br-
Term
Name an example of a noble gas.
Definition
Argon
Term
Name and example of a transition metal.
Definition
Copper
Term
Name the two types of ions.
Definition
cations and anions
Term
What is the isotopic symbol for Neon?
Definition
2010Ne
Term
How many neutrons does titanium have?
Definition
47.88 - 22 = 25.88 = 26
Term
Give the correct formula for a compound containing Cr3+ and S2-:
Definition
Cr2S3:
Term
Write the correct name for MgS:
Definition
magnesium sulfide
Term
How many valence electrons and core electrons does each of the following have?
1. Chlorine
2. Calcium
3. Boron
Definition
1. Chlorine -- 7val, 10core
2. Calcium -- 2val, 18core
3. Boron-- 3val, 2core
Term
Give the proper name or chemical symbol for the following elements:
Nickel
Si
Potassium
Nitrogen
Carbon
S
Definition
Nickel -- Ni
Si -- Silicon
Potassium -- K
Nitrogen -- N
Carbon -- C
S -- Sulfur
Term
Use an orbital box diagram to explain why oxygen normally can be expected to form 2 bonds in any molecule:
Definition
[↑↓] [↑↓] [↑↓][↑ ][↑ ]
1s2 2s2 2p4

Oxygen can be expected to form 2 bonds in any molecule because, as illustrated by the orbital box diagram, there are 2 "vacancies" in the 2 p orbital which O would like to fill with 2e-, thereby resulting in an electron configuration like that of a noble gas.
Term
What needs to surround the Lewis Dot structure for PO43-?
Definition
__ ___ 3-
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