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Chemistry 1B
Chapter 9
7
Chemistry
Undergraduate 1
01/23/2007

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Term
RELATIONSHIP AMONG BOND ORDER, BOND LENGTH, AND BOND ENERGY.
Definition
For a given pair of atoms, a HIGHER bond order results in a SHORTER bond length and a HIGHER bond energy

SHORTER BOND = STRONGER BOND
Term
COMPARING BOND LENGTH AND BOND STRENGTH
Definition
Bond length INCREASES and bond strength DECREASES as the halogen's atomic radius INCREASES.

ATOMIC SIZE INCREASES DOWN A GROUP.
Term
FORMULA FOR CHANGE in HEAT OF RXN
Definition
reactant bonds broken(+) + product bonds formed(-)
Term
ELECTRONEGATIVITY pg.352
Definition
Generally INCREASES UP a group and ACROSS a period.

NONMETALS ARE MORE ELECTRONEGATIVE AND METALS.
Term
Change/Difference in EN and IONIC CHARACTER (relationship)
Definition
>1.7 mostly ionic
0.4-1.7 polar covalent
<0.4 mostly covalent
0 nonpolar covalent
Term
RELATIONSHIP of PERCENT IONIC CHARACTER and DIFFERENCE IN EN
Definition
Percent ionic character generally increases with DIFFERENCE in EN
Term
EN and covalentness...
Definition
as DIFFERENCE IN EN becomes smaller, the bond becomes MORE COVALENT
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