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Chemistry 111
Chapter 2
110
Chemistry
Undergraduate 1
02/02/2015

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Term
Atom & composition
Definition
-basic unit of an element that can enter into a chemical combination
-composed of protons, neutrons, and electrons
Term
Protons(charge and mass)
Definition
- (+) or +1
- m=1837 times that of an electron
- actual mass= 1.673 x10^(-24)
Term
Electron(charge and mass)
Definition
-(-) or -1
- mass=9.110x10^(-28)
- mass=1/1837 of a H atom
Term
Ions (names of (+/-))
Definition
- cations- (+) - loses electrons
-anions- (-) - gains electrons
Term
Atomic number is the number of..
Definition
- number of protons
Term
Mass number is the number of..
Definition
- protons and neutrons
Term
Isotopes
Definition
- atoms with the same number of protons/atomic# but has different mass numbers
Term
Atomic weight
Definition
- average mass of all naturally occuring isotopes of that element
- takes into account relative abundance of the elements isotopes
Term
Percent abundance
Definition
- % of atoms of a natural sample of the pure element represented by a particular isotope to describe isotope composition for an element
Term
Periodic Table (horiz/vert)
Definition
- Horizontal- period
- Vertical- group
Term
Group 1A
Definition
- alkali metals
- very reactive
-shiny solids that react vigorously with air, water,
Term
Group 2A
Definition
- alkaline earth metals
- not quite as reactive
- react with water to form alkaline solutions
Term
Group 6A
Definition
- chalogens
Term
Group 7A
Definition
- halogens
Term
Group 8A
Definition
- noble gases
- rare gases/ inert gases
- least reactive elements
Term
Representative elements
Definition
- main group elements
- group number followed by letter A
Term
Transition metals
Definition
- Group # followed by letter B
Term
Lanthanides and Actinides
Definition
- portions of periods 6 and 7 that are below the main body
Term
Metal properties
Definition
- good conductors of heat and electricity
-high luster (shiny)
- high melting point
- high density
- solids at room temperature (Hg- mercury- liquid)
Term
Nonmetal properties
Definition
-poor conductors of heat and electricity
- no lustrous, relative dull
- low melting point and density
- C, P, S, SE, I are solids
-Br- liquid
- the rest are gases H, N, O, F, Cl, He, Ar, Kr, Xe, Ra
Term
Metalloids or semimetals
Definition
- intermediate between properties of metal and nonmetals
- raw materials or semiconductors device that make the electronic industry possible
- B, Si, Ge, Te, Sb, As, Po
Term
Molecules
Definition
- aggregate of at least 2 atoms in a definite arrangement held together by chemical forces/ chemical bonds
-smallest unit of a compound
Term
Diatomic molecule
Definition
- 2 atoms
Term
Allotropes
Definition
- one or two or more distinct forms of an element
- differ in chemical and physical propterties
Term
Covalent (molecular) compound
Definition
- all elements in the compund are nonmetals
- contain discrete molecular units
- inorganic acids
-many are binary compounds (02)
Term
Molecular covalent compound
Definition
-molecule formed by covalent bonds in which atoms share one or more pairs of valence electrons
Term
Network Covalent Compound
Definition
- chemical compound in which atoms are bonded by covalent bonds in a continuous network (SiO2)
- there are no individual molecules and the entire crystal may be considered a macromolecule
Term
Molecular vs Empirical formula
Definition
-Molecular- shows the exact # of atoms of each element in the smallest unit of a substance
-Empirical- shows the simplest whole number ratio of the atoms in a substance molecule
Term
Structural Forumula
Definition
-shows linkage of all the atoms in the molecule
Term
Condensed structural forumla
Definition
-lists atoms present in groups to indicate connectivity between the atoms
Term
Molecular Compound naming
Definition
- cation first, then anion
-first element listed is the one "more metal like"
-prefixes are written before the name of the element to indicate # of atoms present
Term
Mono, Di, Tri, deca, tetra, penta, hexa, hepta, octa, nona, deca, dodeca
Definition
1,2,3,4,5,6,7,8,9
Term
Molecular compound exceptions-NH3
Definition
-Ammonia
Term
Molecular compound exceptions-CH4
Definition
-methane
Term
Molecular compound exceptions-H20
Definition
-water
Term
Molecular compound exceptions-PH3
Definition
-phosphine
Term
Molecular compound exceptions-H2S
Definition
-hydrogen sulfide
Term
Molecular compound exceptions-B2H6
Definition
- diborane
Term
Hydrocarbon
Definition
-carbon and hydrogen compounds
-simplest of all organic compounds
-used as fuels starting material for chemistry industry
Term
How are organic compounds determined
Definition
-by functional groups chemically bound to parents compound
Term
Functional group -OH
Definition
-hydroxyl group
-alcohol
Term
Functional group -NH2
Definition
- amino group
-amine
Term
Functional group -COOH
Definition
-carbonxyl group
-carboxylic acid- organic acid
Term
Organic chemistry
Definition
-the branch of chemistry that deals with carbon compound and functional groups
Term
Alkanes
Definition
-have no branches
-*SINGLE* carbon chain/bond
-formula: CnH2n+2 where n is greater or equal to 1
Term
Alkenes
Definition
-contains *at least one* carbon-carbon *double bond*
-formula: CnH2n where n is greater or equal to 1
Term
Alkynes
Definition
-contain at *least one* carbon-carbon *triple bond*
-formula: CnH2n-2 where n is greater or equal to 1
Term
Acid
Definition
-produces H+ ions in water
- any substance that dissolves and dissociated into ions and one is H+
Term
Naming acids
Definition
- H cation called hydro-
- anion with the -ide ending becomes -ic
Term
Rules to writing acids
Definition
-write the prefix hydro-
- followed by the stem of the 2nd element of the suffix add ic
-add the word acid
-make sure to add aqueous (aq) after the word "acid"
Term
Oxoacids
Definition
- acids where anion is polyatomic
Term
How to name Oxoacids
Definition
-if the ending is -ite -> change to -ous
if the ending is -ate -> change to -ic
- if there are more than 2 ions in the series, prefixes "hypo" (less than) and "per" (more than) are used
Term
NO3- (name and oxoacidic name & formula if applicable)
Definition
-Nitrate
-HNO3 nitric acid
Term
oxoanions
Definition
- polyatomic ions containing oxygen
- contain different numbers of oxygen
-are named by the number of oxygen in the ion
-if there are 2 in series, the one with more oxygen atoms ends in -ate
-the one with few ends with -ite
-more than 2 ions in the series, "hypo" and "per" are used
Term
Ionic Compounds
Definition
-formed from cations and anions
-species that carry a net (+) or(-) charge
-most are solids with a high melting point
-
Term
Monatomic ion
Definition
-single atom ion
-EX:K+, O-2, Al3+
Term
Polyatomic ion
Definition
- two or more ions
Term
Polyatomic ion: SO42-
Definition
-sulfate
Term
Polyatomic ion:No3-
Definition
-nitrate
Term
Polyatomic ion: NH4+
Definition
-Ammonium
Term
Polyatomic ion: OH-
Definition
-hydroxide
Term
Elements in the same group have...
Definition
-similar chemical and physical properties
Term
A groups
Definition
-are the main-group elements
-also called the representative elements
Term
B groups
Definition
-are transition metals
Term
Crisscross rule
Definition
-the subscript on the cation is numerically equal to the charge of the anion and the subscript of the anion is numerically equal to the charge of the cation
Term
Polyatomic ions
Definition
-groups of covalently bonded ions
Term
Carbonate Formula
Definition
CO32-
Term
Hydrocarbonate or bicarbonate Formula
Definition
HCO3-
Term
Nitrate Formula
Definition
NO3-
Term
Permaganate Formula
Definition
KMnO4
Term
Phosphate Formula
Definition
PO43-
Term
Ionic compund rules and properties
Definition
-formula written in the empirical
-they are 3-D crystal networks
-formula tells cations to anions
-charges in ionic compounds MUST equal 0
Term
Chemical forumlas
Definition
- express the composition of molecules and ionic compounds in terms of chemical symbols
-indicates number of elements and relative number of atoms in a compound
-change the number in a subscript and you change the compound
Term
Ionic Compound naming rules
Definition
-write the name of the cation
-write the name of the stem for the anion and add the suffix "-ide"
Term
Name the polyatomic ion: KNO3
Definition
-KNO3= potassium nitrate
Term
Name the polyatomic ion: Fe(OH)2
Definition
- iron(II) hydroxide
Term
Name the polyatomic ion: KNO2
Definition
- Potassium nitrite
Term
Inorganic compounds
Definition
- formed from more than 3 elements
-one or more of the ions is polyatomic
Term
Only metal liquid at RT
Definition
-mercury (Hg)
Term
Only liquid nonmetal at RT
Definition
-bromine Br
Term
11 gases at RT
Definition
-hydrogen, nitrogen, oxygen, fluorine, chlorine, helium, neon, argon, krypton, xenon, and
radon
Term
Naming Inorganic Compounds
Definition
-identify the ions
-name the cations in order given and follow with the names of the anions
Term
NaHCO3
Definition
Sodium Hydrogen carbonate
Term
NaHSO4
Definition
Sodium hydrogen sulfate
Term
Transition metals
Definition
-uses the stock
Term
Stock system
Definition
- for transition metals
-when a compound contains a metal that forms more than one cation, the charge on the cation or the metal is designated by a roman numeral immediately following the name of the metal
Term
Transition metals naming rules
Definition
-Write the name of the cation
-write the charge of the cation as roman numerals in (...)
- write the stem of the anion and add "-ide"
Term
Copper(II) oxide
Definition
-CuO
Term
Iron(III) chloride
Definition
FeCl3
Term
Chromium(VI) sulfide
Definition
CrS3
Term
Classical nomenclature
Definition
-when a metaalic ion has only 2 types of cations, the name of the metal is modified with suffixes -ous (for the lower charge) and "-ic" (for the higher charge)
Term
Covalent
Definition
-contain only nonmetals
-are named using prefixes to indicate # of each element in the formula
Term
Ionic
Definition
-contain monatomic and polyatomic ions
-usually contain metals and nonmetals
-NEVER named using prefixes
-sometimes name with cation charge in roman numerals
Term
n
Definition
Term
Wedge-and-dash Model
Definition
-is a two-dimensional representation of a three-dimensional
structure that can easily be drawn on paper
- bonds are represented by lines (bonds that lie in the plane of the paper)
-wedges (bonds that lie in front of the plane of the paper)
-dashes (bonds that lie behind the plane of the paper)
Term
Ball and-stick Model
Definition
-shows atoms as colored spheres connected by sticks that represent
covalent bonds.
Term
Space-filling model
Definition
-interpenetrating spheres represent the relative amount of
space occupied by each atom in the molecule
Term
Most common covalent bond categories
Definition
-binary nonmetals and inorganic acids
Term
Binary nonmetal compounds
Definition
-consist of only two elements, both nonmetals
- named using prefixes and -ide
Term
Hydrogen peroxide
Definition
-H2O2
Term
Hydrazine
Definition
-N2H4
Term
Nitric oxide
Definition
NO
Term
Inorganic acids
Definition
-form H+ ions when dissolved in water
-compounds that contain hyderogen and one or more nonmetals
Term
Inorganic acids are named...
Definition
-like binary compounds but without prefixes
Term
hydrogen halides are named... gas phase...aqueous phase....
Definition
-like binary compounds *when in gas form*
- are named with common names when aqueous
Term
Metals in Groups 1A, 2A, and 3A form.... ions and there charge is
Definition
-equal to the group number of the element.
Term
Nonmetals in Groups 5A, 6A, and 7A form....ions and there charge is
Definition
-equal to 8 minus the group number of the element.
Term
CN2-
Definition
-Cyanide
Term
CH3CO2-
Definition
-Acetate
Term
S2O3^2-
Definition
-Thiosulfate
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