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Chemistry 101 PolyAtomic Ions
Flash Cards of Polyatomic ions and their rules of naming.
7
Chemistry
Undergraduate 1
09/17/2010

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Term
Oxanions Rule Number One
Definition
Oxanions consist of oxygen and another element (the central element). The are names for the central element with the ending changed to "-ate" or "-ite".
Term

Rule number 2 for Oxanions

 

Definition
For two oxanions with the same central atom, the one with the "-ite" ending has one less oxygen than the one with the "-ate" ending. (This is the only difference between the two.)
Term

Rule Number 3 Oxanions

 

Definition
An oxanion with an "-ate" ending (and no prefix) will have three oxygen atoms if the central atom is in period 2 or is a halogen. All other oxanions ending in "-ate" have four oxygen atoms.
Term

Rule number 4 oxanions

 

Definition
Many of the halogens can have
Term

Rule #5 oxanions

 

Definition
Oxanions that have a charge of 2- or 3- can form new ions by adding hydrogen. The new ion is named by adding the word "hydrogen" in front of the anion name (for two hydrogen atoms, "dihydrogen" is used). Note that the charge decreases by one for each hydrogen present.
Term

Rule #6 oxanions

 

Definition
Dichromate (Cr2O72), permaganate (MnO4-), cyanate (OCN-), and hydroxide (OH-) are exceptions to these patterns.
Term
What does the prefix "thio-" indicate?
Definition
This prefix indicates that an oxygen atom has been replaced with a sulfur atom. For instance thiocynate (SCN-) is derived from (OCN-) Thiosulfate (S2O32-) is derived from sulfate (SO42-). Of the polyatomic ions needed to be known are cyanide (CN-), thiocynate (SCN-), and ammonium (NH4+).
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