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Chemical Ecology
Chemical Ecology Final Exam Flashcards
80
Chemistry
Undergraduate 4
12/11/2012

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Term
Phenolic
Definition
A natural product that contains hydroxyl groups. Had antioxidant activity.
Term
Phenolic
Definition
Flavenoids fall under this category
Term
Quinone
Definition
When Phenolics are oxidized they become this
Term
Polyphenolic
Definition
A Phelic structure with more than 12 rings
Term
Condensed Tannins
Definition
binds to everything especially in the presence of oxygen, oxidizes into quinones
Term
Shikimate Acid Pathway
Definition
Pathway through which most phenolics are created
Term
Lignin
Definition
A phenolic, wood
Term
Terpenes
Definition
A Natural product made of isoprene units (C5)
Term
steriods
Definition
a king of terpene with a hydroxyl group at position 3 and a cholestane skeleton, has a specific four ring structure
Term
Mevalonic acid pathway
Definition
The Pathway through which terpenes are made
Term
Digitoxin
Definition
Comes from the foxglove plant, is a cardiac glycoside, used to improve heart tone
Term
Alpha-endysone
Definition
an insect molting hormone that is a terpene
Term
N- Containing Compound
Definition
cyanogenic glycosides are under this category of natural product
Term
cyanogenic glycoside
Definition
an inactive form of cyanide- attached to a sugar to prevent auto-toxicity
Term
glucosinolates
Definition
mustard oil defenses of family brassicasea
Term
Alkaloid
Definition
a type of natural produce wherein there is a heterocyclic nitrogen atom, often used as medicine
Term
non-protein amino acid
Definition
a type of natural product that disrupts protien synthesis or DNA transcription
Term
Hemotoxin
Definition
targets and destroys red blood cells
Term
necrotoxin
Definition
necrosis in cells the encounter
Term
pheromone
Definition
an excreted factor that triggers a social response or effect on another individual in the same species. Chemical capable of acting outside the body
Term
Alarm Pheromone
Definition
a pheromone releases when an animal is attacked that causes other conspecifics to display escape behaviors
Term
signal pheromone
Definition
causes short term changes in conspecific liek the release of neurotransmitters
Term
releaser pheromone
Definition
ike an attractant molecule to get mates to come closer
Term
trail pheromone
Definition
in social insects, example: ants use it to help conspecific find foor
Term
primer pheromone
Definition
triggers developmental changes in conspecifics
Term
territorial pheromone
Definition
a pheromone laid down in the environment to mark terriory
Term
epideictic pheromone
Definition
used by female insects to indicate where her eggs have been laid
Term
sex pheromone
Definition
pheromone indicating availability of the female for breeding or males emiting signals about species and genotype
Term
Why is olfaction important?
Definition
Olfaction may serve a purpose in mate selection in sexual reproduction
Term
Limbic system
Definition
olfactory neurons directly connect here, center for aggression fear and mating responses
Term
Pheromone
Definition
A substance secreted by an animal that causes a specific reaction in another animal
Term
VMO
Definition
bilateral tubular structure on the anterior nasal septim that projects to the olfactory bulb
Term
nervus terminalus
Definition
Cranial nerve 0, conserved across all vertebrates degrades fetally in humans
Term
MHC
Definition
major histocompatibility complex
• Set of proteins expressed on the cellular surfaces that uniquely specifies individual and aids in recognition of non-self immune responses
Term
MHC in sexual selection
Definition
Combination are more diverse than what would be expected from chance alone- implying that there is a mechanism for selecting a mate with differing MHC
Term
Apocrine Glands
Definition
• Human apocrine glands make pheromones
o Modified sweat glands
o In areas that produce hair during puberty
o Function is odor secretion
o Commensal bacteria volatilize precursor molecules from the glands, hair aids the bacteria as a living space
Term
Human VMO
Definition
non functional and • signal transduction genes are psuedogenes
Term
Green Earth Hypothesis
Definition
Plants must not be as defenseless as they seem otherwise herbivores would have eaten them all
Term
Constitutive defense
Definition
plant defense that is always present
Term
Inducible defense
Definition
responses due to changes in gene transcription
Term
Tolerance for Herbivory
Definition
when herbivory is beneficial to plants because
o Better nutrient allocation
o Demand for sugars is reduced
o Older leaves are removed to allow younger leaves to grow
Term
Constitutive defense
Definition
plant defense that is always present
Term
Inducible defense
Definition
responses due to changes in gene transcription
Term
Tolerance for Herbivory
Definition
when herbivory is beneficial to plants because
o Better nutrient allocation
o Demand for sugars is reduced
o Older leaves are removed to allow younger leaves to grow
Term
Methods Pathogens use to attack plants
Definition
o Cell wall degrading enzymes
o Toxins that damage plants can be non-host specific or host specific
o Effector proteins: secreted near/ on plant suppress host defense processes like internal signaling mechanisms and production of phytochemicals
Term
Gene-for-gene interaction
Definition
immune response from plants:
• Plants have resistance (R ) genes, pathogen genes that encode for elicitors are AVr genes
o Host/pathogen have matching R + Avr- plants will resist pathogen
o If Avr and R do not match, no reistsance by plant
Term
Cost of Defenses
Definition
• Slowed growth
• Slowed primary processes
• Induced defenses don’t produce product when its not needed, save resources
Term
Benefit of induced defenses
Definition
o Phenotypically plastic plant- reduces chance that attacker adapts to defenses
o Dosage dependent effect- more dose, more damage
• Plant is better off making a lot of defense material when it is needed that a medium level all the time
o N. tabacum plants that produce a continually high level of nicotine flower later=biosynthetic cost
o Plants that produce N-containing compounds, less nitrogen available to produce rubisco which is necessary for photosynthesis
Term
cost of inducible defense
Definition
JA use results in plants with less fruit, longer ripening time and fewer seeds per plant
o Doesn’t attract seed dispersers as well
o Reduced fitness
Term
Physical defenses in plants
Definition
wax, cutin, suberin
Term
Hypersentistive response
Definition
seal off infected part and burn with oxidation
o Prevents spread of infection by microbial pathogens
o Commonly preceeds systemic acquired resistance
Term
Phytolexins
Definition
plant antibiotics, kill microbe AND infected plant cell
Term
Chitinase
Definition
chitinase breaks fungal cell walls and insect exoskeleton
Term
Salicylic acid
Definition
triggers systemic response to pathogens
o Spreads throughout plant
o Aspirin in fertilizer will immunize plant
Term
Gymnosperm
Definition
naked seed, evergreen plants
Term
angiosperm
Definition
flowering plants evolved around the time of pollinating insects
Term
Tri-trophic interactions
Definition
o C. Glomerata
o Larvae develop in caterpillar
o Pupae in silken cocoons
o Adults emerge and lay eggs in caterpillar
o Plant being eaten by caterpillar will release signal to attract adult
Term
Functional foods
Definition
Food factors from plants and animals may be participating in human health promotion
Term
Nutraceuticals
Definition
products produced from foods but sold in tablet, capsule etc
Term
Health benefits of nutraceuticals and functional foods
Definition
a. Treatment of cancer, CVD, aging, diabetes etc
b. Effects of functional foods are due to cocktail of phytochemicals and bioctives present
Term
Anti-carcinogenic effects of functional foods are rendered through
Definition
i. Antioxidant effect
ii. Effect on cell differentiation
iii. Increase activity of enzymes against carcinogens
iv. Change of estrogen metabolism
v. Effect on DNA methylation
vi. Maintenance of DNA repair
vii. Increase apoptosis of cancer cells
viii. Decrease of cell proliferation
Term
Over Processing
Definition
may remove desired components
i. White bread has less antioxidants than wheat bread
Term
Over Processing
Definition
may remove desired components
i. White bread has less antioxidants than wheat bread
Term
LDL cholesterol
Definition
Oxidation of cholesterols leads to plaque in the arteries
Term
Health Benefits of Marine Oils
Definition
Thinning of the blood, lowering triglycerides and lowing cholesterol levels and clot formation incidence
Term
Extreme Generalist
Definition
Humans are not carnivores or herbivores!
Term
Chemical senses
Definition
o Olfaction
o Touch- look for ripe fruit
o Taste/gustation: 4 kinds of taste buds
o Sweet, bitter, salty, sour, umami
Term
Urtication
Definition
o Texture, pain
o Controlled by cranial nerve 5
o Metallic taste keeps you from eating minerals
o TTX- pain
Term
Triterpene, saponins
Definition
surpress sweetness
Term
Bacterial transformation
Definition
• Gut bacteria transform and break down toxins
• Fermentation of alcohol and dairy products- this is more of a behavioral adaptation with humans
Term
Vomiting
Definition
• Eliminate toxins
• Animals that cannot vomit have geophagy- mice eat clay
• Cat and dogs eat grass to force themselves to vomit
• Vagus nerve
Term
Priline rich proteins
Definition
• In saliva
• Bind to phenolics
• Adding creamer to coffee
Term
Neophobia
Definition
adults dont like to try new food
Term
sensory specific satiety
Definition
getting sick of a food, don’t want hamburgers everyday because you need variation in the diet
Term
Fire/ comminution
Definition
other ways of preparing food, like cooking and drying
• Fire kills parasites and toxins
Term
First pass metabolism
Definition
non water soluble toxins - goes to the liver and kidney before the heart so you don’t die
Term
Methyl Salicylate
Definition
MeSA, oil of wintergreen, tells plants they’re about to be attacked
Term
MeJA, MeSA
Definition
aire born cues tell plants they're about to be attacked
Term
Volatile Organic Compounds
Definition
release of these after herbivory attracts parasitiods and predators to actively feeding larvae
Term
Kessler Paper
Definition
• VOC- release of volatile organic compounds after herbivory attracts parasitiods and predators to actively feeding larvae
• In natural systems herbivore mortality is more commonly mediated by a suite of generalist enemies
• Kessler et al. evaluated the role of herbivore-induced VOCs in nature
o VOC release from nicotiana attenuate growing in native population
o Manduca quemaculata
o D. minumus
o E. hirtipenis
• Open flow trapping design to collect VOCs from plants
• All attacked plants released more bergamontene
• MeSA released in headspace of all plants
• May function as a sign of herbivore damage in all plants
• Mimicked volatile release: 200 micrograms of MeJA, MeSA or others in a lanolin paste onto stems of plants in natural environment’s
o Resultant emissions were the same between herbivore infested or MeJA treated plant
Release of VOC affects both predation and ovipositon rates
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