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Chem Midterm
review of all topics on chem midterm
138
Chemistry
10th Grade
01/20/2013

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Term
Si units
Definition
time(s)
length(m)
Mass(kg)
Temperature(K)
amount of substance(Mole)
Term
Celcius to Kelvin
Definition
add 273
Term
density
Definition
mass/volume
Term
scientific notation
Definition
if making the number "bigger"(-)
if making the number "smaller"(+)
Term
signifigant digits
Definition
when(+) or (-) use the least amount of sig figs
Term
metric conversions
Definition
{image:|}
Term
accuracy vs. precision
Definition
correct vs. consistant
Term
percent error
Definition
experimental - accepted
divided by accepted value
times 100
Term
solid
Definition
particles vibrate but cannot move aroung
fixed shape
not compressible
fixed volume
Term
Liquid
Definition
particles can move around but are still close together
not compressible
fixed volume
Term
Gas
Definition
Particles can separate and move freely in container
compressible
variable volume
Term
Physical properties
Definition
Can be observed w/o changing the identity of the substance
melting, boiling point,density
Term
Chemical properties
Definition
describes the ability of a substance to undergo changes in identity
flammable,tarnishes in air
Term
Physical Changes
Definition
Changes the form of the substance without changing its identity
phase changes
Term
Chemical Changes
Definition
chemical reaction
Term
Law of conservation of mass
Definition
mass neither be created or destroyed
Term
phase changes
Definition
evaporation L to G
condensation G to L
melting S to L
freezing L to S
sublimation S to G
deposition G to S
Term
heterogeneous mixtures
Definition
medium to large sized particles that do not settle
salad dressing
Term
homogeneous mixtures
Definition
small particles form a solution
particles do not settle
rubbing alchohol
Term
chromotography
Definition
seperate substances based on their attraction to the water and their ability to be drawn across te paper
Term
distillaiton
Definition
differences in boiling points
Term
filtration
Definition
porous barrier separates solids and liquids
Term
sublimation
Definition
solid changges into a vapor without melting
Term
element
Definition
a pure substance made of the same type of atom
117
cannot be broken down
Term
compound
Definition
conatins atoms of different elements chemically combined together
formula
Term
matter
Definition
anything that has mass and takes up space
Term
Democtirus
Definition
first proposed the idea of an atome
Term
atom
Definition
protons and neutrons surrounded by an electron cloud
Term
electron
Definition
1- charge
elctron cloud
0 amu
J.J. discovered it using the cathode ray
Term
proton
Definition
1+ charge
1 amu
nucleus
Rutherford discovered it using the gold foil experiment
Term
neutron
Definition
0 charge
nucleus
1 amu
Chadwhick
Term
amu
Definition
a unit of amss used to express weight of atoms and molecules
Term
Thompson Model
Definition
[image]
Term
Rutherford Model
Definition
[image]
Term
how to read the periodic table
Definition
[image]
Term
percent abundance
Definition
(mass of first isotope)(X) + (mass of second isotope)(1-X)solve for x and plug it in
Term
atomic number
Definition
number of protons
Term
number of neutrons
Definition
mass#-atomic#
Term
mass number
Definition
protons + neutrons
Term
alpha particles
Definition
[image]
Term
beta particles
Definition
[image]
Term
positron particle
Definition
[image]
Term
electron capture
Definition
[image]
Term
gamma particle
Definition
[image]
Term
half life problems
Definition

Total Time = (length of one half-life) (# of half lives)

 

Remaining Mass = initial mass / 2 number of half lives

 

Initial Mass = (remaining mass) (2 number of half lives )

 

(2 number of half lives ) = initial mass/remaining mass

Term
wavelength
Definition
[image]
Term
frequency
Definition
v
Term
colors of the electro-magnetic spectrum
(lowest to highest frequency)
Definition
red orange yellow green blue indigo violet
Term
electromagnetic spectrum(longest to shortest wavelength)
Definition
Radio micro infrared visible ultraviolet x-rays gamma rays
Term
speed of light
Definition
3.00*10^8 m/s
3.00 * 10 ^17 nm/s
Term
quantum mechanical model
Definition
treats electron as a wave
Term
Bohrs model of the atom
Definition
electrons move in exact paths called orbitals
only worked for hydrogen
Term
two states for electrons
Definition
ground vs. excited
Term
# of energy levels
Definition
4
Term
how many electrons can each orbital hold
Definition
2 electrons with opposite spin
Term
fission
Definition
splitting a heavy nucleus into two nuclei with smaller masses
Term
fusion
Definition
two small nuclei are joined together
Term
Calculating mass defect
Definition
Mass Defect = (mass of isotope) – (# of p+) (mass of one proton) – (# of neutrons) (mass of one neutron)
Term
n quantum number
Definition
principle quantum number
specifies the energy level and the energy of an electron in an atom
Term
l quantum number
Definition

azimuthal quantum number specifies the sub level and the shape of the orbital

§l = 0 corresponds to a s sublevel
§l = 1 corresponds to a p sublevel
§l = 2 corresponds to a d sublevel
§l = 3 corresponds to an f sublevel
Term
ml quantum number
Definition

magnetic quantum number specifies orbitals and labels the different orbitals of a given sublevel

§So, if = 0 (an s orbital), ml =0
§If = 1 (a p orbital), ml =-1, 0, +1
§If = 2 (a d orbital), ml =-2,-1,0,+1,+2
§If = 3 (an f orbital), ml = -3,-2,-1,0,+1,+2,+3
Term
ms quantum number
Definition
spin quantum number
specifies the direction of spin of the two electrons within an orbital
Term
Meneleev
Definition
first periodic table
Term
Henry Mosley
Definition
increasing atomic number
Term
periodic law
Definition
there is a periodic repetition of chemical and physical properties when elements are arranged in increasing atomic number
Term
Group 1
Definition
Alkali metals
left
1 valence electron
very reactive
lose
Term
Group 2
Definition
Alkaline Earth metals
left
2 valence
reactive
gain
Term
Group 3-12
Definition
transition metals
middle
2
Term
Group 17
Definition

halogens right 7

reactive gain

Term
Group 18
Definition
noble gases
right
8 valence
very stable
neither
Term
metals
Definition
left
good conductors of heat and electricity
malleable
ductile
luster
lose electrons when they are heated
Term
metalloids
Definition
staircase elements
less brittle
semiconductors of electricity
some have luster
Term
nonmetals
Definition
right
poor conductors of heat and electricity
brittle
many are gases
gain or share when they heat
Term
4 blocks of the periodic table
Definition
S P D F
Term
ionization energy
Definition
the energy required to remove the outermost electron from a gaseous atom
increase across
decrease down
Term
electronegativity
Definition
measure of the ability of an atomic to attract electrons
increase across
decrease down
Term
electron affinity
Definition
neutral atoms likely-hood of gaining an electron
Term
octet rule
Definition
atoms want 8 valence electrons
Term
successive ionization energy
Definition
it takes more an more energy each time you remove an electron
Term
ionic bond
Definition
transfer of electrons
Term
properties of ionic compounds
Definition
good conductors of electricity when in aqueous state and when in molten state
hard rigid brittle
Term
solid
Definition
crystal lattice
Term
Lewis dot structures
Definition
number of valence electrons in a circle
Term
sea of electrons
Definition
valence electrons are removed and are used by all toms
Term
covalent bond
Definition
a shared pair of electrons
Term
diatomic elements
Definition
Br,i,N,Cl,H,O,F
Term
single
Definition
sigma
1 pi bond
long
weak
Term
double bonds
Definition
1 sigma 1 pi
`
Term
Triple bond
Definition
1 sigma 2 pi
Term
Lewis structures
Definition
hey maybe you know them?
Term
polarity
Definition
differences in electronegativity pull the electrons to one side of a compound
Term
Δ EN
Definition
0 nonpolar
less than .4 mostly covalent
.4 to 1.7 polar covalent
greater than 1.7 ionic
Term
7 shapes of the molecules
Definition
trigonal planar
linear
tetrahedral
pyramidal
bent
trigonal pyramidal
octahedral
Term
chemical reactions
Definition
reactant+reactant=product
Term
synthesis
Definition
A+B=AB
combustion (something burns)
Term
decomposition
Definition
AB=A+B
Term
double replacement
Definition
AY+BX=AX+BY
Term
single replacement
Definition
AY+B=BY+A
Term
activity series
Definition
element that are lower on the activity series cannot replace things higher on the activity seies
Term
MOLE
Definition
1mol=6.2X10^23
avagadro's number
Term
Avagadros number
Definition
relationship between the number of particles and volume of a gas
Term
Molar Mass
Definition
mass of 1 mol of an element or compound
Term
law of definite proportions
Definition
a compound is always composed of the same elements in the same proportion no matter how large or how small the sample size
Term
Law of multiple proportions
Definition
masses of one element that combine with a fixed mass of another will do so in a ratio of small whole numbers.
Term
percent mass of an element in a compound
Definition
%comp.=total mass of element/total mass of compound (X 100)
Term
empirical formula
Definition
smallest whole number ratio of elements in a compound
Term
finding the empirical formula
Definition
1. find the mass of each element
2. fin the moles of each element
3. divide moles by the smallest number to find subscripts
4. must be whole numbers
Term
molecular formula
Definition
"true formula" the actual number of atoms in a compound, either the same as or a whole-number multiple of the empirical formula
Term
finding the molecular formula
Definition
1. Find the EF
2. find the EF mass
3. Divide Molar Mass(given in problem)by the empirical formula mass
4. Multiple each subscript in your EF by the from step 3
Term
HYdrate
Definition
Any salt that has water chemically bonded to the ions in the crystal structure is a hydrate or hydrated crystal
Term
Writing formulas and names of hydrates
Definition
numerical prefixes are used to indicate the # of water molecules that are attached to the ionic compound
Term
how is a hydrate formed?
Definition
a substance that absorbs water from the air is said to be hygroscopic
Term
finding the hydrate formula
Definition
1. determine grams of h20 lostt due to heating
2. convert g H20 to moles & convert g of anhydrate to moles
3. divide moles of H20/moles of anhydrate
Term
limiting reactant
Definition
determines the amount of product that can be formed b/x it gets up b4 the other reactants
Term
excess reactants
Definition
other reactants that areleft over when a reaction stops
Term
determining limiting reactant
Definition
Determine which reactant is limiting by converting the grams of each reactant to moles and then dividing each answer by its coefficient given in the equation. The reactant with the smallest answer is the limiting reactant.
2. use stoichiometry to determine the amount of product produced by the moles of limiting reactant
Term
percent yeild
Definition
measure of the efficiency of a chemical reaction
theoretical yield-the calculated amount
actual yield- amount produced when the reaction is carried out in the lab
Term
nature of gases
Definition
expand to fill their containers
fluid
low density
compressible
effuse and diffuse
Term
kinetic molecular theory
Definition
particles are always in motion
volume of individual particles=zero
collisions of the particles with container walls causue the pressure exterted
particles exert o forces on each other
average kinetic energy is proportional to K temp of a gas
Term
gas particle collisions
Definition
ELASTIC
when particles collide no energy is lost
Term
kinetic energy of gas particles
Definition
all have the same average kinetic energy
KE=(1/2)mv^2
@ the same temp small molecules move FASTER than large molecules
Term
Diffusion
Definition
rate of gas mixing
result of random movement of gas particles
rate increases with temperature
small faster than large
high to low concentration
Term
effusion
Definition
gas escaping from a tiny opening
Term
Grahms law of diffusion and effusion
Definition
high to low concentration
rate of diffusion/effusion for a gas is inversely proportional tothe square root of the MM of the gas
Term
Grahms Law of Diffusion and Effusion
Definition
rate of a/rate of b=M of B/M of A
Term
pressure
Definition
force per area unit
gases exert_____________ when they collide with he sides of their container
Term
atmospheric pressure
Definition
pressure exerted by the stomsphere
lower at higher altitudes
measured with a barometer
Term
closed end manometer
Definition
pressure is equal tothe difference in hight of HG in the two arms
Term
open end manometer
Definition
pressure of gas equal 750-height difference
Term
Dalton law of partial pressure
Definition
the total pressure of a mixture of gases is the sum of the pressure of all the gases in the mixtures
Term
intramoleculat forces
Definition
holds atoms/ions together in ionic, covalent, or metallic bonds
Term
intermolecular forces
Definition
hold identical molecules together
generally weaker that covalent bonds
dipole-dipole,hydrogen, London dispersion
Term
Dipole-dipole
Definition
a molecule or a part of a molecule that contains both partial positive and partial negative regions
created when ther is a large difference in EN
Term
Hydrogen bonds
Definition
have a large difference in eletronegativity, thus creating a large dipole, or hihgly polar bond
VERY strong attraction
Term
London Dispersion forces
Definition
the constant motion fo electrons create temporary dipoles
Term
Liquids
Definition
definite volume but no definite shape(take that of the container)
high density
not compresabel
diffuse
surface tension
fluid
Term
Viscosity
Definition
the resistance fo a liquid to flow
stronger intermolecular forces mean higher viscosity
Term
capillary action
Definition
the rise of liquids through slim tubes or permeable substances due to sdhesive and cohesive forces; adhesive>cohesive
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