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Chem Lab (Wash U - Chem 152)
Midterm Set
23
Chemistry
Undergraduate 1
02/28/2009

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Cards

Term

Temperature At Which Volumetric Flasks

Are Calibrated 

Definition
20° C
Term

Maximum Error of

Electronic Analytical Balance 

Definition

Coarse Range - 0.001 g

Fine Range - 0.0001 g 

Term
Sample Standard Deviation
Definition

 

 

_

S = [Σ (xi - x)2 / (n - 1)]1/2

Term
Average Deviation
Definition

_                         _       

d = [Σ Abs Val(xi - x) / n]

Term
% Average Deviation
Definition

 _     _                                 

%d = [d / Average Value] X 100%

Term

n

(in Statistical Calculations)

Definition
Number of Determinations
Term
Accuracy
Definition
The correctness of a measurement or determination. Measured by error.
Term
Precision
Definition
The reproducability of a set of measurements.  Measured by deviation.
Term
Relative Error
Definition

Abs Val(Absolute Error) / Average Value

Term

Maximum Standard Propagated Error

in a Sum of Values 

Definition

Sum of Maximum Error of

Each Value 

Term

Maximum Relative Propagated Error

in a Product or Quotient of Values 

Definition
Sum of relative standard errors of values.
Term
Molality of X
Definition
Moles of X / Mass of Solvent (kg)
Term
Things to Remember (Lab 1)
Definition

1) Remember to keep significant figures for each sub-calculation of a calulation

2) The avergae deviation of a more precise instruemtn should be smaller than that of a less precise one

3) The mass of a solution will probably have an error of .0002 g because it is ususally calculated by subtracting the mass of the empty container from that of the full one

4) The calculated density of an unknown solution should have 4 SF is V > 10.00 mL and 3 SF if V < 10.00 mL 

Term
Hydrophobic Characteristics
Definition
Nonpolar and insoluble in water.
Term
Hydrophilic Characteristics
Definition
Polar or charged and soluble in water.
Term
Things to Remember (Lab 2)
Definition

1) Absorbances should be written with 3 SF

2)  

Term
Two Components of A Successful Titration
Definition

1) The reaction between the known and unknown must be fast and stoichiometric

2)The must be a method for detecting the completion of the reaction 

Term

Primary Standard

Definition

1) Stable

2) Non-hygroscopic (doesn't absorb moisture from air)

3) Known composition 

Term
Amphiprotic Substance
Definition
A substance that can donate protons or accept protons.
Term
Amphoteric Substance
Definition
A substance that can act as either an acid or a base under different experimental conditions.
Term
Buffer Solution
Definition
A solution that resists changes in pH upon additions of small amounts of acid or base.
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