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chem lab
quiz 1
21
Chemistry
Undergraduate 2
02/20/2012

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Term
what are likely active ingredients in antacids?
Definition
metal hydroxides, carbonates, hydrogen carbonates
Term
what is the net ionic equation for the neutralization of magnesium hydroxide by stomach acid?
Definition
Mg(OH)3(s) + 2H3O(aq) --> Mg2+(aq) + 4H2O(l)
Term
the reaction between calcium carbonate and acid
Definition

CaCO3(s) + 2H3O (aq) --> Ca2+ + H2CO3 (aq) + 2H2O(l)

and then

H2CO3(aq) <--> CO2(g) + H2O

Term
how does the bicarbonate ion HCO3- have a buffering effect?
Definition

it reacts with both the base and the acid:

HCO3- + OH- <--> CO32- + H2O

and

HCO3- + H3O+ <--> CO2 (g) + 2H2O

Term
what is the net ionic equation for the back-titration of acid with base?
Definition
H3O+ + OH- <--> 2H2O
Term
how do you determine the moles of acid neutralized by an antacid tablet after back-titrating it with base?
Definition
subtract the moles of acid from the base used
Term
how do you calculate mass effectiveness of an antacid tablet?
Definition
by putting the moles of acid neutralized by the sample / mass of the sample
Term
what is the name of the indicator used in the back-titration of antacid tablets?
Definition
bromcresol green
Term
what color is bromcresol green in acid? in base?
Definition
yellow in acid, blue in base
Term
how do you tell if your antacid is a carbonate compound?
Definition
carbonate compounds will release bubbles of CO2 gas.
Term
what are the three cations that form insoluble chlorides?
Definition
Hg22+, Ag+, Pb2+
Term
list the net ionic equations expressing the formation of the three insoluble chloride salts
Definition

Hg22+ + 2Cl- <--> Hg2Cl2(s)

Ag+ + Cl- <--> AgCl (s)

Pb2+ + 2Cl- <--> PbCl2(s)

Term
what is the first thing you do to the compound of the three insoluble salts after precipitating by adding HCl?
Definition
add hot water, which will dissolve PbCl2
Term
how do you separate Hg from the precipitate from the hot water mixture? (also containing Ag)
Definition
add NH3
Term
write the equation of AgCl dissolving in ammonia?
Definition
AgCl(s) + 2NH3(aq) <--> [Ag(NH3)2]+(aq) + Cl-(aq)
Term
reaction of Hg2Cl2 with NH3
Definition
Hg2Cl2(s) + 2NH3 <--> HgNH2Cl(s) + Hg(l) + NH4+ + Cl-
Term
how do you verify the presence of Hg22+ in the original mixture?
Definition
after dissolving Pb in hot water, leaving Hg and Ag as precipitant, treat the precipitant with NH3. If Hg22+ is present, it will be black or grey. 
Term
how do you identify the presence (or lack thereof) of Ag+ in the supernatant liquid after reacting Hg with NH3, and what is the equation?
Definition

adding nitric acid solution to the supernatant liquid:

[Ag(NH3)2]+(aq) + 2H3O+ (aq) + Cl- <--> AgCl(s) + 2NH4+ (aq)+2H2O(l)

Term
how do you detect the presence of Pb2+ ions in the hot water filtrate? write the net ionic equation.
Definition

add K2CrO4:

Pb2+ + CrO42- --> PbCrO4 (s) which is yellow.

 

Term
what is the difference between gas and vapor?
Definition
gas is a state of matter at room temperature. vapor is a PART of a substance below critical temperature that is in gaseous form.
Term
as temperature increases, vapor pressure increases at a(n) ___________ rate
Definition
EXPONENTIAL
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