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What is the expression for equilibrium |
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Definition
K=[products]^coeff. /[reactants]^coeff. |
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How do you tell whether the forward or reverse reactant is more successful. |
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Definition
You calculate the k for forward and the k for reverse which is just the opposite. Which ever one is larger, is more successful. |
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Term
Ex. 1 Given: A + 2B <> C
I 10M 8M 0
C 2M 4M 2M
E 8M 4M 2M
1. What does the second row do to the reactants? products?
2. How much is being added or subtracted is determined by what?
3. If you want to find k what row do you use?
4.What does ICE stand for? |
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Definition
1. The second row subtracts from the reactants and adds to the products. 2. The amount added or subtracted is determined by moles 3. To find k use the third row or "e" 4. Initially, Change, equillibrium |
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Forward reactions increase products and reverse reactions decrease products. Catalyst has no effect on the amount of products
Volume increasing favors side with more moles while volume decreasing favors side with less moles.
pressure goes up, volume goes down |
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Definition
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A(g)+2B(g)<>C(g)+D(g)+heat
Favors reverse or forward 1. increasing [A] 2. increasing Temp 3. Decreasing [C] |
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Definition
1. forward 2. reverse 3. forward |
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Term
A(g)+2B(g)<>C(g)+D(g)+heat
Favors reverse or forward
1. increasing the volume of the container 2. increasing [D] 3. Removing some B |
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Definition
1. reverse 2.reverse 3.reverse |
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A(g)+B(g)+heat<>2C(g)+D(g)
increases, decreases, or has no effect on product?
1. Decreasing pressure 2. decreasing temp 3. addition of catalyst 4. decreasing [D] |
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Definition
1. increase 2. decrease 3. no effect 4. increase |
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Term
A(g)+B(g)+heat<>2C(g)+D(g)
increases, decreases, or has no effect on product?
1. decreasing [A] 2. increasing [B] 3. Decreasing volume |
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Definition
1. decrease 2. increase 3. decrease |
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N2O(g)<>2 NO2(g) dH=14kcal
forward, reverse, or no change
1. Increasing pressure 2. increasing temp 3. increasing volume |
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Definition
1. reverse 2. forward 3. forward |
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Term
N2O(g)<>2 NO2(g) dH=14kcal
forward, reverse, or no change
1. Adding NO2 2. Adding a catalyst 3. Removing NO2 |
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Definition
1. reverse 2. no change 3. forward |
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Term
CH4(g)+2 O2(g)<> CO2(g)+2 H2O(g)+ 100kcal more prods, reactants, or no change 1. [CH4] increase 2. some CO2 and H2O are removed 3. temp decrease 4. pressure increase 5. temp increase |
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Definition
1. products 2. products 3. products 4. no change 5. reactant |
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Term
More reactants or products
N2+3 H2 <> 2 NH3+heat 1. remove NH3 2. decrease pressure 3. add N2 gas 4. increase temp |
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Definition
1. products 2. reactants 3. products 4. reactants |
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More reactants or products
2 SO2 +O2 <> 2 SO3+ heat 1. increase SO2 2. increase temp 3. remove O2 |
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Definition
1. products 2. reactants 3. reactants |
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if CO2 were increased what would happen?
CO2+C+heat<> 2 CO 1. temp 2. CO concentration 3. Pressure 4. volume |
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Definition
1. decrease 2. increase 3. no change 4. no change |
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Term
H2+Cl2<> 2 HCl +heat
forward, reverse, or no change
1. increase H2 2. increase pressure 3. decrease temp 4. remove HCL 5. decrease volume |
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Definition
1. Forward 2. no change 3. Forward 4. Forward 5. no change |
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