Term
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Definition
| Simmons Smith (alkene->Carbene) |
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Term
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Definition
| Ozonolysis (alkene-> aldehyde) |
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Term
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Definition
| Oxidative Cleavage (Alkene-> carboxylic acids) |
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Term
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Definition
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Term
OsO4 NaIO4
THF or tBuOH
when using KMnO4: |
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Definition
Periodate cleavage (alkene to ald/ketone)
KMno4= carboxyic acids |
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Term
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Definition
| Hydration of Alkynes (alkyne to carboxylic acid or ketone) |
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Term
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Definition
Allylic or Benzylic Bromination
(addition of bromine to allylic or benzylic carbon) |
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Term
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Definition
Hydration of Alkynes
(alkyne to Aldehyde) |
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Term
1.) Hg(OAc)2, H20
2.) NaBH4 |
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Definition
oxymercuration reduction
(alkene to OH on markovnikov carbon) |
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Term
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Definition
Hydroboration oxidation
(alkene to OH on antimarkovnikov carbon) |
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Term
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Definition
Carbene formation
(alkene to carbene) |
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Term
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Definition
Wolff Kishner RXN
Ketone taken off |
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Term
1. CH3-NH2, H+, -H2O
2. NaBH4/MeOH |
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Definition
Reductive amination
(Ketone->Imine-> Amine) |
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Term
Starting w/ Benzene:
1.) HNO3
2.) SNCl2/HCL MeOH
3.) NaNO2/H2SO4 |
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Definition
formation of diazonium ion
N triple bond N good LG |
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
Diazonium +
phenol and NaOH |
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Definition
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Term
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Definition
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Term
Diazonium +
H20, 100 C OR Cu2O, Cu(NO3)2 |
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Definition
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Term
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Definition
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Term
| t-butyl benzene + H2CrO4, H2SO4/H2O, heat |
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Definition
side chain oxidation
(benzene disapears, carboxylic acid w/t-butyl on it) |
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Term
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Definition
Jones Oxidation
secondary alcohol to Ketone |
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Term
1.DMSO, (COCl)2 CH2Cl2 -60
2.Et3N -20 |
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Definition
Swern Oxidation
primary alcohol to aldehyde |
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Term
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Definition
| Primary alchol to aldehyde |
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Term
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Definition
| product of kinetic enolate |
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Term
| Ph3P=CHCH2Ch3 +aldehyde or ketone |
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Definition
| wittig (carbonyl to alkene) |
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Term
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Definition
Emmons-horner reaction
(carbonyl to alkene) |
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Term
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Definition
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Term
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Definition
| cyanohydrin protecting group |
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Term
| ketone + HONH3CL, py or NaOAC |
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Definition
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Term
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Definition
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Definition
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