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Chem 131 Exam 1
Orgo 3
18
Organic Chemistry
Undergraduate 2
01/26/2011
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Term
[image]
 Definition
Toluene
Term
[image]
 Definition
Phenol
Term
[image]
 Definition
Benzaldehyde
Term
[image]
 Definition
Benzoic
Term
[image]
 Definition
Aniline
Term
[image]
 Definition
Nitrobenzene
Term
[image]
 Definition
Hydroquinone
Term
[image]
 Definition
Catechol
Term
Bromination
 Definition
Br2, FeBr3
Term
Nitration
 Definition
HNO3, H2SO4
Term
Sulfination
 Definition
H2SO4, SO3 (reverse with dilute H2SO4)
Term
Reduction of acylation
 Definition
Zn(Hg) and HCl
Term
acylation to amine
 Definition
NH3 and cat H+ then LiAlH4
Term
Nitrobenzene to Aniline
 Definition
H2/Ni
Term
aniline to nitrobenzene
 Definition
CF3--(=O)--O--OH
Term
Diazonium ion
 Definition
Get aniline, then HONO and H2SO4
Term
Phenol
 Definition
1. take bezene with a halide, add in your OH- and heat, this will make benzyne, then add OH- and H2O

2. Take diazonium ion and add H2O

3. Take benzene with a halide and a withdrawing group as well, add OH-, H2O and heat (you'll get phenol with that initial withdrawing group)
Term
Claisen Recombination
 Definition
Heat and Water
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