Term
What are the states of matter? |
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Definition
Gas(g),Liquid(l),Solid(s) |
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What are the properties of the Gas state(g)? |
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Definition
Indefinite shape
Indefinite volume
Particles widely seperated
Particles moving rapidly |
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What are the properties of the Liquid state(l)? |
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Definition
indefinte shape
fixed volume
particles in close contact
particles can move past one another |
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What are the properties of the Solid state(s)? |
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Definition
fixed shape
fixed volume
particles in close contact
particles vibrate around a central position |
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Term
What is the kenetic theory of gases? |
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Definition
Theory that a gas contains small particles in constant random motion that have no attractive or repulsive forces between them or the walls of the container, are very far apart from each other with a very small negligible total volume compared to the container it occupys,
and has an average kinetic energy proportional to absolute temperature |
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Term
How does kinetic molecular theory of gases explain why gases have low density? |
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Definition
since gases are spread out and have little mass per unit of volume causes them to have a low density |
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Term
How does kinetic molecular theory of gases explain why gases are highly compressible? |
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Definition
since total gas volume is small and the particles are far apart, the container volume can be reduced considerably and still leave space between the gas particles |
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Term
How does kinetic molecular theory of gases explain why gases have no definite shape or volume? |
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Definition
because gases are in constant, random motion and therefore reach all parts of any container they are in |
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Term
How does kinetic molecular theory of gases explain why gases diffuse? |
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Definition
since gas particles are in constant,random motion. if the container is opened the gas particles move out into the surrondings |
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Term
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Definition
spontaneous movement from a region of high partial pressure to a region of low partial pressure. |
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Term
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Definition
Force exerted per unit of area |
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Term
What is the equation for pressure? |
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Definition
P(Pressure)=F(Force)
A(Area)
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Term
What is the equation for Kinetic Energy? |
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Definition
KE(Kinetic Energy)=1/2M(mass)*V2(velocity) |
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Term
What is the average KE(Kinetic Energy) proportional to? |
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Definition
AVG KE is directly proportional to T(Temperature) |
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Term
How does the Kinetic Moleculat Theory of Gases explain why gases never settle? |
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Definition
since there is no attraction or repulsion between gas particles no net energy is lost when particles come in contact with each other or the container. this also explains why the travel in straight lines between collisions. |
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Term
1 atm(atmosphere)=How many Torr, and mmHG? |
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Definition
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Term
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Definition
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Term
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Definition
Device used to measeure atmospheric pressure |
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Term
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Definition
A device used to measure gas pressure inside a reaction vessel |
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Term
What is Boyle's Law(Pressure-Volume Law)? |
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Definition
at a constant amount of gas at a constant temperature
V(Volume) is inversely related to P(Pressure) |
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Term
What is the Pressure-Volume Law equation? |
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Definition
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Term
What is Charles's Law(Volume-Temperature Law)? |
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Definition
For a fixed (constant) amount of gas at a constant pressure
T(Temperature) is directly proportional to V(Volume) |
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Term
What is the Volume-Temperature Law equation? |
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Definition
V1/T1=V2/T2
Temperature must be in Kelvin
K=°C+273
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Term
What is the Combined Gas Law equation? |
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Definition
P1V1/T1=P2V2/T2
Moles stay constant and Temperature in K(Kelvin) |
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Term
What is Avogadro's Hypothesis? |
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Definition
When two gases are at the same temperature and pressure then equal volumes of the gases will contain equal number of particles(moles) |
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Term
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Definition
Standard temperature and Pressure
Standard temp= 0°C or 273K
Standard Pressure= 1 atm or 760 torr
At STP the volume occupied by 1 mol of any gas is 22.4L
22.4L/mol is the standard molar volume of a gas |
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Term
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Definition
a gas that obeys all the gas laws under all conditions |
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Term
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Definition
a gas that deviates from ideal behavior at high pressures and low temperatures |
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Term
What is the Ideal Gas Law equation? |
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Definition
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Term
What is the equation for molar mass? |
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Definition
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Term
What is partial pressure? |
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Definition
The pressure a gas in a mixture would exert if it were the only gas in the container. |
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Term
What is Dalton's Law of Partial Pressure? |
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Definition
The total pressure of a mixture of gases is equal to the sum of the partial pressures of all gases in the mixture |
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Term
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Definition
the partial pressure of the gas phase(vapor) of a substance over a sample of the liquid phase of the substance at equilibrium |
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Term
What is mole fraction(X)? |
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Definition
the moles of a substance in a mixture compared to the total moles in the mixture.
Can be expressed
XA= nA = PA
nT PT |
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Term
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Definition
diffusion through a small hole. |
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Term
What is Graham's Law of Effusion? |
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Definition
the rate of effusion of a gas is inversely proportional to the square root of the density of the gas.
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Term
Heavier gases effuse more what? |
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Definition
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Term
Lighter gases effuse more what? |
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Definition
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Term
Effusion rate is also proportional to? |
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Definition
1/Square root of molar mass |
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Term
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Definition
the study of the energy changes that occur in chemical reactions |
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Term
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Definition
The study of heat, work, and energy in general and its transformations. |
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Term
What is the definition of exothermic? |
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Definition
Chemical reactions that produce heat |
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Term
What is the definition of endothermic? |
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Definition
Chemical reactions that absorb heat |
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Term
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Definition
The capacity to do work or transfer heat |
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Term
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Definition
The energy of motion.
KE=1/2m(mass)V2(velocity) |
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Term
What is potential energy? |
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Definition
Stored energy related to an objects position or composition |
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Term
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Definition
energy used to change the motion of an object? |
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Term
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Definition
Energy transferred from a hotter object to a cooler one |
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Term
What is temperature proportional to? |
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Definition
heat but is not the same as heat energy.
EX: Bucket of warm water has more heat energy than a match because it has more mass |
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Term
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Definition
Object, reaction, or process you are studying. |
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Term
What are the surrondings? |
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Definition
Everything else outiside a system |
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Term
What is the first law of thermodynamics? |
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Definition
Energy cannot be created or destroyed it can only move from one place to another or transform into another form of energy |
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Term
What is the internal energy equation? |
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Definition
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Term
Heat and work energy flowing into the system is what? |
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Definition
a positive quantitity in respect to the system |
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Term
Heat and work energy flowing out of the system is what? |
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Definition
A negative quantity in respect to the system |
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Term
What is the PV work function? |
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Definition
w=-P(pressure)ΔV(change in volume) |
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Term
What is a state function? |
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Definition
any quantity whose value is independent of the pathway taken to get that quantity |
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Term
Are heat and work state functions? |
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Definition
No because their values depend on how the system loses heat or does work. |
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Term
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Definition
The internal energy(E) plus Pressure X Volume
H=E+PV |
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Term
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Definition
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Term
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Definition
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Term
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Definition
Measuring of heat flows for processes |
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Term
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Definition
the amount of heat needed to raise the temperature of a substance or object by one degree celsius or one kelvin unit |
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Term
What is molar heat capacity? |
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Definition
the amount of heat needed to raise the temperature of one mole by one degree celsius or one kelvin unit |
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Term
What is specific heat capacity? |
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Definition
the amount of heat needed to raise the temperature of one gram of substance by one degree celsius or one kelvin unit |
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Term
What is the calorimetry equation? |
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Definition
q= m(mass)X Cs(specific heat)X ΔT(Change in Temperature) |
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Term
What is heat or enthalpy of fusion? |
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Definition
The energy needed to melt a substance |
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Term
What is heat or ethalpy of vaporization? |
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Definition
the energy needed to vaporize a substance |
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Term
What is the heat equations for the flat segments on a Heating and Cooling Curve? |
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Definition
q=ΔHfus X moles
q=ΔHvap X moles |
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Term
What is the heat equations for the slope segments on a Heating and Cooling Curves? |
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Definition
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Term
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Definition
Spontaneous change from liquid to gas at any temperature |
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Term
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Definition
Rapid formation of gas bubbles within a liquid |
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Term
What is the boiling point? |
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Definition
point at which the liquid and gas states are at equlibrium. |
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Term
What is the normal boiling point? |
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Definition
temperature at which liquid and gas are at equlibrium at 1 atm of pressure |
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Term
What is the normal melting point? |
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Definition
Temperature in which solid and liquid states are at equilibrium under 1 atm of pressure. |
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Term
What is the triple point? |
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Definition
temperature and pressure at which gas, liquid, and solid phases of a substance are all at equilibrium. |
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Term
What is the critical point? |
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Definition
temperature and pressure above which the distinction between gas and liquid dissapears. |
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Term
What is the critical temperature? |
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Definition
temperature above which a substance can no longer exist as a liquid regardless of any external pressure |
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Term
What is the critical pressure? |
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Definition
external pressure needed to keep a substance in the liquid state at the critical temperature |
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Term
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Definition
phase transition of a solid directly to a gas |
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Term
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Definition
Phase transition of a gas directly to a solid |
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Term
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Definition
Phase transition of a gas to a liquid |
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