Term
|
Definition
Force exerted per unit area by gas molecules as they strike the surfaces around them. |
|
|
Term
|
Definition
Pa or Pascal (1 N/m2) = 101, 325
Pounds per square inch or psi = 14.7
Torr (1 mmHg) = 760
Inches of Mercury or in Hg = 29.2
Atmosphere or atm = 1 |
|
|
Term
What tool can be used to measure the pressure of a gas sample in lab? |
|
Definition
|
|
Term
4 basic properties of a gas sample |
|
Definition
Pressure (P)
Volume (V)
Temperature (T)
Moles (m) |
|
|
Term
|
Definition
An increase in volume or pressure results in a decrease of the opposite.
Constant: Temp. & moles
P1V1=P2V2 |
|
|
Term
|
Definition
The volume of a gas increases with increasing temperature.
Constant: P & n
V1/T1=V2/T2
|
|
|
Term
|
Definition
When gas in a sample increases at constant temperature and pressure, its volume increases in direct proportion because the greater # of gas particles fill more space.
Constant: T & P
V1/n1=V2/n2 |
|
|
Term
|
Definition
The volume of gas is inversely proportional to the pressure of the gas.
P = atm
V = L
Moles = mol
Temperature = K |
|
|
Term
|
Definition
Volume occupied by one mole of a substance. |
|
|
Term
|
Definition
Standard Temperature = 273 degrees
Standard Pressure = 1 atm
Standard Rate = 0.0821
Standard Volume = 22.4 L |
|
|
Term
Density of gas under standard conditions: |
|
Definition
molar mass / molar volume |
|
|
Term
Density of gas is directly proportional to: |
|
Definition
molar mass.
The greater the molar mass, the more dense the gas.
Density (d = PM / RT) |
|
|
Term
|
Definition
Nitrogen (N2) = 78%
Oxygen (O2) = 21%
Argon (Ar) = 0.9%
Carbon Dioxide (CO2) = 0.04% |
|
|
Term
|
Definition
(Pn)
Pressure due to any individual component in a gas mixture.
The sum of the partial pressure of the components in a gas mixture must equal the total pressure. (Ptotal) |
|
|
Term
|
Definition
Xa = na / ntotal
number of moles of a component in a mixture divided by the total number of moles in the mixture |
|
|
Term
|
Definition
Physiological condition developed due to low oxygen levels. |
|
|
Term
|
Definition
Partial pressure of water in the mixture |
|
|
Term
|
Definition
1.) The size of a particle is negligibly small.
2.) The average kinetic energy of a particle is proportional to the temp. in kelvins.
3.) The collision of one particle with another is completely elastic |
|
|
Term
Boyle's Law
Kinetic Molecular Theory |
|
Definition
If you decrease the volume of a gas, you force the gas particles to occupy a smaller space. Temp. remains same, number of collisions increases, resulting in greater pressure. |
|
|
Term
Charles's Law
Kinetic Molecular Theory |
|
Definition
When you increase the temp. of a gas, the average speed and the average kinetic energy of the particles increases. Since greater kinetic energy results in more frequent collisions and more force per collision, the pressure of the gas increase if its volume is held constant. The only way for pressure to remain constant is for volume to increase. |
|
|
Term
Avogadro's Law
Kinetic Molecular Theory
|
|
Definition
When you increase the number of particles in a gas sample, the number of collisions with the surrounding surfaces increases. The greater number of collisions results in a greater overall force on surrounding surfaces. The only way for pressure to remain constant is for the volume to increase. |
|
|
Term
Dalton's Law
Kinetic Molecular Theory |
|
Definition
The particles have negligible size and they do not interact. Particles of different masses have the same average kinetic energy at a given temperature, so they exert the same force upon collision with a surface. |
|
|
Term
|
Definition
The average distance that a molecule travels between collisions. |
|
|
Term
|
Definition
The process by which gas molecules spread out in response to a concentration gradient. |
|
|
Term
|
Definition
Process by which gas escapes from a container into a vacuum through a small hole. |
|
|
Term
|
Definition
The study of relationships between chemistry and energy |
|
|
Term
|
Definition
|
|
Term
|
Definition
The result of a force acting through a distance. |
|
|
Term
|
Definition
The energy associated with the motion of an object. |
|
|
Term
|
Definition
The energy associated with the temperature of an object |
|
|
Term
|
Definition
The energy associated with the position or composition of an object. |
|
|
Term
|
Definition
The energy associated with the relative positions of electrons and nuclei in atoms and molecules.
Also a form of potential energy. |
|
|
Term
Law of Conservation of Energy |
|
Definition
Energy can be neither created nor destroyed. However energy can be transferred from one object to another and can assume different forms. |
|
|
Term
A good way to understand and track energy changes: |
|
Definition
|
|
Term
|
Definition
Everything with which the system can exchange energy. |
|
|
Term
Energy Conversion Factors |
|
Definition
1 calorie (cal) = 4.184 J
1 Calorie (Cal or kcal) = 4184 J
1 kilowatt-hour (kWh) = 3.60x106 J |
|
|
Term
|
Definition
The sum of the kinetic and potential energies of all of the particles that compose the system. |
|
|
Term
|
Definition
Value depends only on the state of the system, not on how the system arrived at that state. |
|
|
Term
|
Definition
-If the reactants have a higher internal energy than the products, deltaEsys is negative and energy flows out of the system into the surroundings.
-If the reactants have a lower internal energy than the products, deltaEsys is positive and energy flows into the system from the surroundings. |
|
|
Term
|
Definition
The heat transfer from an object to the surroundings stops when the two reach the same temperature. |
|
|
Term
Heat capacity is an extensive property because: |
|
Definition
1.) It's dependent on the amount of matter being heated.
2.) Water is more resistant to temperature change than steel. |
|
|
Term
|
Definition
The measure of the intrinsic capacity of a substance to absorb heat. |
|
|
Term
|
Definition
The amount of heat required to raise the temperature of 1 mole of a substance by 1 degree Celsius. |
|
|
Term
|
Definition
Occurs when the force is caused by a volume change against an external pressure. |
|
|
Term
|
Definition
A piece of equipment designed to measure deltaE for combustion reactions. |
|
|
Term
|
Definition
The sum of its internal energy and the product of its pressure and volume. |
|
|
Term
|
Definition
A chemical reaction with a positive deltaH that absorbs heat from its surroundings. |
|
|
Term
Enthalpy of Reaction or Heat Reaction |
|
Definition
deltaHrxn
Extensive Property |
|
|
Term
Relationships Involving deltaHrxn |
|
Definition
1.) If a chemical equation is multiplied by some factor, then deltaHrxn is also multiplied by the same factor.
2.) If a chemical equation is reversed, then deltaHrxn changes sign.
3.) If a chemical equation can be expressed as the sum of a series of steps, then deltaHrxn for the overall equation is the sum of the heats of reactions for each step. |
|
|