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Chapter 9
chapter 9 notecards for Chem 1303
20
Chemistry
Undergraduate 1
11/09/2014

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Term
Lewis structure
Definition
a representation of covalent bonding in which shared electron pairs are shown either as lines or as pairs of dots between two atoms, and lone pairs are shown as pairs of dots on individual atoms. Only valence electrons are shown in a Lewis structure.
Term
octet rule
Definition
An atom other than hydrogen tends to form bonds until it is surrounded by eight valence electrons.
Term
single bond
Definition
two atoms are held together by one electron pair
Term
multiple bonds
Definition
two atoms share two or more pairs of electrons
Term
double bonds
Definition
two atoms share two pairs of electrons
Term
triple bond
Definition
two atoms share three pairs of electrons
Term
bond length
Definition
the distance between the nuclei of two covalently bonded atoms in a molecule
Term
Polar covalent bond/polar bond
Definition
a covalent bond in which the electrons spend more time in the vicinity of one atom than the other
Term
electronegativity
Definition
the ability of an atom to attract toward itself the electrons in a chemical bond
Term
Formal Charge
Definition
the electrical charge difference between the valence electrons in an isolated atom and the number of electrons assigned to that atom in a Lewis structure
Term
resonance
Definition
the use of two or more Lewis structures to represent a particular molecule
Term
coordinate covalent bond
(A.K.A. dative bond)
Definition
a covalent bond in which one of the atoms donates both electrons
Term
bond enthalpy
Definition
the enthalpy change required to break a particular bond in 1 mole of gaseous molecules
Term
covalent bond
Definition
bond in which two electrons are shared by two atoms
Term
covalent compounds
Definition
compounds that contain only covalent bonds
Term
Born-Haber cycle
Definition
A procedure that relates lattice energies of ionic compounds to ionization energies, electron affinities, and other atomic and molecular properties. (based on Hess's law)
Term
lattice energy
Definition
a quantitative measure of the stability of any ionic solid is its _______, defined as the energy required to completely separate one mole of a solid ionic compound into gaseous ions.
Term
Coulomb's law
Definition
A law that states that the potential energy (E) between two ions is directly proportional to the product of their charges and inversely proportional to the distance of separation between them.
Term
ionic bond
Definition
the electrostatic force that holds ions together in an ionic compound
Term
Lewis dot symbol
Definition
consists of the symbol of an element and one dot for each valence electron in an atom of the element
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