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Chapter 8
covalent bonding
51
Chemistry
11th Grade
10/26/2008

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Term
what is monatomic
Definition
noble gases (consist of single atoms)
Term
covalent bond
Definition
a bond formed by the sharing of electrons between atoms
Term
molecule
Definition
a neutral group of atoms joined together by covalent bonds
Term
diatomic molecule
Definition
a molecule consisting of two atoms
Term
molecular compound
Definition
a compound that is composed of molecules Ex) H2O
Term
what are all molecules of a molecular compound
Definition
the same
Term
what are molecular compound melting and boiling points like
Definition
relatively lower
Term
what are molecular compounds at room temperature
Definition
mostly gases or liquids
Term
molecular formula
Definition
a chemical formula of a molecular compound that shows the kinds and numbers of atoms present in a molecule of a compound
Term
why do covalent bonds occur
Definition
so that atoms can attain the octet rule and noble gas VE structure
Term
what groups tend to form covalent bonds?
Definition
4A 5A 6A 7A
Term
what noble gas VE structure does hydrogen gain thourhg covalent bonding
Definition
The VE structure of Helium (2 VEs)
Term
single covalent bond
Definition
a bond formed when two atoms share a pair of electrons
Term
what represents a single covalent bond in a structural formula?
Definition
a -
Term
structural formula
Definition
a chemical formula that shows the arrangement of atoms in a molecule or a polyatomic ion: each dash between a pair of atoms indicates a pair of shared electrons
Term
double covalent bond in a structural formula
Definition
=
Term
unshared pair
Definition
a pair of valence electrons that is not shared between atoms
Term
why can't oxygen form a diatomic molecule?
Definition
experimental evidence says that oxygen has to have unattached electrons because it is magnetic
Term
double covalent bond
Definition
a covalent bond in which two pairs of electrons are shared by two atoms
Term
triple covalent bond
Definition
a covalent bond in which three pairs of electrons are shared by two atoms Ex N2
Term
coordinate covalent bond
Definition
a covalent bond in which one atom contributes both bonding electrons
Term
what represents a coordinate covalent bond in a structural formula?
Definition
an arrow
Term
polyatomic ion
Definition
a tightly bound group of atoms that behaves as a unit and has a positive or negative charge
Term
bond dissociation energy
Definition
the energy required to break the bond between two covalently bonded atoms; this value is usually expressed in kJ per mol of substance
Term
what has a higher bond dissociation energy? a double covalent bond or a triple covalent bond?
Definition
triple bond
Term
oxygen atoms in the ozone are
Definition
a mixture of extremes represented by resonance forms
Term
resonance structure
Definition
one of the two or more equally valid electron dot structures of a molecule or polyatomic ion
Term
when are their exceptions to the octet rule?
Definition
odd number of ve/ less then 8 ve/ more than 8 ve
Term
molecular orbital
Definition
an orbital that applies to the entire molecule
Term
each molecular orbital is full if it contains...
Definition
2 electrons
Term
bonding orbital
Definition
a molecular orbital that can be occupied by two electrons of a covalent bonds
Term
sigma bond
Definition
a bond formed when two atomic orbitals combine to form a molecular orbital that is symmetrical around the axis connecting the two atomic nuclei
Term
sigma bond picture
Definition
oval with two nuclei (two circles, s oribitals, combined)
Term
pi bonds
Definition
a covalent bond in which the bonding electrons are most likely to be found in sausage-shaped regions above and below the bond axis of the bonded atoms
Term
pi bond picture
Definition
two ovals with the two nuclei in between ,two p orbitals (barbells)combined
Term
tetrahedral angle
Definition
a bond angle of 109.5 degrees that results when a central atom forms four bonds directed toward the center of a regular tetrahedron (tripod)
Term
VSEPR theory
Definition
valence –shell electron-pair repulsion theory; because electron pairs repel, molecules adjust their shapes so that valence electron pairs are as far apart as possible
Term
hybridization
Definition
the mixing of several atomic orbitals to form the same total number of equivalent hybrid orbitals
Term
nonpolar covalent bond
Definition
a covalent bond in which the electrons are shared equally by the two atoms
Term
polar covalent bond
Definition
a covalent bond between atoms in which electrons are shared unequally
Term
electronegative atoms in covalent bonds
Definition
attract electrons and gain a slightly negative charge (polar covalent bond)
Term
less electronegative atoms in covalent bonds
Definition
have a slighlty positive charge
Term
polar molecule
Definition
a molecule in which one side of the molecule is slightly negative and the opposite side is slightly positive
Term
dipole
Definition
a molecule that has two poles, or regions, with opposite charges
Term
intermolecular attractions are what compared to ionic and covalent bonds?
Definition
weaker
Term
van der Waal forces
Definition
the two weakest intermolecular attractions-dispersion forces and dipole interactions
Term
dipole interactions
Definition
intermolecular forces resulting from the attraction of oppositely charged regions of polar molecules
Term
dispersion forces
Definition
attractions between molecules caused by the electron motion on one molecule affecting the electron motion on the other through electrical forces; these are the weakest interactions between molecules
Term
hydrogen bonds
Definition
attractive forces in which a hydrogen covalently bonded to a very electronegative atom is also weakly bonded to an unshared electron pair of another electronegative atom
Term
network solid
Definition
a solid in which all of the atoms are covalently bonded to each other
Term
the requirements for melting a network solid
Definition
breaking covalent bonds throughout the solid
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