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a reaction once started that proceeds on its own without external influence |
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what two factors determine if a process will be spontaneous or not |
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energy change or entropy change |
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if a process gives off energy it is considered |
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if a process involves an increase in entropy, it is considered |
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exotheremic and endothermic refer specificall to |
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units used for energy changes |
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energy cannot be (blank) but can be (blank) |
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created or destroyed, converted into another form of energy |
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what two types of energy are often interconverted in chemical reactions |
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what is more probable, an ordered or disordered state |
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do all spontaneous reactions occur at the same rate |
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change in concentration/change in time |
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the steps the molecules go through on the way from reactants to products |
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what two things must be true of molecules for a chemical reaction to take place |
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molecules must collide and have proper orientation |
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collisions must have enough energy to |
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break the bonds that already exist |
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what will happen if the collisions don't have enough energy to break the bonds? |
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they will bounce off one another |
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what four things does heat increase in a chemical reaction |
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energy, speed of molecules, number of collisions and force of collisions |
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does it take enery to break bonds |
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is energy given off when bonds form? |
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there is always an energy barrier to a reaction proceeding as written. What is this called |
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The larger the activation energy the (blank) the rate. |
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The smaller the activation energy, the (blank) the rate |
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Is there any relationship between the activation energy and the energy change for the overall reaction |
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How are two ways an increase in temperature increase the rate of reaction? |
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number of collisions, force of collisions |
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how does an increase in concentration of reactants increase the rate of reaction |
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how would you increase the rate of reaction when using a solid |
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increase the surface area |
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how does a catalyst increase the rate of a reaction? |
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Definition
It provides a new reaction pathway, which has a lower activation energy |
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