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Chapter 7
ionic and metallic bonding
45
Chemistry
11th Grade
10/26/2008

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Term
valence electron
Definition
electron in the highest occupied energy level of an atom
Term
The number of valence electron largely determines...
Definition
the chemical properties of an element
Term
what subatomic particle is used in chemical bonds
Definition
electrons
Term
How do you find the number of valence electrons an element has
Definition
look at it's group number
Term
How many VEs does helium have?
Definition
2 VE
Term
electron dot structure
Definition
a notation that depicts valence electrons as dots around the atomic symbol of the element; the symbol represents the inner electrons and atomic nucleus
Term
what is shown in a electron dot structure?
Definition
Valence electrons
Term
Octet rule
Definition
- atoms react by gaining or losing electrons so as to acquire the stable electron structure of a noble gas, usually eight valence electrons
Term
Who came up with the octet rule?
Definition
1916, Chemist Gilbert Lewis
Term
sublevels in the octet rule
Definition
ns2np6
Term
By following the octet rule what VE structure do the elements form
Definition
The noble gas VE structure
Term
metals (left) tend to
Definition
lose VEs
Term
Nonmetals (left) tend to
Definition
gain electrons from other nonmetals
Term
Cation
Definition
lose electron; metals; positive
Term
anion
Definition
gain electron; mostly nonmetals; negative
Term
halide ion
Definition
negative ion formed when a halogen atom gains an electron
Term
Halogen
Definition
7A
Term
charge of halide ion
Definition
-1
Term
ionic compound
Definition
compounds composed of positive and negative ions
Term
ionic compounds usually contain
Definition
metal cations and nonmetal anions
Term
charge of ionic compounds
Definition
neutral
Term
ionic bond
Definition
the electrostatic attraction that binds oppositely charged ions together
Term
what happens in an ionic bond between sodium and chlorine
Definition
Sodium gives an electron to chlorine so that they both contend to the octet rule
Term
chemical formula
Definition
an expression that indicates the number and type of atoms present in the smallest representative unit of a substance
Term
formula unit
Definition
the lowest whole number ratio of ions in an ionic compound
Term
what are most ionic compounds at room temperature?
Definition
crystalline solids
Term
What at ionic compound melting points like?
Definition
high
Term
why ionic compounds have high melting points
Definition
they are a stable structure and are tightly packed
Term
cooridnation number
Definition
the number of ions of opposite charge that surround each ion in a crystal
Term
what can ionic compounds conduct in water
Definition
electrical currents
Term
when in an electrical current what happens to cations
Definition
move freely to one electrode
Term
anions move towards what in an electric current
Definition
The electrode opposite the elctrode the cations migrated towards
Term
VEs on atoms can be modeled as what?
Definition
a sea of electrons- they are mobile
Term
Why are metals good conductors of electricity
Definition
their electrons move freely
Term
metallic bonds
Definition
the force of attraction that holds metals together; it consists of the attraction of free-floating valence electrons for positively charged metal ions
Term
metal cations move freely past each other so...
Definition
metals are ductile and malleable
Term
why do metal cations (+ and +) movely free past each other?
Definition
drifting VEs insulate them
Term
Metal atoms are arrnaged how?
Definition
compact and orderly patterns
Term
body centered cube has how many atom neighbors?
Definition
8
Term
face centered cubic has how many atom neighbors?
Definition
12
Term
hexagonal closed packed has how many atom neighbors?
Definition
12
Term
alloys
Definition
a mixture composed of two or more elements, at least one of which is a metal
Term
whats good about alloys
Definition
they have more useful properties than metals alone
Term
substitutional alloy
Definition
components in alloy are about the same size and can replace each other in the crystal
Term
interstitial alloy
Definition
components’ atomic sizes are very different; smaller atoms fit into larger spaces
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