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What is potential energy? |
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What are the 4 forms energy can take? |
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1.) mechanical 2.) electric current 3.) heat 4.) light |
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P - bitch at top of slide. K - bitch actually sliding. |
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How is heat energy measured? |
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The amount of heat required to raise the temp of 1 gram of water by 1 degree Celsius |
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1 kilocalorie = 1,000 ________ = 1 _________ (dietary) |
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Energy flows into the biological world from the ________. |
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How do photosynthetic organisms store the energy they receive from the sun? |
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As potential energy in chemical bonds. |
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How can potential energy be transferred? |
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By transferring electrons from one molecule to another. |
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What is oxidation? What is reduction? What is redox? |
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O I Loss
R I Gain
Redox = those two coupled together. |
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What is the first law of thermodynamics? |
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Definition
Energy cannot be created or destroyed. Energy can only be converted from one form to another. Total amount of energy in the universe remains constant. |
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Why are energy transfers inefficient? |
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Energy is "lost" as heat. |
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What is the second law of thermodynamics? |
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Disorder is more likely than order. |
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Disorder in the universe. |
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What does the 2nd law actually mean? |
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Energy transformations proceed spontaneously to convert matter from more ordered (less stable) to less ordered (more stable) form |
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According to the 2nd law of thermodynamics, ________ is always increasing. |
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What is an endergonic reaction? |
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A reaction requiring an input of energy. |
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What is an exergonic reaction? |
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A reaction that releases free energy. |
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If looking at graphs, what does an exo/endo look like? |
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Endergonic has the line going above the zero line signifying energy must be used.
Exergonic has the line going below the zero line signifying that energy has been released. |
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What is activation energy? |
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Definition
Extra energy required to destabilize existing bonds and initiate a chemical reaction. |
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What does an exergonic reaction rate depend on? |
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Definition
The activation energy required. Larger activation energy goes slower vs smaller going faster. |
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How can rate be increased? (2 ways) |
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1.) Increasing energy of reacting molecules (heating) 2.) Lowering the activation energy (catalyst) |
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Substances that influence chemical bonds in a way that lowers activation energy. |
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What does a catalyst NOT do? |
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Definition
1.) Violate laws of thermodynamics - Endergonic rxn cannot be spontaneous 2.) Alter the proportion of reactant turned into product. - Makes rxn faster, does not increase the amount made |
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What is the energy currency of the cell? |
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Definition
ATP. Adenosine triphosphate. |
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What is the structure of ATP? |
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A ribose (5 carbon sugar) Adenine Three phosphates |
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Where is the energy stored in ATP? |
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Definition
The bonds between the three phosphates. |
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Because phosphates are highly negative, what 3 things does this cause? |
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Definition
1.) They repel each other 2.) Much energy is required to bond them to each other 3.) Much energy is released when the bonds are broken between them |
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What does the structure become when ATP is broken down? Is this reaction reversible? |
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What breaks apart the bonds of the phosphate in ATP? |
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Molecules that catalyze reactions in living cells. |
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What are enzymes (mostly) structure-wise? |
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Definition
Most are proteins, some are RNA |
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What is an enzymes function? |
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Definition
Lower the activation energy required for a reaction. |
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Are enzymes changed or consumed by the reaction? |
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What do enzymes interact with? |
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A molecule that will undergo a reaction. |
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Region of the enzyme that binds to the substrate |
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What does the binding of an enzyme to a substrate cause? |
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Definition
The enzyme to change shape, producing a better INDUCED FIT between molecules. |
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Where are enzymes located in the cell? |
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Definition
Suspended in the cytoplasm, attached to the cell membrane, or attached to organelles. |
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What is a multienzyme complex? |
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Subunits work together to form a molecular machine. |
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What are the pro's of a multienzyme complex? |
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Definition
1.) Product can be delivered easily to the next enzyme 2.) Unwanted side reaction can be prevented 3.) All reactions can be controlled as a unit |
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What is an enzyme's effectiveness effected by? |
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Definition
It's environment like concentrations of substrate and enzyme factors that can change an enzymes overall shape. |
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How does temperature effect enzyme activity? |
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Definition
Enzyme activity can be increased by increasing the temperature to optimal level. Too high and they can denature. |
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What pH range to enzymes function best at? |
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Definition
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Substance that binds to an enzyme and decreases its activity. |
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What is a competitive inhibitor? |
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Definition
Competes with the substrate for the active site. |
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What is a noncompetitive inhibitor? |
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Definition
Binds to enzyme at another site other than the active site thus changing the shape which makes the actual enzyme unable to bond. |
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Allosteric enzymes exists in _______ and ________ forms |
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Definition
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What do noncompetitive inhibitors bind to? |
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Definition
Allosteric site which acts as the chemical on/off switch |
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What is an allosteric inhibitor? |
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Definition
Binds to allosteric site and reduces enzyme activity. |
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What is an allosteric activator? |
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Definition
Binds to allosteric site and increases enzyme activity. |
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Usually metal ions, found in the active site participating in catalysis. |
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Nonprotein organic molecule, often used as an electron donor or acceptor in redox reaction |
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Total of all chemical reactions carried out by an organism, |
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What is anabolic vs catabolic? |
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Definition
Ana - Use energy to build up molecules Cat - Harvest energy by breaking down molecules |
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In a biochemical pathway, the ______ of one reaction is the ________ for the next. |
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Definition
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What is feedback inhibition? |
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Definition
End-product pathway binds to an allosteric site on an enzyme that catalyses first reaction in pathway. Shuts it down so raw materials and energy aren't wasted. |
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