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Chapter 6
Chemical bonding
63
Chemistry
11th Grade
11/02/2008

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Term
A mutual electrical attraction between the nuclei and valence electrons of different atoms that binds atoms together
Definition
Chemical Bond
Term
Metals tend to _____ electrons and become _______; Nonmetals tend to _________ electrons and become _______
Definition
Lose/Cations;Gain/Anions
Term
Chemical bonding that results from the electrical attraction between cations and anions;give up electrons to other atoms
Definition
Ionic Bonding
Term
Sharing of electron pairs between two atoms; electrons "owened" equally by bonded atoms
Definition
Covalent Bonding
Term
How do you determine the type of bond?
Definition
The difference in eectronegativity
Term
Bonding between two atoms of the same element is completely _______
Definition
Covalent
Term
Covalent bond in which the bonding electrons are shared equally by the bonded atoms, resulting in balanced distribution of electrical charge
Definition
Nonpolar-covalent bond
Term
Have uneven distribution of charge
Definition
Polar
Term
Covalent bond in which the bonded atoms have unequal attraction for the shared electrons
Definition
Polar-covalent bond
Term
0-.3=_______
.3-1.7=________
1.7-...=__________
Definition
Nonpolar-covalent;polar-covalent;ionic
Term
Neutral group of atoms that are held together by covalent bonds
Definition
Molecule
Term
Chemical compound whose simplest units are molecules
Definition
Molecular Compound
Term
Composition of a compound is given by the __________ ________
Definition
Chemical Formula
Term
Indicates the relative numbers of atoms of each kind in a chemical compound by using atomic symbols and numerical subscripts
Definition
Chemical Formula
Term
Shows the types and numbers of atoms combined in a single molecule of a molecualr compound
Definition
Molecular Formula
Term
Molecule containing only two atoms
Definition
Diatomic Molecule
Term
Potential energy ________ as the attraction gets stronger and _______ as the repulsion gets stronger
Definition
Decreases;Increases
Term
Distance between two bonded atoms
Definition
Bond Length
Term
Energy is ________ when bonded
Definition
Released
Term
The energy required to break a chemical bond and form neutral isolated atoms
Definition
Bond Energy
Term
As length _______ energy _______ and visa versa
Definition
Increases;Decreases
Term
Chemical compounds tend to form so that each atom, by gaining, sharing, or losing electrons has an octet of electrons in its highest energy level
Definition
Octet Rule
Term
Exceptions to the octet rule
Definition
Boron can only have 6 VE;Expanded Valence(More than eight electrons esp. when bonded with F,O, or Cl)
Term
An electron-configuration notation in which only the valence electrons of an atom of a particular element are shown, indicated by dots placed around the element's symbol
Definition
Electron-dot notation
Term
Pair of electrons that is not involved in bonding and that belongs exclusively to one atom
Definition
Unshared(Lone) pair
Term
Formulas in which atomic symbols represent nuclei and inner-shell electrons, dot pairs or dashes between two atomic symbols represent electron pairs in a covalent bonds, and dots adjacent to only one atomic symbol represent unshared electrons
Definition
Lewis Structures
Term
A covalent bond in which one pair of electrons is shared between two atoms
Definition
Single Bond
Term
Covalent bond in which two pairs of electrons are shared between two atoms, esp. C,N,O
Definition
Double Bond
Term
Covalent bond in which three pairs of electrons are shared between two atoms
Definition
Triple Bond
Term
________ get shorter
Definition
Stronger
Term
Bonding in molecules or ions that cannnot be correctly represented by a single lewis structure
Definition
Resonance
Term
Composed of positive and negative ions that are combined so that the numbers of positive and negative charges are equal
Definition
Ionic Compound
Term
Simplest collection of atoms from which an ionic compound's formula can be established
Definition
Formula unit
Term
Ratio of ions in a compound depend on the _______ of the ions combined
Definition
Charges
Term
Orderly arrangement in which ions are combined to minimize potential energy
Definition
Crystal Lattice
Term
The energy released when one mole of an ionic crystalline compound is formed from gaseous ions
Definition
Lattice Energy
Term
Bond between molecules determine _______/_________ and ________ (Stronger equals ______)
Definition
Melting point/boiling point and hardness;Higher
Term
Ionic compounds are ______ but ________
Definition
Hard but Brittle
Term
Ionic compounds are only conductors in _________ state or in ________
Definition
Molten/Water
Term
What two things are required for conductors
Definition
Ions and movability
Term
A charged group of covalently bonded atoms
Definition
Polyatomic ions(have characteristics of Molecular and ionic)...for lewis structures, if pos, subtract....if neg add
Term
Do not belong to any one atom but move freely about the metal's empty atomic orbitals
Definition
Delocalized
Term
The chemical bonding that results from the attraction between metal atoms and the surrounding sea of electrons
Definition
Metallic Bonding
Term
Properties of metals(4)
Definition
Good thermal/electrical conductors;Strong absorbers/reflectors of light
Term
Ability of a substance to be hammered into thin sheets
Definition
Malleability
Term
Ability of a substance to be drawn through a small opening to produce wire
Definition
Ductility
Term
The amount of energy absorbed as heat when a specified amount of a substance vaporizes at constant pressure
Definition
Enthalpy(heat) of vaporization
Term
5 bond sites 5 bonds
Definition
triginal bipyramidal
Term
5 bond sites 4 bonds
Definition
seesaw
Term
5 bond sites 3 bonds
Definition
T shape
Term
5 bond sites 2 bonds
Definition
linear
Term
6 bond sites 6 bonds
Definition
octahedral
Term
6 bond sites 5 bonds
Definition
square base pyramid
Term
6 bond sites 4 bonds
Definition
square planar
Term
3 bond sites 3 bonds
Definition
triginal planar
Term
4 bond sites 4 bonds
Definition
tetrahedral
Term
4 bond sites 3 bonds
Definition
triginal pyramidal
Term
4 bond sites 2 bonds
Definition
bent
Term
2 bond sites 2 bonds
Definition
linear
Term
VSEPR stands for...
Definition
Valance shell electron pair repulsion
Term
states that repulsion between the sets of valance electrons surrounding an atom causes these sets to be oriented as far apart as possible
Definition
VSEPR theory
Term
The mixing of two or more atomic orbitals of similar energies on the same atom to produce new hybrid atomic orbitals of equal energy
Definition
hybridization
Term
Intermolecular forces
Definition
Dipole-dipole;Hydrogen;London dispersion forces
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