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The state of a substance depends on what two factors |
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what four properties are commonly used to distinguish substances? |
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density, shape, compressibility, thermal compression |
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the mass of a sample of matter divided by the volume of the same sample |
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sometimes dependant on container and sometimes not, depending on the state of matter |
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the chamge in volume resulting from a pressure change |
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the change in volume resulting from temperature changes |
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how does a thermometer work? |
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thermal expansion-as the temp of the liquid increases, it expands and fills more of the fine capillary tube on with the temp scale is engraved. |
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compressibility of a solid |
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thermal expansion of a solid |
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high-usually lower than the corresponding solid |
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compressibility of a liquid |
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small-usually higher than that of the corresponding solid |
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thermal expansion of a liquid |
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thermal expansion of a gas |
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the kinetic molecular theory of matter is used to explain |
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the behavior of matter in its various states |
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first postulate of the KMT |
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matter is composed of tiny particles called molecules |
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second postulate of the KMT |
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the particles are in constant motion and therefore possess kinetic energy |
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third postulate of the KMT |
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the particles possess potential energy as a result of attracting or repelling each other |
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fourth postulate of the KMT |
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the average particle speed increases ass the temperature increases |
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fifth posulate of the KMT |
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the particles tansfer energy to each other during collisions in which no net energy is lost from the system |
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What makes a substance a solid liquid or gas |
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itdepends on the strength of attractive foreces active between atoms. |
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what unit is used for the volume of a solid |
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what unit will be used for volume of a gas? |
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unit for volume of a liquid? |
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exact density is dependant on |
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formula for kinetic energy |
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one half times mass times velocity squared |
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energy can be transformed from one type to another but cannot |
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heat, light, chemical, electrical, mechanical, nuclear |
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Kinetic molecular theory of gases (1) |
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consists of many particles (atoms or molecule) motion is random no attractive forces |
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kinetic molecular theory of gases (2) |
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space betweeen particles very large compared to size of particles |
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Kinetic molecular theory of gases (3) |
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kinetic energy of average particle proportional to temperature in kelvins |
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kinetic molecular theory of gases (4) |
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energy total after collsions results in NO loss of kinetic energy |
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kinetic molecular theory of gases is based on the assumpts for |
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Three factors that are involved (when amount of gas is kept constant) |
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pressure, volume, temperature (kelvins) |
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when doing experiments you want to have only a single |
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the result of collisions of particles with sides of containers |
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the more frequent and stronger the collisions of particles |
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pressure per unit area (pounds per square inch) |
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Conversion factor from atm to mmHg |
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conversion factor from psi to atm |
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conversion factors from atm to torr |
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conversion factor atm to bars |
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conversion factor from kPal to atm |
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is temperature the same thing as heat? |
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temperature can tell you the direction of |
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what happens at absolute zero? |
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all motion stops...particles have NO kinetic energy |
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water freezing and boiling point (F) |
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water freezing and boiling point in celsius |
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water freezing and boiling point in kelvins |
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boyles law involves the relationship between |
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Charles law involves the relationship between |
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the higher the temperature |
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in charles law, what is constant |
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law of gay-lussac involves the relationship between |
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work when the amount of gas is fixed and the conditions are changed. |
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avogadros law involves the relationship between |
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when pressure and temperature are constant |
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volume of a gas is directly proprtional to number of moles of gas |
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standard temperature and pressure zero degrees C (273.15k) and 1 atm (760 mmHg) |
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0.0821 L atm/mol k universal gas constant |
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total and partial pressure |
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partial pressures of individual components are additive because |
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the particles do not interact |
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grahams law is the relationship between |
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diffusion rate and molecular weight |
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heat taken in (melting, boiling, sublimation) |
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heat given off (freezing, condesation, deposition) |
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describe the position and relationship of particles in liquid |
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they are in constant motion but are constantly in contact with other molecules |
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when particles have enough energy |
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molecules can break free of others and go from the liquid to gas phase (overcome intermolecular forces) |
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the gas molecules in equilibrium with a liquid |
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in evaporation, the molecules disperse because |
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there is no closed container |
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the partial pressure of gas molecules in equilibrium with the liquid |
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vapor pressure is dependant on what two factors? |
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identity of the liquid and teh temperature |
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is vapor pressure a physical or chemical property? |
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what is the relationship between vapor pressure and intermolecular forces operating |
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they are inversly related |
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the stronger the intermolecular forces the (blank) the vapor pressure |
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what happens when vapor pressure equals atmospheric pressure what happens? |
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the boiling point is dependant on |
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temperature at which a solid changes to a liquid |
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solid changes directly into a gas withour going through the liquid phase |
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problems involving temperature chage but no phase change need to take what into account? |
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amounf of heat it takes to raise the temperature of 1 gram of a substance one degree |
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specific heat times mass times temp change |
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units used for specific heat |
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joules per gram degrees celcius or calories per gram degrees celcius |
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which has a higher specific heat, water or metal |
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quantity of head required to completely melt a substance once it has reached its melting point |
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quantity of heat needed to vaporize a liquid once it has reached its boiling point |
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when a substance is melting or boiling, the temperature |
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when doing change of state problems, each step will be one of two teypes of problems: |
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specific heat or phase change |
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partial pressures of individual components are additive because |
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the particles do not interact |
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