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Chapter 4
Carbon and the Molecular Diversity of Life
22
Biology
Undergraduate 1
01/25/2012

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Cards

Term
elements that make up living organisms
Definition
H, O, N, S, P, & C
Term

organic chemistry

 

organic/inorganic compounds

Definition

branch of chemistry that specializes in the study of carbon compounds

 

organic= those arising in living organisms

inorganic= found only in the nonliving world

 

Term
vitalism theory
Definition
belief in a life force outside the jurisdiction of physical and chemical laws
Term
mechanism theory
Definition
view that physical and chemical laws govern all natural phenomena, including the processes of life
Term
tetravalence
Definition
can branch out in 4 diff directions showing its versatility that makes large, complex molecules possible...Carbon exhibits this
Term
methane
Definition
CH4
Term
ethane
Definition
C2H6
Term
ethene
Definition
C2H4
Term
hydrocarbons
Definition
oranic molecules consisting of only carbon and hydrogen
Term
isomers
Definition
compounds that have the same number of atoms of the same elements but diff structures and hence diff properties
Term
structural isomers
Definition
differ in the covalent arrangements of their atoms
Term

geometric isomers

 

Cis/ trans isomers

Definition

have same covalent partnerships, but they differ in their spatial arrangements

 

cis= both X's on the same side of the double bond

trans= X's on opposite sides of the double bond

Term
enantiomers
Definition
isomers that are mirror images of each other
Term
functional groups (7 main one's)
Definition
the chemical groups that affect molecular function by being directly involved in chemical reactions
Term
Hydroxyl
Definition

(-OH) alcohols: name ends in -ol

 

-is polar as a result of the electrons spending more time near the electronegative oxygen atom

-can form hydrogen bonds with wawter molecules, helping dissolve organic compounds such as sugars

Term
Carbonyl
Definition

(>C=O) ketones: if w/in carbon skeleton; aldehydes: if at end of carbon skeleton

 

-a ketone and an aldehyde may be structural isomers w/ diff properties

-these two groups are also found in sugars, giving rise to ketoses and aldoses

Term
Carboxyl
Definition

(-COOH; -C<=O,-OH) carboxylic acids

 

-has acidic properties (is a source of hydrogen ions) b/c the covalent bond btwn oxygen and hydrogen is so polar

-found in cells in the ionized form with a charge of 1- and called a carboxylate ion

Term
Amino
Definition

(-NH2) amines

 

-acts as a base; can pick up H+ from the surrounding solution

-ionized with a charge of 1+, under cellular conditions

Term
Sulfhydryl
Definition

(-SH/-HS) Thiols

 

-two sulfhydryl groups can react, forming a covalent bond; this "cross-linking" helps stabilize protein structure

-"cross-linking" of cysteines in hair proteins maintains the curliness/ straightness of hair

Term
Phosphate
Definition

(-OPO32-) organic phosphates 


-contributes negative charge to the molecule of which it is a part 

-has the potential to react with water, releasing energy

Term
Methyl
Definition

(-CH3) methylated compounds

 

-addition of a methyl group to DNA, or to molecules bound to DNA, affects expression of genes

-arrangement of methyl groups in male + female sex hormones affects their shape and function

Term
adenosine triphosphate
Definition

ATP: complicated organic phosphate that stores energy; aka storing the potential to react with water

 

-3 phosphates joined to adenosine

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