Term
|
Definition
One reactant loses electrons. |
|
|
Term
|
Definition
Other reactant gains electrons. |
|
|
Term
What does a Voltaic Cell (galvanic) do? |
|
Definition
|
|
Term
What does a Electrolytic Cell do? |
|
Definition
Load that is powered by energy |
|
|
Term
A | B || C | D phase of lower oxidation state | phase of Higher oxidation state || phase of higher oxidation state | phase of Lower oxidation state
Oxidation Half cell on right then Reduction Hall cell on left |
|
Definition
Notation of a Voltaic Cell |
|
|
Term
The standard cell potential is the difference between the standard potential of the cathode (reduction) half-cell and the standard potential of the anode (oxidation) half-cell. |
|
Definition
E°cell = E°cathode - E°anode |
|
|
Term
Writing Spontaneous Redox Reactions |
|
Definition
Stronger Reducing Agent + Stronger Oxidizing Agent <==> Weaker Oxidizing Agent + Weaker Reducing Agent |
|
|
Term
Formula to calculate the total charge of E0Cell |
|
Definition
|
|
Term
The interrelationship of DG0, E0, and K. |
|
Definition
|
|
Term
The Effect of Concentration on Cell Potential |
|
Definition
When Q < 1 and thus [reactant] > [product], lnQ < 0, so Ecell > E0cell When Q = 1 and thus [reactant] = [product], lnQ = 0, so Ecell = E0cell When Q >1 and thus [reactant] < [product], lnQ > 0, so Ecell < E0cell
Ecell = E0cell - .0592/n *log Q |
|
|
Term
|
Definition
A primary battery cannot be recharged, it is discarded when the components have reached their equilibrium concentrations |
|
|
Term
|
Definition
A secondary battery is recharged when it runs down by supplying electrical energy to reverse the cell reaction. |
|
|
Term
Properties and Differences of Voltaic and Electrolytic Cells |
|
Definition
Delta G's Opposite Delta E's Opposite Signs (charges) Opposite |
|
|
Term
|
Definition
|
|