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Chapter 21
Electrochemistry: Chemical Change and Electrical Work
14
Chemistry
Undergraduate 1
05/15/2010

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Term
OXIDATION
Definition
One reactant loses electrons.
Term
REDUCTION
Definition
Other reactant gains electrons.
Term
What does a Voltaic Cell (galvanic) do?
Definition
Powers a load
Term
What does a Electrolytic Cell do?
Definition
Load that is powered by energy
Term
A | B || C | D
phase of lower oxidation state
|
phase of Higher oxidation state
||
phase of higher oxidation state
|
phase of Lower oxidation state

Oxidation Half cell on right then Reduction Hall cell on left
Definition
Notation of a Voltaic Cell
Term
The standard cell potential is the difference between the standard potential of the cathode (reduction) half-cell and the standard potential of the anode (oxidation) half-cell.
Definition
E°cell = E°cathode - E°anode
Term
Writing Spontaneous Redox Reactions
Definition
Stronger Reducing Agent + Stronger Oxidizing Agent <==> Weaker Oxidizing Agent + Weaker Reducing Agent
Term
Formula to calculate the total charge of E0Cell
Definition
E0cell = (RT/nF) ln K
Term
The interrelationship of DG0, E0, and K.
Definition
[image]
Term
The Effect of Concentration on Cell Potential
Definition
When Q < 1 and thus [reactant] > [product], lnQ < 0, so Ecell > E0cell
When Q = 1 and thus [reactant] = [product], lnQ = 0, so Ecell = E0cell
When Q >1 and thus [reactant] < [product], lnQ > 0, so Ecell < E0cell


Ecell = E0cell - .0592/n *log Q
Term
primary battery
Definition
A primary battery cannot be recharged, it is discarded when the components have reached their equilibrium concentrations
Term
secondary battery
Definition
A secondary battery is recharged when it runs down by supplying electrical energy to reverse the cell reaction.
Term
Properties and Differences of Voltaic and Electrolytic Cells
Definition
Delta G's Opposite
Delta E's Opposite
Signs (charges) Opposite
Term
One Amp ='s?
Definition
One coulomb per second
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