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Chapter 12
Organic Chemistry Test 2
25
Chemistry
Undergraduate 2
03/29/2011

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Term

Dehydration of Alcohols

(produces)

Definition

Alkene & H2O

(loss of -H and -OH)

Term

Boiling Point

Aldehydes & Ketones

Definition

High BP's

Dipole Dipole Interaction

No Hydrogen Bonding.

Term
Thiols
Definition

C-SH

Strong oder

Detect gas 

Term
Naming Thiols
Definition

- hiol

 

Term
Ether
Definition

R1-O-R2

Single bonded

Term
Boiling Point of Ether
Definition

Lower BP

No Hydrogen bonding.

Term
Aldehyde
Definition

O=CH

-al

 

Term
Ketone
Definition

C-C=O-C

-one

Term
Oxidation of Ketones produce
Definition
Nothing. No reaction.
Term
Oxidation of Aldehydes
Definition
Carb. Acid
Term
Solubility of Aldeyhydes and Ketones.
Definition
>5 Only
Term
Benedicts Test
Definition
Test for Aldeyhydes with Hydroxyl group.
Term
Enatiomers
Definition
Stereoisomers can not be superimposed.
Term
"L" and "D" Formation
Definition

Furthest -OH is on Left "L"

Furthest -OH is on Right "D"

Term
Fishcer Projection
Definition

Oxidized C at top.

Vertical back bond.

Horizontal front bond.

Intersections Chiral.

Term

Combustion of Alcohol

(produce)

Definition
O2 -> CO2 and H20
Term
Phenol Solubility
Definition
Yes. Weak Acid.
Term
Solubility of Alcohol & Ether
Definition
>5
Term
BP of Alcohols
Definition
High. Hydrogen Bonding. Higher then alkanes.
Term
Oxidation of Primary Alcohol
Definition
Produces Aldehyde
Term
Oxidation of Secondary Alcohol
Definition
Produces Ketone
Term
Oxidation of 3 Alcohol
Definition
No Reaction.
Term
Thiol
Definition

-SH

-hiol

Term
Oxidation of Thiol
Definition
Disulfide Bonds
Term
Reduction of Alcohols
Definition
Forms Alkane.
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