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Chap 6-9
Concordia University chem 101 exam 3
84
Chemistry
Undergraduate 1
11/07/2010

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Term
Define Physical Change
Definition

The identity and composition of the substance do not change.
The state can change, or the material can be torn into smaller pieces.

Term
Define Chemical Change
Definition

Reacting substances form new substances with different compositions and properties.
A chemical reaction takes place.

Term

Balance:

 

CH4 + O2 -----> CO2 + H2O

Definition
CH4 + 2O2 -----> CO2 + 2H2O
Term

Define Combination reaction 

 

Definition

two or more elements bond to form one product

 

 

A + B-------> AB

Term
define Decompostition Reaction
Definition

A reactant splits into two or more simpler products.

 

 

AB -----> A + B

Term
Define Single Replacement Reaction 
Definition

A reacting element switches place with an element in the other reacting compound

 

A + BC ----> AC + B

Term
Define Double Replacement Reaction
Definition

the positive ions in the reacting compounds switch places

 

AB + CD ------> AD + CB

Term
Define Oxidation
Definition
Loss of electrons 
Term
Define Reduction 
Definition
the gain of electrons 
Term
Oxidation always involves:
Definition

Loss of electrons

Electrons are a product 

 

 

May Involve: addition of oxygen, loss of hydrogen

Term
Reduction always involves:
Definition

Gain of electrons 

electrons are a reactant 

 

May involve: Loss of oxygen, Gain of hydrogen

Term
# of particles in a mole?
Definition
6.02x10^23
Term
Define Molar mass
Definition

the mass of one mole of a substance
the atomic mass of an element expressed in grams

Term

n the reaction or iron and sulfur, how many moles of sulfur are needed to react with 6.0 moles of iron?

 

2Fe + 3S -----> Fe2S3

Definition

6.0moles Fe x    3 moles S

                       __________

                        2 moles Fe 

 

 

= 9.0 Moles of S

Term

Mass of product from mass of reactant 

 

pg  238

 

Sample prob. 6.11

Definition
Term
Percent Yield equation
Definition

actual yield             

____________     x 100

Theoretical yield             

Term
define endothermic reaction 
Definition
the energy of the products is greater than that of the reactants
Term
Define exothermic
Definition
the products have less energy than the reactants. 
Term
define mole
Definition
unit that contains 6.02x10^23 items
Term
Define coefficient 
Definition
whole numbers in front of formulas to balance an equation
Term
define oxidizing agent 
Definition

  • Oxidizing agents give oxygen to another substance or remove hydrogen from it.

oxidizing agent is reduced

Term
Define reducing agent 
Definition

Reducing agents remove oxygen from another substance or give hydrogen to it.

 

 

reducing agent is oxidized.

Term
Major features of the kinetic theory of gases?
Definition

1- A gas consists of small particles that move randomly with rapid velocities

2- the attractive forces between the particles of a gas can be neglected

3- the actual volume occupied by gas molecules is extremely small compared to the volume that the gas occupies

4- Gas particles are in constant motion, moving rapidly in straight paths

5-the average kinetic energy of gas molecules is proportional to the kelvin temperature.

Term

Boyle's Law? (equation)

 

Definition
P1V2 = P2V2
Term
Charles Law? (equation)
Definition

V1     =      V2

_____    _______

T1              T2

Term
Gay-Lussac's Law? (equation)
Definition

P1    =    P2

_____    _______

T1          T2

Term
The combined Gas Law? (equation)
Definition

P1V1  =  P2V2

_______   ________

T1            T2

Term
Avogadro's Law? (equation)
Definition

V1   =   V2

______    ______

N1          N2

Term
The ideal Gas Law? (equation)
Definition
PV = nRT
Term
What is R (ideal gas constant)
Definition
R (ALWAYS) = 0.0821 L
Term
What is Standard Temperature? (STP)
Definition
0 degree C (273K)
Term
What is Standard Pressure? (STP)
Definition
1 atm (760 mmHg)
Term
Define atmospheres and millimeters (atm)
Definition
the most common units used for gas measurement
Term
Relate temperature and pressure to gas
Definition

As temperature increases the pressure of a gas increases

 

As temperature decreases the pressure of a gas decreases 

Term
relate vapor pressure to atmospheric pressure and boiling point
Definition

A liquid reaches its boiling point when its vapor pressure becomes equal to the external pressure.

 

ex: at an atm of 760mmHg, water will boil at 100C, the temperature at which its vapor pressure reaches 760mmHg.

Term
Describe the relationship between the amount of a gas and its volume
Definition
(avagadro's law) if the number of moles of a gas is doubled, then the volume will double as long as we do not change the pressure or temperature. 
Term
Volume of 1 mole of gas at STP?
Definition

1 mole of gas = 22.4 L

 

22.4 L is considered a gas's molar volume

Term
Describe how the partial pressure of oxygen gas vary in the lungs, blood, and tissues, and how those levels serve to deliver oxygen from the air to the tissues. 
Definition
partial pressure of oxygen in venous blood is 40 mmHg, oxygen diffuses from the aveoli into the bloodstream. The oxygen combines with hemoglobin, which carries it to the tissues of the body, where the partial pressure of oxygen can be very low. Oxygen diffuses from the blood where the partial pressure of oxygen is high into the tissues where oxygen pressure is low. (carbon dioxide diffuses from the tissues into the bloodstream and is carried to the lungs)
Term
Daltons Law? (equation)
Definition

P total= p1 + p2 + p3 + ......

 

total pressure= sum of the partial pressures

Term
Define Barometer
Definition
measures atmospheric pressure
Term
Define pressure gradient
Definition
the rate of decrease (that is, the gradient) of pressure in space at a fixed time
Term
Define solute and solvent
Definition
a solution is a homogeneous mixture in which one substance called the solute is uniformly dispersed in another substance called the solvent.
Term
Describe strong electrolytes
Definition

100% of the solute dissociates into ions.

Ex: Sodium Chloride (NaCl)

 

when the electrodes from the light bulb apparatus are placed in the NaCl solution, the light bulb is very bright.

Term
Define weak electrolytes
Definition

only a small percentage of the dissolved solute dissociates into ions. 

Ex: HF

 

When the electrodes are placed in a solution of a weak electrolyte, the glow of the light bulb is very dim. 

Term
Define Nonelectrolytes
Definition

a nonelectrolyte such as sucrose (sugar) dissolves in water as molecules which do not dissociate into ions. 

 

When electrodes are placed in a solution of a nonelectrolyte, the light bulb does not glow because the solution does not conduct electricity 

Term
Define colloids
Definition
the particles in a colloidal dispersion are much larger than solute particles in a solution.
Term
Define suspensions
Definition
heterogeneous, nonuniform mixtures that are very different from solutions or colloids. So large, can often be seen with the naked eye. - trapped by filters and semipermeable membranes
Term
Define Solutions
Definition

Are homogeneous mixtures of two or more substances
Consist of a solvent and one or more solutes.

Term
Describe hydrogen boding and water
Definition

Water Is a polar molecule.
Forms hydrogen bonds between the hydrogen atom in one molecule and the oxygen atom in a different water molecule

Term
Describe the effect of temperature on solubility
Definition

Of most solids increases as temperature increases.
Of gases decreases as temperature increases.

Term
Define percent concentration (equation)
Definition

Is the amount of solute dissolved in a specific amount of solution.

                        amount of solute

                      amount of solution

 


Term
If finding percent concentration, you already have percent, and you need grams. What do you do?
Definition

Molarity question!

change mL ---> L and then multiply moles/1 L

 

Once you have the moles, multiply by the molar mass to get answer.

Term
Equation for mass/volume percent?
Definition

grams of solute           

______________      x100

milliliters of solution            

Term
Equation for dilution
Definition
C1V1 = C2V2
Term
How many mL are in a L?
Definition
1000mL = 1L
Term
Define osmosis 
Definition
water molecules move through a semipermeable membrane from the solution with the lower concentration of solute into a solution with the higher solute concentration. 
Term
Define dialysis
Definition
A semipermeable membrane, called a dialyzing membrane, permits small solute molecules and ions as well as solvent water molecules to pass through, but it remains large particles, such as colloids. 
Term
What happens to a red blood cell in hypotonic solutions?
Definition
water flows into the red blood cell causing it to swell and burst.
Term
What happens to a red blood cell in isotonic solutions?
Definition

exert the same osmotic pressure as body fluids.

 

"equal to"

 

red blood cell retains its normal volume

Term
What happens to a red blood cel in hypertonic solutions?
Definition
water leaves the red blood cell causing it to SHRINK
Term
What is the molarity of 60.0g of NaOH in 0.250L of solution? (pg. 316)
Definition

60.0g NaOH x    1 mole

                        _________

                          40.0g NaOH

 

= 1.50 moles

 

 

1.50 moles NaOH

___________________

0.250 L 

 

= 6.00 M NaOH

Term
How many Liters of a 2.00 M NaCl solution are needed to provide 67.3g of NaCl? (pg. 317)
Definition

67.3g NaCl x   1 mole NaCl    x      1L NaCl

                      __________       __________

                           58.5g NaCl       2.00moles NaCl

 

=0.575 L of NaCl solution

Term
Define isotonic
Definition

exert the same osmotic pressure as body fluids 

"equal to"

Term
Define Hypertonic
Definition
higher solute concentration water leaves the cell by osmosis.
Term
Define Crenation
Definition
As water is lost the cell shrinks.
Term
Define Hypotonic
Definition

when a red blood cell is placed in pure water, water flows into the cell by osmosis.  

"lower than"

Term
define Hemolysis
Definition
increase in fluid causes the cell to swell, and possibly burst
Term
Define osmolarity
Definition
the measure of solute concentration
Term
Define hydration 
Definition
when ions form a solution they undergo hyrdration as water molecules surround each ion.
Term
Define saturated
Definition

the rate of the reaction that dissolves the solute becomes equal to the rate of recrystallization. 

 

Term
Define collision theory
Definition
indicates that a reaction takes place only when molecules collide with the proper orientation and with sufficient energy. 
Term
Identify the factors that will speed up or slow down a reaction. 
Definition

Temperature: at higher temperatures the increase in kinetic energy makes the reacting molecules move faster.

Concentrations of reactions: the rate of the reaction increases when the concentrations of the reactants increase. 

Catalysts: another way to speed up a reaction is to lower the activation energy. when activation energy is lowered more collisions provide sufficient energy for reactants to form product.

Term
Define activation energy 
Definition
the amount of energy required to break the bonds between atoms of reactants
Term
Define rate of reaction
Definition

determined by measuring the amount of a reactant used up, or the amount of a product formed, in a certain period of time: 

 

change in concentration 

______________________

change in time

Term
Define catalysts
Definition
speeds up reaction by providing a different way for the reaction to proceed that has a lower activation energy. 
Term
Define forward reactions
Definition

all of the reactants were converted to products.

 

----->

Term
Define reverse reactions
Definition

products come together to form the reactants

 

----->

<------

Term
At equilibrium.....
Definition
the rate of the forward reaction is equal to the rate of the reverse reaction. 
Term
write equilibrium constant exoression
Definition

products 

_________

Reactants

 

=

 

[c]^c [D]^d

______________

[A]^a [B]^b

Term
Define heterogeneous equilibrium 
Definition
when the reactants and products are in two or more physical states
Term
Define homogeneous equilibrium
Definition
a reaction in which all the reactants and products are in the same physical state
Term
If products are LARGE then what will Kc be?
Definition

[PRODUCTS]                 

______________ = LARGE Kc

[reactants]                  

Term
When the reactants are large then what will Kc be?
Definition

[products]                

__________ = small Kc

[REACTANTS]                 

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