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CCiBT2
Concise Course in Brewing Technology Week 2
98
Chemistry
Undergraduate 1
10/29/2013

Additional Chemistry Flashcards

 


 

Cards

Term
What are the names of the strains of ale and lager yeast?
Definition
saccharomyces cerevisiae
s. cerevisiae var carlsbergensis
Term
List the principal functions of yeast in the production of beer
Definition
reproduce, convert extract to alc
Term
How do brewers' yeasts reproduce?
Definition
budding
Term
What are the yeast nutrients in wort?
Definition
carbohydrates, inorganics (calcium, zinc, Mg), oxygen, fan
Term
Define 'yeast growth'
Definition
the use of nutrients to increase biomass and cell division
Term
List the 3 phases of yest growth
Definition
lag, log, stat
Term
What is flocculation?
Definition
when yeast die or go dormant and sediment
Term
What two substances have an effect on whether yeast adopts a respiratory or fermentative mode of metabolism?
Definition
oxygen and glucose
Term
What are the 2 primary fermentation metabolites?
Definition
ethanol and co2 + acetaldehyde
Term
Define the term beer spoilage
Definition
a change which results in uncharacteristic properties (appearance, pH, flavor, aroma)
Term
What characteristics make beer resistant to spoilage bacteria?
Definition
pH, hop extract, alcohol, low O2
Term
Name 3 gram positive spoilage bacteria
Definition
bacillus, lactobacillus, pediococcus
Term
Define wild yeast in a brewery
Definition
any organism not purposefully added to a beer
Term
List 4 general detection methods for beer spoilage organisms
Definition
microscopy, selective media, membrane filtration, rapid methods
Term
Define quality
Definition
standard of excellence, fitness for use, characteristics of a product/service
Term
What is the difference between Quality Control and Quality Assurance?
Definition
QA is the system, QC are the checks on incoming materials, in-process and final product
Term
List 3 formalized systems for quality management?
Definition
GMP, HACCP, WCM
Term
Define 'World Class Manufacturing'
Definition
holistic approach that focuses on waste materials and wasted process/time
Term
What exactly is meant by the term pure culture?
Definition
starting a culture from a single cell
Term
Name and describe a method for a) isolating a pure brewing yeast culture and b) preserving it
Definition
streak plating which isolates by streaking on media. -80C storage using a slant
Term
List 3 reasons why brewing yeast is propagated
Definition
1) prevent problems
2) keeps mutant yeast out
3) pitching amount
Term
List 3 aspects to be considered when propagating brewing yeast in the plant
Definition
1) aseptic technique
2) 1:10 vol increments
3) temp
Term
Name 3 stresses which can affect brewing yeast
Definition
1) temp
2) OG
3) pH
Term
List 2 yeast viability tests and 2 yeast vitality tests
Definition
viabilty: plate and dye
vitality: OUR and ACP
Term
Explain why yeast glycogen levels need to be maintained high during storage
Definition
yeast needs glycogen to pick up oxygen to convert glucose during glycosis
Term
What are the main aims of yeast pitching?
Definition
minimize lag and consistent viable levels
Term
Describe a method for acid-washing of yeast and name 3 disadvantages of this procedure
Definition
2hr phosphoric acid at 2C, pH of 2
yeast stress, must use yeast immediately, lots or rules
Term
What must be done before beginning to sterilize equipment?
Definition
alkali for soil, rinse, acid for salt/mineral, rinse
Term
Fats and protein are attacked best by alkalis. True or False?
Definition
true because fat and protein are soluble in alkali solution
Term
What 5 factors impact on the efficacy of detergent performance?
Definition
1) concentration
2) temp (10C:100% chemical reaction on soil)
3) time
4) mechanical action
5) amount of soil
6) remove CO2
Term
Name the key attributes we want in an ideal sanitizer
Definition
1) effective against micro at low levels
2) stable in storage
3) non corrosive
4) easily applied
Term
Heat is effective in sanitizing and sterilizing. What is a strong negative aspect of using heat?
Definition
costly and destroys gaskets
Term
Oxidizing sanitizers are grouped in four ways. What are they?
Definition
1) peroxide based
2) gluteraldehydes
3) chlorine based
4) iodophors
Term
What is the main way a surface active sanitizer works?
Definition
stays on surface for a long time
Term
What is a Q.A.C.?
Definition
Quaternary Ammonium Compounds
Term
Why must we be concerned about the environment when cleaning and sanitizing?
Definition
purge co2 so that you dont suck in a tank
Term
List 5 characteristics of ale yeast
Definition
1) + temp
2) faster ferm
3) + ferm byproducts
4) + esters
5) + fusels
Term
List 5 fermentation control points
Definition
1) wort composition
2) strength
3) pH
4) temp
5) time
Term
Why are cylindo-conical fermenters now the brewery standard?
Definition
a) better space utilization (2height:1wide)
b) ability to easily remove yeast
c) accelerated maturation with inert gas
d) temperature control using a jacket
e) thermal current convection
Term
Name 2 advantages of continuous fermentation
Definition
1) large volume output (beer done in 1-2 days)
2) $ savings
Term
List 4 possible disadvantages of high gravity brewing
Definition
1) -efficiency
2) +yeast stress
3) +fermentation time
4) -flavor match
Term
What is Cleaning in Place?
Definition
automated cleaning of a tank using a sprayball and pump
Term
List the advantages and disadvantages of sprayballs in vessel
cleaning.
Definition
internal cleaning
no scrubbing
easy
can clog
cant see the spray pattern
Term
List 3 tank cleaning problems.
Definition
clogged sprayball
reduced flowrate
shadow areas
Term
What are 3 requirements in pipeline cleaning?
Definition
turbulent flow
5ft/sec
reverse when possible
Term
List the steps in a normal CIP cycle.
Definition
caustic>rinse>acid>rinse>sanitizer
Term
What are the major components in ‘blended caustic’?
Definition
caustic, gluconates, phophonates, surfactant
Term
What care should be taken when storing iodine-based
sanitizers?
Definition
keep away from alkali, acid and heat
Term
Name 5 fermentation flavor compounds.
Definition
1) acetaldehydes (mg/l) from high temp ferm producing bruised apple
2) fusels (mg/l) from fast ferm producing
3) esters (mg/l)from yeast strain and yeast growth
3a) ethyl acetate producing nail polish remover
3b) iso-amyl-acetate from low pitching rate producing fruity/banana
4) carbonyls
4a) diacetyl - butter
4b) acetaldehyde - bruised apple
5) organic acid lower pH increasing sourness
5a) acetic (vinegar)
6) phenolic producing spicy, cloves
7) yeast autolysis produces meat/savory
Term
How many flavor compounds have been identified in beer?
Definition
90
Term
How can higher alcohols be reduced in fermentation?
Definition
increase:
pressure, pitch rate
Term
What is the flavor of iso-amyl-acetate?
Definition
fruity, banana
Term
List 4 factors effecting ester production.
Definition
1) OG
2) ferm temp
3) low oxygen
4) high pitch rate
Term
If beer has high diacetyl after fermentation what can be done
to reduce it?
Definition
krausening
Term
What common taste attribute do organic acids have?
Definition
sour
Term
Are fatty acid flavors desirable in beer?
Definition
Term
What is yeast autolysis?
Definition
meat like flavor/aroma from yeast expelling insides as it dies
Term
If pressure is increased in fermentation which of the following
beer attributes are raised (R) or lowered (L)?
a) Dissolved CO2 ____
b) Acetaldehyde ____
c) Diacetyl ____
d) Esters ____
e) Higher Alcohols ____
Definition
Term
Define colloidal stability.
Definition
lasting clear beer
Term
What are the components of beer haze?
Definition
protein and tannins
Term
What are 3 negative factors that may promote haze formation in beer?
Definition
1) Cu and Fe
2) agitation
3) oxygen
Term
List 3 common modern ‘chillproofing’ methods.
Definition
1) precipitants
2) insoluble adsorbents
3) PVPP
Term
What do chillproofing treatments attempt to change in beer?
Definition
removal of proteins and tannins to stop or retard chill haze (PT complexes)
Term
What happens to sweetness and bitterness as beer ages?
Definition
+sweetness, -bitterness
Term
What is responsible for the formation of aldehydes in beer?
Definition
oxidized alcohols
Term
What measures can be taken in fermentation and maturation
to retard flavor instability?
Definition
adequate active yeast during maturation
avoid stressing yeast
Term
List 3 types of anti-oxidants.
Definition
1) sulfites
2) ascorbic acid
3) enzymes
Term
List 4 questions to ask (before asking to a recheck) if analytical data looks ‘suspicious’.
Definition
1) is it within limits?
2) how critical?
3) how far from previous batches
4) is it a trend or spike?
Term
Before reprocessing beer what must be considered?
Definition
will it do more damage to reprocess?
Term
If diacetyl level is analyzed and found to be high what other parameter must be considered to guide corrective action?
Definition
DMSP
Term
List the 3 basic types of wastewater discharged from packaging breweries.
Definition
1) storm water
2) sanitary
3) process
Term
List 3 parameters that should be measured in brewery waste water.
Definition
1) pH
2) flow
3) total suspended solids
Term
Name the 2 basic types of wastewater treatment systems.
Definition
1) primary is screen and settle 50%
2) secondary is anaerobic/aerobic 95%
Term
List 3 advantages of anaerobic wastewater treatment systems in breweries.
Definition
1) lower investment cost
2) small land area
3) lower energy costs
Term
List the important characteristics of draught beer.
Definition
unpasteurized, less CO2
Term
What is the most common draught keg?
Definition
sankey
Term
What are the objectives of a draught dispensing system?
Definition
delivered at:
correct temp
controlled CO2
w/o foam
brewery fresh
Term
What is equilibrium pressure?
Definition
equal spacing of a specific gas' molecules in a pressurized vessel
Term
What are ‘beer clean’ glasses?
Definition
1) no residue
2) not in smoky area
Term
What are the 2 most common reasons for draught system problems?
Definition
temp and pressure
Term
Define ‘Real ale’.
Definition
A name for draught (or bottled) beer brewed
from traditional ingredients, matured by secondary
fermentation in the container from which it is
dispensed, and served without the use of extraneous
carbon dioxide.
Term
Name 2 types of Spiles and their use.
Definition
The hard plastic or hardwood Spile is inserted in the Shive during ‘conditioning’ when carbonation level is rising and after the cask has been tapped but is not in use.
The Porous (Soft) Spile is used to release some CO2 after ‘conditioning’ to control carbonation before cask is tapped.
Term
What happens when a cask is being ‘conditioned’?
Definition
fermentation within the cask
Term
What does it mean when a beer is in good ‘condition’?
Definition
Term
How does a Beer Engine work?
Definition
Term
What is the purpose of a ‘Sparkler’?
Definition
Term
What are the temperature inversion effects in ‘cold room’ tanks.
Definition
none,
Term
List 3 methods to aid sedimentation.
Definition
1) finings
2) centrifuge
3) crash and wait
Term
List 3 undesirable volatile compounds in beer.
Definition
1) diacetyl
2) hydrogen sulfide
3) acetaldehyde
Term
List 5 factors effecting haze development.
Definition
1) tannin concentration
2) protein concentration
3) O2
4) Heat
5) metal ions
Term
List 5 process measures that reduce the development of beer hazes.
Definition
1) raw materials
2) vigorous rolling boil
3) cold conditioning
4) finings/filtration
5) limitation of o2 ingress
Term
Define filtration.
Definition
 Any contrivance or porous substance such as felt, paper, charcoal, sand, etc., through which liquid or gas is passed to remove ‘impurities’ or other matter
 Any device containing a filtering substance
Term
List 4 mechanisms of filtration.
Definition
1) Direct Interception (mechanical)
2) inertial impaction (absorption)
3) adsorption (electro-chemical)
4) bridging (DE body feed)
Term
What are the advantages of surface filters?
Definition
absolute
single use
easy
low solids capacity
Term
What are the advantages of depth filters?
Definition
 High void volume, high throughput
 Often can be regenerated
 Can handle high solids loading
 Can filter to relatively specific particle sizes
 Most need to use filteraids
Term
Why is Diatomaceous Earth used as a filteraid?
Definition
porous and void volume
Term
What is the purpose of pre-coating in a D.E. filter?
Definition
 Prevent filter screen from becoming clogged by particles to
be removed
 Provide immediate clarity
 Facilitate cleaning of the filter screen at the end of the filter
cycle
*set using 1.5x rate of filter
*100mesh
 1/8” - 1/4” (3.2 - 6.4 mm) thickness
10 - 30 lb. D.E. = 5 - 15 kg D.E.
100 ft2 filter area 10 m2 filter area
 Precoat D.E. concentration at filter screen of
0.5 - 1 wt% (1 wt% = 2.5 lb/bbl = 1.3 kg/hl)
 Velocity of 4.5 ft/sec (1.5 m/min)
 Precoat flow rate of 1 gpm/ft2
25 - 50% faster than filtering
 Should give DP of 2 psi
Term
What brewing process measures may be used to aid beer filtration?
Definition
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