Term
What atoms do all carbohydrates contain? |
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Definition
Carbon, Hydrogen and Oxygen |
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Term
What atoms do some (but not all) carbohydrates contain? |
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Definition
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Term
Which groups define a carbohydrate? |
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Definition
A hydroxyl group AND either a ketone of aldehyde group |
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Term
What is the general formula for a carbohydrate? |
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Definition
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Term
Which are the two most common carbohydrates? |
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Definition
Glyceraldehyde and Dihydroxyacetone |
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Term
What is a chirally active carbon? |
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Definition
A carbon atom with four different groups bonded to it |
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Term
How many sterioisomers can one chirally active carbon have? |
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Definition
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Term
How do carboydrates form ring structures? |
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Definition
The aldehyde or ketone group combines with one of its many alcohol groups. |
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Term
What is the name given to a five carbon ring? |
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Definition
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Term
What is the name given to a six carbon ring? |
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Definition
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Term
Pyranose sugars assume what 'visual' structure? |
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Definition
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Term
What orientation of atoms would result in a physical clash within the molecule? |
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Definition
If the axial atoms pointed in the same direction of the carbon atoms |
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Term
How many asymmetric carbons does glucose have? |
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Definition
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Term
Which isomer of glucose is naturally found in nature? |
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Definition
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Term
Which asymmetric carbon in sugars determines the stereoisomerism of the sugar? |
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Definition
The asymmetric carbon furthest from the aldehyde/ketone group |
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Term
Why are sugars referred to as 'D' or 'L'? |
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Definition
In the direction to which the sugar rotates polarized light |
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Term
What does the 'D' in a D sugar stand for? |
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Definition
Dextrorotatory (Clockwise) |
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Term
What does the 'L' in a L sugar stand for? |
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Definition
Laevorotatory (Anticlockwise) |
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Term
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Definition
Sugars that are isomers at more than one asymmetric carbon |
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Term
During the formation of a hemiacetal which carbon also becomes asymmetric? |
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Definition
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Term
What determines the formation of alpha and beta sugars? |
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Definition
The stereochemistry on C1 in comparison to C5 |
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Term
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Definition
A sugar that has either an alpha or beta conformation |
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Term
What determines a beta anomer? |
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Definition
Same stereochemistry at C1 and C5 |
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Term
What determines an alpha anomer? |
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Definition
Different sterochemistry at C1 and C5 |
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Term
What determines a L-sugar? |
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Definition
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Term
What determines a D-sugar? |
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Definition
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Term
What is a polysaccharide? |
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Definition
A polymer made of repeating sugar monomers |
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Term
What is an ogliosaccharide? |
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Definition
A polymer made of a small number (10-20) repeating sugar monomers |
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Term
What is the name given to the link between sugar monomers? |
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Definition
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Term
Glycosidic bonds can have different orientations. What are the different orientations? |
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Definition
Sticking down from the plane or equatorial on the plane |
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Term
What is the disaccharide generated from starch? |
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Definition
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Term
Which main monosaccharide in milk? |
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Definition
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Term
Which organism/s synthesise starch? |
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Definition
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Term
Which family of the animal kingdom synthesise glycogen? |
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Definition
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Term
What is the function of cellulose? |
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Definition
Maintaining structure in plant cell walls |
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Term
What organism/s synthesise cellulose? |
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Definition
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Term
Which polysaccharide is present in bacteria cell walls? |
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Definition
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Term
What is a reducing sugar? |
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Definition
The sugar at the end of a polysaccharide that has it's aldehyde group exposed and is able to be opened to reduce its adjacent sugar |
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Term
What type of glycosidic bonds are present in glycogen |
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Definition
1,4 glycosdic bonds AND 1,6 glycosidic bonds |
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Term
What is a reducing sugar? |
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Definition
The sugar at the end of a polysaccharide that has it's aldehyde group incorporated into the glycosidic bond and therefore is unable to be open unless the adjacent sugar is reduced |
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Term
What causes the helical structure in glycogen and starch? |
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Definition
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Term
What is the advantage of glycogen and starch having a helical structure? |
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Definition
It makes the molecule more compact and therefore easier to store |
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Term
What is the advantage of glycogen being branched? |
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Definition
Lots of non-reducing sugars that can be forced open and hydrolysed to produce glucose more quickly |
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Term
What gives strength to cellulose fibres? |
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Definition
The -OH groups forming hydrogen bonds |
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Term
What causes cellulose to have a highly crystalline structure? |
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Definition
The interconnection of hydrogen bonds |
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Term
Which enzyme synthesises sugars? |
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Definition
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Term
Which enzyme determines our blood group? |
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Definition
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Term
Which glycosyltransferase/s creates blood group A? |
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Definition
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Term
Which glycosyltransferase/s creates blood group B? |
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Definition
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Term
Which glycosyltransferase/s creates blood group AB? |
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Definition
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Term
Which glycosyltransferase/s creates blood group O? |
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Definition
None, the glycosyltransferase is inactive |
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Term
Which sugar does GTA add? |
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Definition
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Term
Which sugar does GTB add? |
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Definition
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Term
What factors contribute to the difference in blood groups? |
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Definition
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Term
Which two key surface proteins are present on the influenza virus? |
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Definition
Hemagglutinnin AND Neuraminidase |
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Term
What does the hemagglutinnin receptor do? |
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Definition
Recognises the sugar sialic on the surface of target cells |
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Term
What does the neuraminidase receptor do? |
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Definition
Allows the release of the new virus by removing sialic acid |
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Term
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Definition
A protein embedded in the plasma membrane that has a carbohydrate chain attached |
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Term
What are the two types of bacteria cell wall? |
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Definition
Gram-negative and Gram-positive |
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Term
What two monosaccharides make up a peptidoglycan? |
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Definition
N-Acetyl-B-D-Glucosamine (NAG) AND N-Acetyl-muramic acid (NAM) |
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Term
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Definition
A chain of four amino acids |
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Term
Which amino acids are present in the tertapeptide of N-Acetyl-muramic acid (NAM)? |
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Definition
L-Alanine, D-Glutamic Acid, DAP (Diaminopimelic acid), D-Alanine |
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Term
What is the purpose of the tetrapeptide in peptidoglycan? |
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Definition
It forms cross links with other tertapeptides to give strength and flexibility to the bacterial cell wall |
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Term
Which enzyme forms the cross links in peptidoglycan? |
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Definition
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Term
How does Penicillin destroy bacterial cell walls? |
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Definition
It inhibits transpeptidase, this prevents tetrapeptide crosslinks forming making the cell wall osmotically sensitive which allows cell lysis to occur |
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Term
Which bacterial cell wall contains more peptidoglycan? |
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Definition
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Term
Which bacterial cell wall contains less peptidoglycan? |
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Definition
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