Shared Flashcard Set

Details

C4
Tensors
36
Chemistry
Undergraduate 3
05/31/2011

Additional Chemistry Flashcards

 


 

Cards

Term
Matter v. Field Tensor
Definition

Matter: properties have an orientation dependence and must conform to material's symmetry (must obey Neumann's principle)

 

Field: relates quantities, can have any orientation with respect to material, can exist in isotropic bodies, need not conform to mateiral's symmetry (ie conductivity/stiffness)

Term
Neumann's Principle
Definition

A property must have at least the symmetry of the underlying material but could have more

 

aka the symmetry elements of a material property must include the symmetry elements of the point group of the material

Term
Definition of isotropic materials
Definition
  • infinite symmetry
  • macroscopic continuum
  • amorphous solids at atomic scale

strain depends only on stress state not orientation

prinicpal axes for stress and strain will coincide

 

Hooke's law can be  used to related stress and strain

Term
Rank
Definition
The total number of indices is equal to the dimension of the array and is called the order or the rank of the tensor
Term
Elastic deformation
Definition
  • recoverable: remove load and it returns to initial state
  • metals and ceramics are elastic at SMALL strains
  • polymers are elastic at small and large strains
  • can get elastic failure of a material (buckling)
Term
Converse Properties
Definition

can not simply find the inverse of individual terms; must find the inverse of the entire tensor

 

1/ρij≠1/σij

Term
Physical meaning of eij
Definition

e12=e21 "pure shear"

e12=-e21 "rotation"

e12=c, e21=0 "simple shear"

 

eijijij

εij-symmetric/strain/shear tensor=(eij+eji)/2

ωij-antisymmetric/rotation tensor=(eij-eji)/2

 

Term
Plastic deformation
Definition
  • permanent - irrecoverable
  • strains may be large
  • important in metal working (forging/extrusion)
  • microscopic scale (deformation at crack tip)
  • often the desireable failure mode (absorbs energy (impace/crumble zone)
Term
Brittle fracture
Definition
  • catastrophic propagation of crack
  • no macroscopic deformation
Term
principal axis
Definition
one along which the resultant stress is a purely normal stress.  there are no shear stresses in teh plane perpendicular to the axis.  Whatever the stress state, however comiplicated, we can always find a set of axes which allow for no shear
Term
What can Mohr's Circle be used for
Definition
  • finding principal axes/stresses/strains
  • knowing stresses for one orietnation and calculate for any other
  • calculate maximum shear stress
Term
Hydrostatic v. deviatoric
Definition

hydrostatic: volume change

deviatoric: shape change

 

plastic flow only depends on deviatoric and this is true even to very high hydrostatic

dilation based on hydrostatic bit

Term
Values of poisson ratio
Definition

metals ~ 0.25-0.33

rubber ~0.5

Term
Elastic constants
Definition

Bulk Modulus, K: found by relating sum of strains (dilation) and sum of stresses (3*hydrostatic) via Hooke's law

Lame's constants: Used to get stresses from strains

two indepent elastic statnts for an isotropic material can specify many elastic properties

Term
Cauchy relation
Definition

when atoms lie at centers of symmetry and interatomic forces are entirely along the line joining the centers (C12=C44)

roughly ture for simply ionic crystals

does not work for metals bbecause bonding is not localized

Term
physical interpretation of different deformation modes
Definition

isotropic: 2 independent elastic constants and 2 deformation modes: dilation/shear

cubic: 3 independent cosntants and 3 deformation modes: dilation, shear on cube face, shear at 45 degrees to cube axis

Term
cubic crystal
Definition

3 independent terms

 

C11=C22=C33, C12=C23=C31, C44=C55=C66

Term
Strain gauge
Definition

devces which exploit changes in resisitance as a function of change in length

based on R=ρL/A

to measure strain, we fix wire secuely to object.  once fixed we allow deformation to occur.  we measure changes in R and infer strain however strains are usually very small so it is desirable to have a small gauge length but large actual length; done by folding

strain guage contacts are connected along a wheatstone bridge

 

these gauges are sensitive only to normal strains

Term

Photoelasticity

birefringent coatings

Definition

applying a stress to a transparent material results in optical anisotropy

light will propagate with two different velocities and two mutually perpendicular wave fronts

n1-n2=c(σ1-σ2) [c-stress optical coefficient]

if wavelength dependent: isochromatic fringes

if wavelengeth independent: isoclinic fringes

 

birefringent coatings are placed on surface under stress then birefringence is viewed.  materials with high stress optical coefficient are used (PMMA, epoxy, etc.)

Term
Methods of 3D stress analysis
Definition

Birefringent coatings

brittle coatings

XRD

Ultrasonics

Residual stresses

Stress strain analysis

Term
brittle coating method
Definition

used to determine teh directions of principal axes on surface

apply a thin coating of a brittle mateiral to unstressed body, cracks appear once critical stress is reached

first set of cracks appear perpendicular to sigma 1 then second appear later

if principal stresses are the same, "crazed" surface appears as direction of cracks is indeterminate

σspecimen=Especimenεcoating

 

Advantages:

can be used on real structure, obtain actual stresses, useful (determine directions and instrument with strain gauges)

Disadvantages:

need ceramic coating for high T, failure strain of coating must be calibrated

Term
XRD Stress Measurement
Definition

measure strain by changes in lattice parameter (thin films)

non destructive/no contact

useful only for surface strains (penetration less than a micron)

Term
Ultrasonics
Definition

applicable to larger objects than XRD

real materials are non linearly elastic so modulus varies with stress/strain

Term
optical interferometry
Definition

optical methods are attractive: non invasive, sensitive

lookign at small movements on surface rather than penetrating

Term
residual stresses
Definition

retained internal stresses not a result of external force

must be retained by interlocking

 

origins: thermal stress/differential thermal expansion, plastic flow/bending due to shot peening or machining, volume changes (phase transformations, carbides, nitriding)

Term
plane stress
Definition

thin films

there is no force on the free surface and in most cases σ1=σ2=σ [σ3=0]

 

these stresses are due to thermal expansion differences, deposition stresses, epitaxial stresses (difference in lattice parameters)

Term
plane strain
Definition
typically in edge dislocations
Term
st. venant's principle
Definition

if hte forces acting on a small part of the surface of a body are replaced by statically equivalent forces, the stress state is negligibly changed at large distance

 

upon mathematical treatment, it is evident that the decay of the effect of this small load is irrelevant at distances larger than the dimensions of that effect

 

(Venant's principle states that high order momentum of mechanical load ( momentum with order higher than torque) decays so fast that they never need to be considered for regions far from the short boundary. Therefore, the Saint-Venant's principle can be regarded as a statement on the asymptotic behavior of the Green's function by a point-load.)

Term
Airy Stress
Definition

The most generic relationship between stress and strain based on three principles. used for discontinuities such as cracks/holes

  1. stress equilibrium (the sum of all forces must equal zero though force can change through a body)
  2. strain compatibility  (displacements must vary smoothly)
  3. stress/strain relationships
Term
Piezoelectricity
Definition

direct piezoelectricity: polarization derived directly from application of stress

converse piezoelectricity:strains derived from application of electric field

 

can not include centrosymmetric terms

this process can exist if indivdiual grains are themselves piezoelectric and there is some texture

Term
Ferroelectricity
Definition
used in poling polycrystalline piezoelectrics
Term
Elastic waves in materials
Definition

important in dynamic response of materials/structures

important in mechanical testing at high strain rates

 

in general for bulk isotropic materials there are two wave modes which correspond to the two deformation modes

Term
pyroelectricity
Definition

if polarization of ferroelectric material is temperature sensitive

primary pyroelectricity: volume of teh sample is held constant

secondary pyroelectricity: volume change exists

Term
electrostriction
Definition

non linear piezoelectric effect

could include centrosymmetric crystals

Term

Representation surface of second rank tensors

Optical indicatrix

Definition

the radius length in any direction is the property to the -1/2 power

the normal to the representation surface at the point where the radius intersects is parallel to the resultant vector

Optical indicatrix: n=(K)1/2=(B)-1/2


JiiσiEi

σijxixj=1

x1=rλ1

r2σijxixj=1

r2σ=1

r=(σ)-1/2

Supporting users have an ad free experience!