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Bonding
Ionic bonds, Covalent bonds, Metallic bonds, electron dot diagrams, shapes, bond polarities, molecular polarity, and IMFs
59
Chemistry
10th Grade
03/05/2012

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Term
Ionic
Definition
Transfer of 1 or more electrons between atoms (cations and anions)
Held together by electrostatic force (opposite charges)
Elements = metallic and nonmetallic
chrystalline
solids at room temperature
conducts an electric current in the molten state (or dissolved in water)
Brittle
STRONGEST BOND (ninja)
high melting points
formula units
high boiling points
ex: titanium dioxide, cesium chloride, sodium chloride, salt
Term
Covalent (molecular)
Definition
A pair of electrons is shared between 2 atoms
Some are gases, some are liquids, some are solids (solids = malleable)
Molecule
elements = nonmetallic
low melting point and boiling point
poor conductors
ex: water, ammonia, diatomic elements (HONClBrIF), methane, carbon monoxide
Term
Metallic
Definition
Attraction of the free-floating valence electrons for the positive charged metal ions (forces that hold metals together) AKA: Overlapping of valence electrons
Malleable
Ductile
Shiny
Medium boiling & melting points
good conductors
all METALS
tend to be solid at room temp
ex: chromium, gold, zinc
Term
Covalent compounds
Definition
Share bonding electrons
Exist as molecules
Follow the octet rule
Term
Ionic compounds
Definition
brittle
involve the transfer of electrons
form crystal structures
held together by electrostatic force
follow the octet rule
Term
Metallic compounds
Definition
Good conductors
malleable
held together by electrostatic force
electron sea (free moving electrons around nucleus)
Term
how many electrons are shared by 2 atoms in a double covalent bond?
Definition
4
Term
how many electrons are shared by 2 atoms in a triple covalent bond?
Definition
6
Term
Bond b/w: H and Br
Definition
ionic
Term
Bond b/w: Fe and Cr
Definition
metallic
Term
Bond b/w: C and O
Definition
covalent
Term
Bond b/w: Ag and Au
Definition
metallic
Term
Bond b/w: Li and O
Definition
ionic
Term
Bond b/w:Br and Br
Definition
covalent
Term
Bond b/w: Cl and F
Definition
covalent
Term
Bond b/w: Zn and Cu
Definition
metallic
Term
Bond b/w: K and Cl
Definition
ionic
Term
Valence electrons
Definition
involved in chemical bonding
Term
Electrons and bonds are indicated in Lewis dot structures with...
Definition
dots
Term
Lone pair (of electrons)
Definition
a valence electron that doesn't bond
Term
The central atom in a Lewis Dot Structure can never be...
Definition
Hydrogen
Term
Halogens will N-E-V-E-R...
Definition
double or triple bond
Term
Single covalent bond
Definition
2 electrons are shared
Term
double covalent bond
Definition
2 electron pairs or 4 total electrons
Term
Triple covalent bond
Definition
3 electron pairs or 6 total electrons
Term
Polyatomic ion
Definition
a compound with a charge
Term
If the ion is POSITIVE []+
Definition
subtract electrons
Term
If the ion is NEGATIVE []-
Definition
add electrons
Term
So who goes in the middle??
Definition
Put the hydrogens (etc.) on the element with fewer valence electrons
Term
How do 2 nonpolar molecules attract one another?
Definition
they form temporary dipoles that stick ("induced dipoles")
Term
What is the name of the intermolecular force where 2 nonpolar molecules attract one another?
Definition
London Dispersion Forces
Term
Dipole-Dipole forces
Definition
2 polar molecules that are attracted to each other
Term
how do dipole-dipole forces arise between molecules?
Definition
the partial positive end is attracted to the partial negative end of the other
Term
Hydrogen bonding
Definition
an intermolecular force that occurs between H-O, H-N, and H-F
Term
IMF? Ne
Definition
LDF (London Dispersion Forces)
Term
IMF? NH3
Definition
Hydrogen bonding
Term
IMF? I2
Definition
dispersion
Term
IMF? Br2
Definition
dispersion
Term
IMF? HI
Definition
dipole-dipole
Term
IMF? H20
Definition
hydrogen bonding
Term
Rank the following from lowest to highest anticipated boiling point:
C2H4, FCN, NH3, H3COCH3
Definition
C2H4, H3COH3, FCN, NH3
Term
Exception to octet rule?
Definition
Hydrogen, Boron, and anything below the second period
Term
Shape: Linear
Definition
bonds on central atom: 2
lone pairs on central atom: 0
Term
Shape: Linear
Definition
bonds on central atom: 2
lone pairs on central atom: 0
Term
Shape: bent
Definition
bonds on central atom: 2
lone pairs on central atom: 1
Term
shape: bent
Definition
bonds on central atom: 2
lone pairs on central atom: 2
Term
shape: tetrahedral
Definition
bonds on central atom: 4
lone pairs on central atom: 0
Term
shape: trigonal planar
Definition
bonds on central atom: 3
lone pairs on central atom: 0
Term
shape: trigonal pyramidal
Definition
bonds on central atom: 3
lone pairs on central atom: 1
Term
non-polar covalent
Definition
0-0.4
Term
polar covalent
Definition
0.41-1.9
Term
ionic (polarity)
Definition
2.0 and up
Term
REMEMBER: Bond polarity must read:
Definition
1. Non-polar COVALENT
2. Polar COVALENT
3. (or ionic)
Term
Resonance
Definition
move a double/triple bond without changing the structure/molecule
Term
octet rule
Definition
all elements must have 8 electrons in their outer most energy level to be considered stable
Term
electron dot diagrams
Definition
designed to show valence electrons in an atom
(also used to show bonding b/w multiple atoms)
Term
VSEPR: Valence Shell Electron Pair Repulsion Theory
Definition
electron pairs repel to be as far apart from each other as possible
Term
Stronger intermolecular force...
Definition
higher boiling point. why? harder to break the force
Term
IMF: (from weakest to strongest)
Definition
London dispersion forces, dipole-dipole, hydrogen bonding, ion-ion
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