Shared Flashcard Set

Details

biomaterials
n/a
488
Mechanical Engineering
Post-Graduate
07/30/2010

Additional Mechanical Engineering Flashcards

 


 

Cards

Term
biomechanics
Definition
the study of the mechanical laws relating to the movement or structure of living organisms
Term
biomaterial
Definition
synthetic material used to replace part of a living system or to function in intimate contact with a living issue (also read various definitions given by other authors in the text)
Term
biological material
Definition
a material praduced by a living organism
Term
biocompatibility
Definition
acceptance of an artifical implant by the surrounding tissues and by the body as a whole. the biomaterial must not be degrated by the body environment, and its presence must not harm tissues, organs, or systems. if the biomaterial is designed to be degraded, then the products of degradation should not harm the tissues or organs
Term
CDRH
Definition
(Center for Devices and Radiological Health): branch of the FDA that administers medical devices-related regulations
Term
cytotoxicity
Definition
toxic to living cells
Term
ETO (ethylene oxide gas, (CH2)2O)
Definition
a flammale toxic gas used as a sterilization agent
Term
FDA (Food and Drug Administration)
Definition
government agency regulating testing, production, and marketing of food and drugs including medical devices within the United States
Term
FEM or FEA
Definition
(finite-element modeling/analysis): stress and strain analysis of a structural body using computer software. The object is divided and the distribution of stresses and strains calculated
Term
Gamma (y)-radiation
Definition
the emission of energy as short electromagnetic waves that cause ionization. The radioactive isotope 60CO is an effective source of the radition. To be effective for sterilization, about 10^6 Gy (J/Kg) is needed
Term
GMP
Definition
(Good Manufacturing Practices): medical devices are made in a clean room condition to prevent any contamination. Such practices are required by the FDA for manufacture of implants
Term
hemolysis
Definition
Lysis (disdsolution) of erythrocytes in blood with the release of hemoglobin
Term
ISO
Definition
(International Standard Organization): ISO9000 is a set of standards related to medical devices necessary to maintain an efficiant and quality system. A standard focuses on controlling organizations rather than specific requirements for final products. ASTM 13.01 focuses on specific products in the United States
Term
microsphere
Definition
a microscopic hollow sphere, especially of a protein or synthetic polymer
Term
mutagenicity
Definition
the capacity of a chemical or physical agent to cause permanent genetic alterations
Term
PMA
Definition
(Premarket Approval): some medical devices can be approved by the FDA without extensive tests required by the FDA through MDE (medical divice exemptions) 510K
Term
pyrogenic
Definition
caused or produced by combustion or the application of heat-inducing fever
Term
sensitization
Definition
making (an organism) abnormally sensitive to a foreign substance, such as a metal
Term
systemic
Definition
denoting the part of the circulatory system concerned with transportation of oxygen to and crbon dioxide from the body in general
Term
tissue engineering
Definition
generation of new tissue using living cells, optimally the patient's own cells, as building blocks, coupled with biodegradable materials as a scaffold
Term
composites
Definition
materials obtained by combining two or more materials at a scale larger than the atomic/molecular, e.g., nanoscale, microscale, or macroscale, taking advantage of salient features of each material. An example is (high-strength) fiber-reinforced epoxy resin
Term
copolymers
Definition
polymers made from two or more homopolymers; can be obtained by grafting, block, alternating, or random attachment of the other polymer segment
Term
covalent bonding
Definition
bonding of atoms or molecules by sharing valence electrons
Term
elastomers
Definition
rubbery materials. the restoring force comes from uncoiling or unkinking of coiled or kinked molecular chains. they can be highly stretched
Term
free volume
Definition
the difference in volume occupied by the crystalline state (minimum) and noncrystalline state of material for a given temperature and a pressure
Term
Glass Transition Temperature
Definition
(T^g): see T^g
Term
hydrogen bonding
Definition
a secondary bonding through dipole interactions in which a hydrogen ion is one of the dipoles
Term
ionic bonding
Definition
bonding of atoms or molecules through electrostatic interatction of positive and negative ions
Term
imperfections
Definition
defects created in a perfect (crystalline) structure by vacancy, interstitial, and substitutional atoms by the introduction of an extra plane of atoms (dislocations) or by mismatching at the crystals during solidification (grain boundries)
Term
lattice constant
Definition
the spacing ofatoms in a crystal lattice. for example, in cubic crystal systems all the lattice constants are the same, i.e., a=b=c, so that the atomic apacing is the same in each prinicipal direction
Term
metallic bonding
Definition
bonding of atoms or molecules through loosly bound valence electrons around positive metal ions
Term
minimum radius ration (r/R)
Definition
ration between the radius of a smaller atom to be fitted into the space among the larger atom's radius based on geometric consideration
Term
packing efficiency
Definition
the (atomic) volume per unit volume (or space)
Term
plasticizer
Definition
substance made of small molecules, mixed with (amorphous) polymers to make the chains slide more easily past each other, making the polymer less rigid
Term
polycrystalline
Definition
structure of a material that is an aggregate of single crystals (grains)
Term
semiconductivity
Definition
electrical conductivity of a material lies between that of a conductor and an insulator. there is an energy band gap of the order of 0.1 eV (Sn) to 6eV (C, diamond), which governs the conductivity and its dependence on temperature
Term
semicrystalline solid
Definition
solid that contains both crystalline and noncrystalline regions; for example, in polymers due to thier long-chain molecules
Term
tacticity
Definition
arrangement of asymmetrical side groups along the backbone chain of polymers; groups could be distributed at random (atactic), on one side (isotactic), or alternating (syndiotactic)
Term
unit cell
Definition
smallest repeating unit of a space lattice representing the whole crystal structure
Term
valence electrons
Definition
outermost (shell) electrons of an atom
Term
van der Walls bonding
Definition
secondary bonding arising through the fluctuating dipole-dipole interactions
Term
vinyl polymers
Definition
thermoplastic linear polymers synthesized by free radical polymerization of vinyl monomers having a common structure of CH2=CHR
Term
vulcanization
Definition
crosslinking of rubbers by sulfer
Term
adhesion
Definition
joining of two different materials
Term
adsorption
Definition
physical attachment of foreign material (usually gas) on a surface
Term
Boltzmann superposition principle
Definition
effect of a compound cause is the sum of the effects of individual causes. this is the statement of linearity for viscoelastic materials
Term
chemisorption
Definition
chemical attachment of foreign material (usually gas) on a surface
Term
cohesion
Definition
joining of identical materials
Term
contact angle
Definition
angle made when a drop of liquid spreads over a solid surface. it is governed by the balance of surface tension at various interfaces
Term
convolution
Definition
type of integral equation used in the analysis of viscoelastic materials
Term
creep
Definition
increase of strain with time in viscoelastic materials under constant stress
Term
endurance limit
Definition
stress level below which the material will not fail by cyclic fatigue loading no matter how many cycles (a practical limit is often chosen as 10^7 cycles)
Term
engineering stress
Definition
stress calculated beased on its original cross-sectional area
Term
fourier transform
Definition
integral transform equation involving sinusoids. in the context of viscoelastic materials, fourier transforms relate the time and frequency domains
Term
Griffith theory
Definition
energy approach to the fracture of a (brittle) material in which the fracture strength in tension is inversely proportional to the square root of theh crack length. the intrinsic properties of sureface energy and Young's modulus are directly related to the strength
Term
Heaviside step function
Definition
unit step function; has a value of zero for arguments less than zero, and one for arguments greater than zero. it is used in analysis of viscoelastic materials
Term
Hooke's law
Definition
stress is linearly propoertional to strain. most materials follow this law at low strains
Term
isotropic
Definition
properties of material are the same in every direction. materials such as steel and glassy polymers are usually isotropic, but composite materials and biological materials are not
Term
Kramers-Kronig relations
Definition
relationships between teh compliance of frequency in viscoelastic materials
Term
limited solubility
Definition
results when only a maximum amount of solute material can be dissolved in a solution (solid)
Term
martensite
Definition
iron carbon alloy (steel) obtained by quenching from austenite (y); has a body-centered tetragonal crystal structure. other silular crystal structures such as those occuring in shape memory alloys (e.g., nickel-titanium) are also called martensite
Term
Maxwell model
Definition
mechanical analog model consisting of a spring and a dashpot in series for describing viscoelastic material properties
Term
necking
Definition
unstable irreversible flow of material locally during tensile deformation, resulting in a neck-like shape
Term
phase
Definition
having the same (atomic or micro) structure and properties throughout
Term
relaxation modulus
Definition
stress relaxation of viscoelastic materials is teh decrease in stress that occurs under constant strain. the relaxation modulus is the ratio of stress and strain during stress relaxation
Term
solid solution
Definition
solid phase that contains more than two elements that are mixed uniformly everywhere in the phase
Term
surface tension (surface energy)
Definition
amount of free energy exhibited at the surface of a material
Term
tempering
Definition
toughening of martensite by heat treatment; the structure becomes more stable by converting to ferrite (a) and carbide microstructure
Term
thermal conductivity
Definition
amount of heat (thermal energy) passed for a given thickness, time, and cross-sectional area of a material
Term
thermal conductivity
Definition
amount of heat (thermal energy) passed for a given thickness, time, and cross-sectional area of a material
Term
toughness
Definition
amount of energy expended before its fracture or failure
Term
true stress
Definition
stress calculated based on a specimen's true cross-sectional area
Term
Voigt or Kelvin model
Definition
mechanical analog model describing materal properties by arranging a spring and a dashpot in parallel
Term
yield point
Definition
point of the stress-strain curve where transition takes place from elastic to plastic deformation, i.e., the curve deviates from initial linear portion
Term
attenuation
Definition
absorption of sound or ultrasound waves
Term
compton effect
Definition
mechanism for scattering of x-rays by free or weakly bound electrons in matter
Term
diopter
Definition
optical power of lens, or degree of ray divergence of a bundle of light rays. the power in diopters is the inverse of the focal length measured in meters
Term
piezoelectricity
Definition
electrical polarization of a material in response to mechanical stress
Term
permeability
Definition
ability of a material to pass a gaseous or ionic species, under a pressure gradient or a concentration gradient
Term
photoelectic effect
Definition
mechanism for the extinction of x-rays by the x-ray photon knocking bound electrons out of atoms
Term
pyroelectricity
Definition
electrical polarization of a material in response to temperature change
Term
streaming potential
Definition
electric potential developed when charged particles such as ions flow through a tube or porous medium such as bone; potential may be attributed to the imbalance created by washing away the eletric double layer
Term
Maxwell's equations
Definition
set of four field equations that govern electricity, magnetism, radio wave propagation, and the behavior of light
Term
refractive index
Definition
ratio of the speed of light in a vacuum to the speed of light in a material. it is a measure of the ability of a material to refract [bend] a beam of light
Term
Snell's law
Definition
governing equation for the angle of incident of refracted light rays
Term
Tensor
Definition
a mathematical expression with well-defined transformation properties under changes in coordinates. a vector is a tensor of rank one; a scalar is a tensor of rank zero. stress and strain are examples of tensors of rank two
Term
amalgam
Definition
alloy obtained by mixing silver tin alloy with mercury
Term
anode
Definition
positive electrode in an electrochemical cell
Term
cathode
Definition
negative electrode in an electrochemical cell
Term
corrosion
Definition
unwanted reaction of metal with environment. in a pourbaix diagram it is the region in which the metal ions are present at a concentration of more the 10^-6 molar
Term
crevice corrosion
Definition
form of localized corrosion in which concentration gradients around pre-existing crevices in the material drive corrosion processes
Term
Curie temperature
Definition
temperature above which a ferromagnetic material ceases to be ferromagnetic. for a ferroelectric material used in piezoelectric transducers, the Curie point is the temperature at which teh material loses it permanent electric polarization. Control of the temperature of a magnetic metal implant is possible using electromagnetic induction and knowledge of teh Curie temperature.
Term
Galvanic corrosion
Definition
dissolution of metal driven by macroscopic differences in electrochemical potential, usually as a result of dissimular metals in proximity
Term
Galvanic series
Definition
table of electrochemical potentials associated with ionization of metal atoms. these are called Nernst potentials
Term
Hyperthermia
Definition
temperature (>42 degrees C) above normal body temperature (37 degrees C). sufficiently high temperature can denature proteins, kill cells, and cause burns. prolonged heat may also produce heat shock proteins (hsp), which may resist heat better than normal protiens.
Term
immunity
Definition
resistance to corrosion by an energetic barrier. in a Pourbaix diagram it is the region in which the metal is in equilibrium with its ions at a concentration of less than 10^-6 molar
Term
Nerst potential
Definition
standard electrochemical potential measured with respect to a standard hydrogen electrode
Term
noble
Definition
type of metal with a positive standard electrochemical potential. noble metals resist corrosion by immunity.
Term
passivation
Definition
production of corrosion resistance resistance by a surface layer of reaction products
Term
passivity
Definition
resistance to corrosion by a surface layer of reaction products. in a Pourbaix diagram it is the region in which the metal is in equilibrium with its reaction products at a concentration of less than 10^-6 molar
Term
pitting
Definition
form of localized corrosion in wich pits form on the metal surface
Term
Pourbaix diagram
Definition
plot of electrical potential versus pH for a material in which the regions of corrosion , passivity, and immunity are identified
Term
Shape memory effect (SME)
Definition
Thermoelastic behavior of some alloys that can revert to their original shape when the temperature is greater than the phase transformation temperature of the alloy
Term
activation energy
Definition
og phrase transformation: thermal energy required to overcome an energy barrier. E^activation=RT In(transformation rate), where R is the gas constant and T is temperature (K)
Term
alumina
Definition
aluminum oxide (A1^2O^3), which is very hard (Mohs hardress of 9) and strong. single crystals are called sapphire or ruby depending on the color. alumina is used to fabricate hip joint socket components or dental root implants
Term
baddeleyite
Definition
mineral containing zircon
Term
biolox
Definition
trade name of alumina ceramic
Term
calcium phosphate
Definition
a family of calcium phosphate ceramics including hydroxyapatite B-whitlockite, mono-, di-, tri-, and tetra-calcium phosphate, which are used to make substitute or augment artificial bone substitutes
Term
cubic zirconia
Definition
partially stabilized zirconia in cubic structure to prevent fracture during cooling
Term
electronegativity
Definition
potential of an atom to attract electrons, especially in the context of forming a chemical bond
Term
fluorite (CaF^2) structure
Definition
AX^2 structure of ceramic, where A is a metal and X is a nonmetal
Term
glass-ceramics
Definition
a glass crystallized by heat treatment. some of those have the ability of forming chemical bonds with hard and soft tissues. Bioglass and Ceravital are well-known examples
Term
hydroxyapatite [Ca^10(PO4)^6(OH)^2]
Definition
a calcium phosphate ceramic with a calcium-to-phosphorus ratio of 5/3 and nominal composition. it has good mechanical properties and excellent biocompatibility. hydroxyapatite is the mineral constituent of bone
Term
LTI carbon
Definition
a silicon alloyed pyrolytic carbon deposited onto a substrate at low temperature with isotropic crystal morphology. highly blood compatible and used for cardiovascular implant fabrication, such as artificial heart valves
Term
maximum radius ratio
Definition
the ratio of atomic radii computed by assuming the largest aotm or ion which can be placed in a crystal's unit cell structure without deforming the structure
Term
Mohs scale
Definition
a hardness scale in which 10 (diamond) is the highest and 1 (talc) is teh softest
Term
partially stabilized zirconia
Definition
see cubis zirconia
Term
monoclinic structure
Definition
one crystal system having a=/=b=/=c, a=B=y=90 degrees
Term
phase transformation toughening process
Definition
by transforming phases under stress the material becomes stronger due to the volume expansion of the transformed phase
Term
tetragonal structure
Definition
one crystal system having a=b=/=c, a=B=y=90 degrees
Term
wear factor
Definition
similar to the wear constant; wear volume generated by given load and sliding distance
Term
weibull modules
Definition
slope of teh Weibull plot. larger values indicate predictable failure stress. ceramics are 10~20, metals are >50
Term
Weibull plot
Definition
plot of teh logarithm of probability of failure (F) [actually, 1n 1n 1/(1-F)] and test stress/strength fraction
Term
B-whitlockite (3CaO`P^2O^3)
Definition
one of the calcium phosphate compounds, similar to tricalcium phosphate, 3Ca`PO^4
Term
Yttrium oxide (Y^2O^3)
Definition
oxide used to partcially stabilize zirconia
Term
Zircon (ZrSiO^4)
Definition
crystalline mineral, a silicate of zirconium with tetragonal structure
Term
Zirconia (ZrO^2)
Definition
Zirconium oxide, which is hard and strong
Term
addition (or free radical) polymerization
Definition
polymerization in which monomers are added to the growing chains, initiated by free radical agents
Term
backbone
Definition
the main molecular chain of a polymer
Term
barium sulfate
Definition
inert ceramic mixed in the bone cement as powder to make it radio opaque to x-rays for better visualization of the implant on x-ray film
Term
bone cement
Definition
mixture of polymethylmethacrylate powder and methylmethacrylate monomer liquid to be used as a grouting material for the fixation of othopedic implants
Term
branching
Definition
chains grown from the sides of the main backbone chains
Term
condensation (step reaction) polymerization
Definition
polymerization in which two or more chemicals are reacted to form a polymer by condensing out small molecules such as water and alcohol
Term
Delrin
Definition
polyacetal made by Union Carbide
Term
filler
Definition
materials added as a powder to a rubber to improve its mechanical properties
Term
hydrogel
Definition
polymer that can absorb water 30% or more of its weight
Term
hydroquinone
Definition
chemical inhibitor added to the bone cement liquid monomer to prevent accidental polymerization during storage
Term
initiator
Definition
chemical used to initiate the addition polymerization by becoming a free radical which in turn reacts with a monomer
Term
Kevlar
Definition
aromatic polyamides trademarked by DuPont
Term
Lexan
Definition
polycarbonate trademarked by General Electric
Term
N,N-dimethyl-p-toluidine
Definition
chemical added to the powder portion of the bone cement for the acceleration of its polymerization
Term
repeating unit
Definition
basic molecular unit that can represent a polymer backbone chain. the average number of repeating unit is called the degree of polymerization
Term
relaxation time
Definition
a time constant for stress relaxation assuming the polymer exhibits an exponential behavior. real polymers exhibit a distribution of relaxation times. this term is sometimes taken to refer to a time constant for other time-dependent processes.
Term
retardation time
Definition
a time constant for creep assuming the polymer exhibits an exponential creep behavior. real polymers exhibit a distribution of retardation times
Term
side group
Definition
chemical group aattached to the main backbone chain. it is usually shorter than the branches and exists before polymerization
Term
Simplex
Definition
acrylic bone cement made by Howmedica Inc.
Term
tacticity
Definition
arrangement of side groups of a linear polymer chain that can be atactic (random), isotactis (same side), and syndiotactic (alternating side)
Term
Teflon
Definition
polytetrafluoroethylene made by DuPont
Term
Udel
Definition
polysulfone made by General Electric
Term
vulcanization
Definition
crosslinking of a (natural) rubber by adding sulfer
Term
Ziegler catalyst
Definition
organometallic compounds which have the remarkable capacity of polymerizing a wide variety of monomers to linear and stereoregular polymers
Term
nisotropic
Definition
dependent upon direction, referring to the material properites of composites
Term
closed cell
Definition
a type of cellular solid in which a cell wall isolates the adjacent pores
Term
composite
Definition
composite materials are those that contain two or more distinct constituent materials or phases, on a microscopic or macroscopic size scale
Term
cubic
Definition
a type of anisotropic symmetry in which the unit cells are cube shaped. there are three independent elastic constants
Term
hexagonal
Definition
a type of anisotropic symmetry in which the unit cells are hexagonally shaped. there are five independent elastic constants. transverse isotropy is mechanically equivalent to hexagonal although the structure may be random in the transverse direction
Term
inclusion
Definition
embedded phase of a composite
Term
isotropic
Definition
independent of direction, referring to material properties
Term
matrix
Definition
the portion of a composite in which inclusions are embedded. the matrix is usually less stiff than the inclusions
Term
neointima
Definition
new lining of a blood vessel. it is stimulated to form by fabric-type blood vessel replacements
Term
open cell
Definition
a type of cellular solid in which there is no barrier between adjacent pores
Term
orthotropic
Definition
a type of anisotropic symmetry in which the unit cells are shaped like rectangular parallelepipeds. in crystallography, this is called orthohombic. there are nine independent elastic constants.
Term
porous ingrowth
Definition
growth of tissue into the pores of an implanted porous biomaterial. such ingrowth may or may not be desirable
Term
replamineform
Definition
cellular solid made using a biological material as a mold
Term
transverse isotrophy
Definition
see hexagonal
Term
triclinic
Definition
a type of anisotrophic symmetry in which the unit cells are oblique parallelepipeds with unequal sides and angles. there are 21 independent elastic constants
Term
aspartic acid (Asp)
Definition
one of the essential amino acids
Term
canaliculi
Definition
small channels (~0.3 um in diamter) radiating from the lacunae in bone tissue
Term
cementum
Definition
calcifed tissue of mesodermal origin covering the root of a tooth
Term
chondroitin
Definition
one of the polysaccharides commonly found in the cornea of the eye
Term
chondroitin sulfate
Definition
sulfated mucopolysaccharides commonly found in cartilages, bones, cornea, tendon, lung, and skin
Term
crown
Definition
a crown-shaped structure, especially the exposed or enamel covered portion of a tooth. it is largely (97%) made of hydroxypatite mineral. an artificial replacement of the exposed surface of the upper part of a tooth is also called a crown
Term
dentin
Definition
the chief substance of the tooth, forming the body, neck, and roots, being covered by enamel on the exposed part of the tooth and by cementum on the root. is is simular in composition and properties (but not structure) to compact bone
Term
desmosine
Definition
one of the crosslinking chemicals in elastin
Term
elastin
Definition
one of the proteins in connective tissue. it is highly stable at high temperatures and in chemicals. it also has rubber-like properties; hence it is nicknamed "tissue rubber"
Term
glutamic acid (Glu)
Definition
one of the essential amino acids, much more commonly occurring in collagen than in elastin
Term
glycine (Gly)
Definition
one of the amino acids having the simplest structure
Term
haversian system
Definition
same as "osteon"
Term
Histidine (His)
Definition
one of the amino acids
Term
hyaluronic acid
Definition
one of the polysaccharides commonly found in synovial fluid, aortic walls, etc
Term
hydroxypatite
Definition
mineral component of bone and teeth. it is a type of calcium phosphate, with composition Ca^10(PO^4)^6(OH)^2
Term
hydroxyproline (Hypro)
Definition
one of the amino acids commonly occuring in collagen molecules
Term
isodesmosine
Definition
isomer of desmoine
Term
lacuna
Definition
a pore (~10x15x25 um) in Haversian bone; lacune often contain osteocytes (bone cells)
Term
Lysine(Lys)
Definition
one of the amino acids from which hydrogen bonding takes place stabilizing collagen chains
Term
lysinonorleucine
Definition
one of the crosslinking chemicals in elastin
Term
mixture rule
Definition
properties of a material made of many materials depend linearly on the amount of each material contributed
Term
osteons
Definition
large fiber-like structure (150~250 um in diamter) in compact bone. concentric layers or lamellae surround a central channelor Haversian cnal that contains a small blood vessel. each lamella contains smaller fibers. osteons, also called Haversian systems, are separated by cement lines
Term
piezoeletricity
Definition
electric polarization resulting from mechanical stress upon a material; conversely, deformation resulting from an imposed electric field
Term
polysaccharides
Definition
polymerized sugar molecules found in tissues as lubricant (synovial fluid), cement (between osteons, tooth root attachment), or complexed with proteins, such as glycoproteins or mucopolysaccharides
Term
pulp
Definition
richly vascularized and innervated connective tissue inside a tooth
Term
proline(Pro)
Definition
one of the amino acids commonly occurring in collagen molecules
Term
streaming potential
Definition
electric potential generated in the (solid) wall of a channel when charged particles are flowing and polarized takes place in the wall
Term
tropocollagen
Definition
precursor of collagen, right-handed superhelical coil structure, which, in turn, is made of three left-handed helical peptide chains
Term
valine (Val)
Definition
one of the essential amino acids more commonly occurring in elastin than in collagen
Term
Volksmann's canal
Definition
vascular channels in compact bone. they are not surrounded by concentric lamellae as are the Haversian canals
Term
Wolff's law
Definition
remodeling of bone takes place in response to mechanical stimulation, so that the new structure becomes better adapted to the load
Term
a granule
Definition
released through the vessel walls after injury, in turn releasing coagulation agents
Term
adenosine diphosphate (ADP)
Definition
a ompound consisting of an adenosine molecule bonded to three phosphate groups, present in all living tissue. the breakage of one phossphate linkage (to form adenosine diphosphate, ADP) provides energy for physiological processes such as muscular contraction
Term
aflatoxin
Definition
a naturally occurring carcinogenic material. it is formed by mold infestation of food crops such as corn or peanuts
Term
Ames test
Definition
a screening test for carcinogenic potential of a material. genetic mutations are observed in bacteria; carcinogenicity is correlated with mutagenicity
Term
biocompatibility
Definition
acceptance of an artificial implant by surrounding tissues and by the body as a whole. the implant should be compatible with tissues in terms of mechanical, chemical, surface, and pharmacological properties
Term
callus
Definition
unorganized fibrous collagenous tissue formed during the healing process of bone fracture. it is usually replaced with compact bone
Term
carcinogen
Definition
any substance that produces cancer
Term
embolus
Definition
any foreign matter, as a blood clot or air bubble, carried in the bloodstream
Term
epidemiology
Definition
the study of disease incidence in a population of humans. epidemiologic study constitutes the final test of the potential of a causative agent, such as a biomaterial, in inducing disease
Term
formed elements of blood
Definition
this refers to the solid components of blood-red and white blood cells and platelets
Term
Hageman Factor (Hfa, Factor XII)
Definition
the first of the cascading events of blood vessel wall damage control
Term
Heparin
Definition
a substance found in various body tissues, especially in the liver, that prevents the clotting of blood
Term
hydrogel
Definition
highly hydrated (over 30% of weight) polymer gel that is used to make soft contact lenses. acrylamide and poly-HEMA (hydroxyethylmethacrylate) are two common hydrogels
Term
Kinin system
Definition
the consequences of blood vessel wall damage described in a cascading manner from triggeringHfa to the dilation of blood vessels and increased vascular permeability
Term
linearity hypothesis
Definition
this is the assumption that the incidence of cancer produced by a carcinogen is linearly proportional to the dose
Term
macrophage
Definition
any of various phagocytic cells in connective tissue, lymphatic tissue, bone marrow, etc. sometimes called foreign body giant cell, and is associated with the presence of implants. becomes multinucleated if teh implant is not biocompatible
Term
neointima
Definition
sometimes called pseudointima. it is a new lining formed in the inner surface of porous arterial grafts, and it has simular nonthrombogenic properties as the intima (natural lining) of the arteries
Term
PCB
Definition
polychlorinated biphenyl, an industrial carcinogen. it is not used in biomaterials
Term
platelet
Definition
a small colorless disk-shaped cell fragment without a nucleus, found in large numbers in blood and involved in clotting. also called a thrombocyte
Term
pseudopod
Definition
a temporary protrusion of the surface of an ameboid cell for movement and feeding
Term
silica
Definition
silicon dioxide, SiO^2. it is chemically identical to the mineral quartz and is used in particle form as a filler in polymeric and rubbery materials
Term
silicon
Definition
chemical element, Si
Term
silicone
Definition
polydimethyl siloxane, a polymer that contains the element silicon. it is available in rubber and gel forms. it is used in soft tissue reconstruction in the face, as well as in breat implants
Term
supralinear model
Definition
this is the assumption of a nonlinear relation between the dose of a carcinogen and the number of cancers produced. more commonly a linear relation is assumed. see linearity hypothesis
Term
thrombin
Definition
an enzyme in blood plasma that causes the clotting of blood by converting fibrinogen to fibrin
Term
thrombus
Definition
the fibrinous clot attached at the site of thrombosis
Term
catgut
Definition
a material used for the strings of musical instruments and for surgical absorbable sutures. it is made of the dried twisted intestines of sheep or horses, but not cats
Term
chromic salt
Definition
chemical compound that is used to treat collagen to achieve crosslinking between molecular chains of collagen. such treatment increases its strength but decreases its flexibility
Term
cochlea
Definition
the spiral cavity of the inner ear containing the organ of Corti, which produces nerve impulses in response to sound vibrations
Term
cyanoacrylate
Definition
a polymer used as a tissue adhesive since it can polymerize fast in the presence of water
Term
Dacron
Definition
Polyethylene terephthalate polyester that is made into fibers. if the same polymer is made into a film, it is called Mylar
Term
FDA
Definition
Food and Drug Administration, which regulates the use of medical devices in the United States
Term
Fibrin
Definition
an insoluble protein formed from fibrinogen during the clotting of blood. it forms a fibrous mesh that impedes the flow of blood
Term
fibrinogen
Definition
a plasma protein of high molecular weight that is converted to fibrin through the action of thrombin. this material is used to make (absorbable) tissue adhesives
Term
hydrocephalus
Definition
a condition in which fluid accumulates in the brain, typically in young children, enlarging the head and sometimes causing brain damage
Term
hydrogel
Definition
a gel in which the liquid component is water (>30% by weight)
Term
keratoplasty
Definition
surgery carried out on the cornea, especially corneal transplantation
Term
LADAR
Definition
similar to lasik and uses an active radar eye tracking system, which compensates for involuntary eye movements
Term
LASIK
Definition
(laser in-situ keratomileusis): surgical correction of teh curvature of the cornea using a laser
Term
LASIK
Definition
(laser in-situ keratomileusis): surgical correction of teh curvature of the cornea using a laser
Term
ossicle
Definition
(ossicular, adj.): a small bone, especially one of those in the middle ear
Term
percutaneous device (PD)
Definition
an implant designed to transfer matter, information, etc. from the body to the outside of the body transcutaneously
Term
Plastipore
Definition
porous polyethylene
Term
polyglycolic acid (PGA)
Definition
polymer made from glycolic acid and used to make absorable sutures or other products
Term
Polylactic acid (PLA)
Definition
polymer made from lactic acid and used to make absorbable sutures or other products
Term
Proplast
Definition
a composite material made of fibrous polytetrafluoroethylene and carbon. it is usually porous and has a low modules and low strength
Term
pulpectomy
Definition
removal of dental pulp
Term
Pyrolite
Definition
Pyrolytic carbon
Term
scala media
Definition
the central duct of the cochlea in the inner ear, containing the sensory cells and separated from the scala tympani and scala vestibuli by membranes
Term
silicone
Definition
a polymer containing the element silicon. depending on molecular weight, it may be a gel or a rubber
Term
suture
Definition
material used in closing a wound with stiches
Term
Teflon
Definition
polytetrafluoroethylene
Term
Vitallium
Definition
Co-Cr alloy
Term
VISX
Definition
a commercial method using an excimer laser to treat myopia
Term
anastomosis
Definition
interconnection between two blood vessels
Term
aneurysm
Definition
abnormal dilation or bulging of a segment of a blood vessel, often involving the aorta or pulmonary artery
Term
angioplasty
Definition
surgical repair or unblocking of a blood vessel, especially a coronary artery
Term
artificial blood
Definition
use of synthetic polymers [perfloroctyl bromide (C^8F^17Br) or perfluorodichloroctane (C^8F^16C1^2)] or regenerated blood cells to substitute blood
Term
autograft
Definition
a transplanted tissue or organ transferred from one part of a body to another part of the same body
Term
cannula
Definition
a thin tube inserted into a vein or body cavity to administer medicine, drain off fluid, or insert a surgical instrument
Term
denier
Definition
a unit of weight for measuring the fineness of threads of silk, rayon, nylon, etc., equal to 1 gram per 9000 meters
Term
dialysate
Definition
the part of a mixture that passes through the membrane in dialysis.
~the solution this forms with the fluid on the other side of the membrane
~the fluid used on the other side of the membrane during dialysis to remove impurities
Term
dialysis
Definition
the separation of particles in a liquid on the basis of differences in their ability to pass through a membrane
Term
fibroblast
Definition
a cell in connective tissue that produces collagen and other fibers
Term
glomerulus
Definition
a small tuft or cluster, as ofblood vessels or nerve fibers; applied especially to the coils of blood vessels, one projecting into the expanded end or capsule of each of the uriniferous tubules of the kidney
Term
incompetence
Definition
incomplete closure of a heart valve
Term
left-ventricular assist device (LVAD)
Definition
balloon-type heart assist device connected to left ventricle of the heat
Term
neointima
Definition
new lining, intima (blood vessel lining) formed by ingrowth of tissues through pores of a vascular graft
Term
oxygenator
Definition
an apparatus by which oxygen is introduced into the blood during circulation outside the body, as during open-heart surgery
Term
pacemaker (cardiac)
Definition
a device designed to stimulate, by electrical impulses, contraction of the heart muscle at a certain rate
Term
pericardium
Definition
the membrane enclosing the heart, consisting of an outer fibrous layer and an inner double layer of serous membrane
Term
pseudointima
Definition
see neointima
Term
pyrolysis (pyrolytic, adj.)
Definition
decomposition brought about by high temperatures
Term
regurgitation
Definition
backflow of blood of a heart valve
Term
replamineform
Definition
devices or materials made by replicating natural tissues such as sea urchin tentacles. the objective is to achieve better tissue ingrowth into the pores
Term
sorbent
Definition
a substance that has the property of collecting molecules of another substance by sorption
Term
sorption
Definition
the ability of some substances to soak up or attract materials such as contaminants and hold them
Term
stent
Definition
a tubular support placed temporarily inside a blood vessel, canal, or duct to aid healing or relieve an obstruction
Term
tenacity
Definition
the normalized strength of a fiber; strength per unit size (e.g., expressed in terms of denier). tensile strength=tenacityxdensityxconstant, in appropraite units
Term
xenograft
Definition
a transplanted tissue or organ transferred from an individual of another species
Term
BMP
Definition
bone morphogenic protein. see morphogen. this is a protein used to stimulate bone growth
Term
bone inductions
Definition
interactions amoung pluripotential cells and bone morphogenetic proteins (BMPs), converting these cells to osteoblasts
Term
cancellous bone
Definition
spongy bone
Term
cortical bone
Definition
dense compact bone found in the cortex (outer layer) of a bone
Term
compression plate
Definition
bone plate designed to give compression on the fractured site of a broken bone for fast healing. a minimum amount of callus is observed; this is considered to be a better sign of healing in comparison with the conventional plate.
Term
electrical stimulation
Definition
tissues can be stimulated by applying a small amount of electrical energy in either alternating or direct current at low electrical potential so as not to hydrolyze the water medium. dosage-response relationships are not fully established yet for various tissues
Term
18-8sMo
Definition
one of the stainless steels made of 18w/o Cr, 8 w/o Ni and a small (2-4 w/o) amount of Mo for saltwater corrosion resistance
Term
fracture plate
Definition
plate used to fix broken bones by open (surgical) reduction. screws are used to fix it to the bone
Term
Helmholtz coil
Definition
a wire-wound coil to generate (pulsed) electromagnetic field to induce electric current in the tissues to stimulate their growth
Term
Hoffmann external fixator
Definition
a mechanical device used to reattach broken long bones using percutaneously inserted pins to compress the bones together for faster healing
Term
intramedullary device
Definition
a rod-like device inserted into the intramedullary marrow cavity to promote healing of long bone (spiral, non-comminutive) fractures
Term
Kirschner wire
Definition
metal surgical wires with diameters less than 3/32 inches (2.38 mm)
Term
lane plate
Definition
first fracture plate used extensively for repair of broken long bones designed by Dr. Lane in teh first years of the twentieth century
Term
Lordosis
Definition
abnormally increased concavity in the curvature of the lumbar spine
Term
morphogens (BMPs)
Definition
cartilage-derived morphogenetic proteins-1 and -2 (CDMP-1 and -2) to regenerate form for skeletal insufficiencies caused by oncologic resection, trauma, disease, or developmental deficiency
Term
Osteopenia
Definition
condition of insufficient bone mass or density
Term
Osteoporosis
Definition
condition of abnormally high porosity of bone. Osteoporosis is associated with aging and with disuse atrophy due to inactivity. it can also be caused locally by shieling of stress by an implant or deficiency of calcium or vitamin D
Term
Schneider nail
Definition
one of the intramedullary rods used to fix broken long bones
Term
scoliosis
Definition
lateral curvature of vertebral column; it is always abnormal
Term
Steinmann pin
Definition
metal pins with diameters greater than 3/32 inches (2.38 mm)
Term
Stellite
Definition
Co-Cr alloy
Term
Strain-generated electric potential
Definition
electric potential generated due to strains during deformation of the bone. they may be related to the remodeling processes of bone
Term
stress-shield effect
Definition
prolonged reduction of stress on a bone may result in porotic bone (osteoporosis), which may weaken it. the process can be reversed if the natural state of stress can be restored to its original state
Term
Vitallium
Definition
originally the name was given to 19-9 stainless steel, but it was changed to designate a Co-Cr alloy
Term
acetabulum
Definition
the socket portion of the hip joint
Term
apatite
Definition
mineral phase of bone usually found as hydroxyapatite, Ca^10(PO^4)^6(OH)^2
Term
arthroplasty
Definition
plastic repair of a joint
Term
Branemark dental implant
Definition
popular dental implant supposed to be integrated with bone of the root portion. it is made of Ti alloys such as Ti6A14V
Term
C-FLEX TPE
Definition
polysiloxane modified styrene-ethylene/butylene-styrene block copolymer of thermoplastic elastomer
Term
c.p.-Ti
Definition
commercially pure Ti having excellent corrosion resistance and biocompatibility
Term
CoCr alloy
Definition
co-based alloys commonly used in orthopedic implants. some are made castable (CoCrMo) or hot-forgable (CoNiCrMo). these alloys are stiff and strong and offer good corrosion resistance
Term
Dacron
Definition
polyethylene terephlhalate polyester that is made into a fibrous form
Term
edentulous
Definition
without teeth
Term
endosseous
Definition
in the bone, referring to dental implants fixed to the jawbone
Term
finite-element analysis or model (FEA or FEM)
Definition
study of a structure or structural member by subdividing it into small elements (mesh). a computer is used to analyze stresses and strains. the stresses/strains are then expressed in a graphic form
Term
glass-ceramics
Definition
a ceramic made by controlled nucleation and crystallization for fine grains with capacity for tissue bonding by selected surface dissolution. Bioglass is an example
Term
HDPE
Definition
high-density polythylene, having a high m.w. and crystallinity, resulting in high-density and moderate m.w. (1/2 million amu). before ultrahigh-m.w. polyethylene (UHMWPE) was avaliable. HDPE polymers were used extensively in the early 1980s
Term
HDPE
Definition
high-density polythylene, having a high m.w. and crystallinity, resulting in high-density and moderate m.w. (1/2 million amu). before ultrahigh-m.w. polyethylene (UHMWPE) was avaliable. HDPE polymers were used extensively in the early 1980s
Term
HDPE
Definition
high-density polythylene, having a high m.w. and crystallinity, resulting in high-density and moderate m.w. (1/2 million amu). before ultrahigh-m.w. polyethylene (UHMWPE) was avaliable. HDPE polymers were used extensively in the early 1980s
Term
Hexsyn
Definition
hexene-bsed polyolefin rubber
Term
hyaluronic acid
Definition
one of the polysccharides commonly found in synovial fluid, the aortic wall, etc.
Term
hydrogel
Definition
highly hydrated (over 30% by weight) polymer gel used to make soft contact lenses, such as acrylamide and poly-HEMA (hyroxyethylmethacrylate)
Term
Krebs cycle
Definition
the sequence of reactions by which most living cells generate energy during the process of aerobic respiration. it takes place in the mitochondria, consuming oxygen, producing carbon dioxide and water as waste products, and converting ADP to energy-rich ATP
Term
Mersilene
Definition
type of woven polyethlene
Term
Nitinol
Definition
Ni-Ti shape memory alloy originally experimented with at the Naval Ordinance Labatory; hence the name
Term
osseo(osteo)integration
Definition
direct apposition of bone on the implant surface without intervening collagenous membrane formation. it is largely used in dentisty, not in orthopedics. Branemark dental implant represents such a implant fixation technique in bone
Term
PGA
Definition
a biodegradable polymer made from glycolic acid
Term
Phusiline
Definition
a polylactic acid
Term
PLA
Definition
a biodegradable polymer made form lactic acid
Term
polymethylmethacylate (PMMA)
Definition
an amorphous, hard plate used to make bone cement and hard contact lens
Term
Proplast
Definition
a composite material made of carbon and polytetrafluoroethylene. it has moderate porosity and strength
Term
shape memory alloy (SMA)
Definition
alloys having "recovery of its shape" by thermomechanical transformation of its crystalline structure (see Nitinol)
Term
Silastic
Definition
polydimethyl siloxane silicone elastomer
Term
stainless steel
Definition
iron- (Fe) based alloys made to resist corrosion by adding Cr, Ni, and small amounts of Mo. by lowering C (.8 to .3%), the corrosion resistance of the stainless steel can be enhanced (316 to 316L)
Term
subchondral
Definition
bone lying under the cartilage of a joint
Term
thixotropic gel
Definition
a gel that, when disturbed or shaken, will become fluid, and if left undisturbed will set into a gel; it is a reversible transformation that can occur under application of isothermal shearing stresses followed by rest. ketchup is a typical example
Term
Ti6A14V
Definition
one of the most widely used Ti alloys having a relatively low modules for a metal (110 GPa) with high strength and corrosion resistance. it has about half the specific gravity of Co-based alloys and stainless steels. 6 w/o aluminium and 4 w/o vanadium are alloyed for preserving phases (B for V, a for A1), density, and process consideration
Term
Vitrident
Definition
a defunct dental root implant made of glassy carbon
Term
UHMWPE
Definition
ultrahigh-molecular-weight polyethylene, having m.w. = 2~4 million amu, semicrystalline, thermoplastic, linear polymer used in the acetabular cup of hips and tibia plateaus of joint fabrication
Term
Wollastonite
Definition
SiO^2-CaO ceramic used to make glass-ceramics with apaitite
Term
allograft
Definition
transplant between different individuals of teh same species
Term
anastomosis
Definition
joining two blood vessels or other tubular structures in the body
Term
antigen
Definition
a forgeign protein that elicits an aimmune system response
Term
autograft
Definition
transplant within one individual, from one part of teh body to another
Term
biocompatibility
Definition
compatibility of nonliving implant materials with the body
Term
brain death
Definition
death of the brain including the brain stem resulting in unreceptivity and unresponsivity, absence of spontaneous respiration or movement, absence of relexes, and a flat EEG
Term
cyclosporin
Definition
an immunosuppressive drug
Term
EEG
Definition
electroencephalogram, wich is a plot of teh electrical activity of the brain as measured via electrodes on the scalp
Term
histocompatibility
Definition
compatibility of transplant tissue with teh recipient's body in relation to immune response
Term
iliac
Definition
referring to the ilium, the large flat bone of teh pelvis
Term
Island of Langerhans
Definition
a cluster of endocrine cells found in the pancreas; they secrete insulin.
Term
isograft
Definition
transplant between genetically identical individuals, i.e., identical twins
Term
graft
Definition
a transplant
Term
homograft, allograft
Definition
transplant between different individuals of the same species
Term
heterograft, xenograft
Definition
transplant between members of different species
Term
heterotopic
Definition
transplanted in a location different from teh anatomically correct one
Term
hypothermia
Definition
abnormally low body temperature. it can cause an unresponsive condition that can mimic brain death, so transplants are not taken from hypothermic patients
Term
Kaposi's sarcoma
Definition
a type of cancer, once rare, now largely associated with immune system deficiencies such as those produced in AIDS or by immunosuppressive drugs used in transplant procedures. this disease produces bluish skin lesions
Term
Keratoplasty
Definition
replacement of the cornea
Term
orthotopic
Definition
transplanted in the anatomically correct location
Term
Parkinson's disease
Definition
a neurological disorder characterized by tremor and paralysis. attempts have been made to cure it by transplantation of brain or adrenal cells into the brain
Term
porcine
Definition
from a pig
Term
replantation
Definition
surgical reattachment of a severed body part
Term
T cells
Definition
immunologically competent cells derived from the thymus
Term
transplantation
Definition
transfer of a tissue or organ from one body part to another, or from one location in a body to another
Term
tubule
Definition
a small tube
Term
aldehyde
Definition
any one group of organic chemical compounds having the radical CHO, derived from the primary alcohols by oxidation of methanol (CH^3CHO)
Term
autograft
Definition
a transplant from a part of one's body to another part of the body
Term
autologous
Definition
derived from a person's own tissue
Term
bioabsorption
Definition
being absorbed by blood or tissues of the decomposed polymer by products in vivo
Term
biodegradation
Definition
being decomposed by bacterial or enzymatic action in vivo
Term
chemical degradation
Definition
erosin of polymers by breakage main chains or crosslinks
Term
chitin
Definition
a horny substance forming the hard outer covering of lobsters, crabs, beetles, crickets, and some fungi; closely related to cellulose
Term
chitosan
Definition
a derivative of chitin by N-deacetylation
Term
collagen
Definition
protein substance in the fibers of connective tissues, bone, and cartilage of vertebrates. boiling with water converts collagen to gelatin
Term
collagen-glycosaminoglycan copolymer
Definition
two natural polymers made into a copolymer, one being protein (collagen) and another polysaccharide, would give good mechanical, chemical, and biologicalproperties for such applications as scaffold material
Term
Dexon
Definition
suture made of copolymer of PGA and PLA (Davis and Geck, Danbury, CT)
Term
fibrin
Definition
an insoluble protein formed from fibrinogen during the clotting of blood. it forms a fibrous mesh that impedes the flow of blood
Term
gelatin
Definition
denatured collagen obtained by boiling bones and cartilage
Term
glutaraldehyde (C^5H^8O^2)
Definition
chemical made from cyclohexene in atmospheric reaction, used to preserve tissues and serilization
Term
immunogenicity
Definition
the property of causing immunity (antigenicity) to a disease
Term
PGA
Definition
poly(hydroxybutylate), a natural polymer usually copolymerized with PHV to make biodegradable polymer scaffolds
Term
PHB
Definition
poly(hydroxybutylate), a natural polymer usually copolymerized with PHV to make biodegradable scaffolds
Term
PHV
Definition
poly(hydroxyvaleric acid), a natural polymer usually copolymerized with PHB to make biodegradable polymer scaffolds
Term
physical degradation
Definition
erosin of polymers at the surface or bulk
Term
PLA
Definition
poly(lactic acid), one of the synthetic polymers, poly(a-hydroxyesters) used to make biodegradable scaffolds
Term
polyanhydride
Definition
step-reaction polymerized polymer from HOOC(CH^2)^8COOH resulting in HO[-CO(CH^2)^XCOO-]^YH+H^2O
Term
poly(e-caprolactone) (PCL)
Definition
a biodegradable, biocompatible, thermoplastic homopolymer used to coat, fabricate scaffold, films, etc. can be copolymerized to modify its properties
Term
poly(ortho esters) (POE)
Definition
a polymer produced from 3,9-bis(ethylidene 2,4,8,10-tetraoxaspirol [5,5]undecane) (DETOSU) condensed with di-alcohols. this generation of POEs released nonacidic byproducts and eliminated teh autocatalytic process. combined with certain additives, POes were found to degrade by surface erosion, making DETOSU-based POEs well suited for controlled drug delivery
Term
racemic
Definition
consisting of an optically inactive, equimolar mixture of the dextrorotatory and levorotatory forms of certain substances
Term
resorption
Definition
a material, typically a polymer, being absorbed by the body in vivo
Term
sodium alginate (C^6H^7NaO^6)^n
Definition
sodium salt of alginic acid, with 10~600 k m.w. dissolves slowly in water, forming a viscous solution; used as stabilizer, thickener, gelling agent, and emulsifier
Term
stem cells
Definition
undifferentiated cells capable of proliferation and of self-renewal and of differentiation into at least one type of specialized cells
Term
tissue engineering
Definition
an intersdisciplinary field involving engineering and life sciences for the development of biological substitutes containing living cells, with the aim to restore, maintain, or improve cells, tissues, and organs in the body
Term
Vicryl
Definition
suture made of copolymer of PGA and PLA (Ethicon, Somerville, NJ)
Term
alloy
Definition
a metallic material that is obtained by chemical combinations of different elements, typicall alloys ahve much better mechanical properties than pure metals
Term
Ceramics
Definition
a group of crystalline inorganic materials characterized by good strength, especially in compression and high melting temperatures, many have good electrical and thermal insulation behavior
Term
composites
Definition
a group of material formed from mixtures of metals, ceramics, or polymers in such a manner that unusual combinations of properties are obtained.
Term
composition
Definition
the chemical makeup of a material
Term
crystal structure
Definition
the arrangment of atoms in a crystalline material
Term
crystalline material
Definition
a material comprised of one or many crystals, in each crystal atoms or ions show a long range periodic arrangement
Term
glass
Definition
an amorphous material derived from teh molten state, typically, but not always bsed on silica
Term
glass-ceramics
Definition
a special class of materials obtained by forming a glass and then heat treating it to form small crystals.
Term
grain boundaries
Definition
regions between grains of a polycrystalline material
Term
grains
Definition
crystals in a polycrystalline material
Term
mechanical properties
Definition
properties of a material, such as struegth, that describe how well a material withstands applied forces, a materials response to an applied force, microstructure sensitve
Term
physical properties
Definition
describe characteristics such as color, elasticity, electrical or thermal conductivity, magnetism, etc. a material's response to an applied fied, not microstructure sensitive
Term
polycrystalline material
Definition
a material comprised of many crystals (as opposed to a material comprised of just one crystal)
Term
polymers
Definition
a group of materials normally obtained by joining organic molecules into gian molecular chains or networks, characterized by low strength, low melting temperatures and poor electrical conductivity.
Term
thermoplastics
Definition
a special group of polymers in which molecular chains are entangled, but not interconnected, they can easily be melted and formed into useful shapes, normally they have a chinline structure (eg polyethylene)
Term
thermosets
Definition
a spcial group of polymers that decompose ratehr than melt upon heating, they are normally quite brittle due to a relatively rigid 3-D network structure (eg-polyurethane)
Term
elastomers
Definition
polymers that have a higly coiled structure that provides them with the ability to exhibit extreme elastic deformation.
Term
amorphous material
Definition
a material that does not have a long range order of atoms (only short range order)
Term
anion
Definition
a negatively charged ion produced when an atom, usually of a nonmetal, accepts one or more electrons.
Term
atomic structure
Definition
all atoms and their arrangments that constitute teh building blocks of matter
Term
binding energy
Definition
The energy required to separate two atoms from their equilibrium spacing to an infinite distance apart, the strength of the bond between two atoms.
Term
cation
Definition
a positively charged ion produced when an atom usually a metal gives up its valence electrons
Term
coefficient of thermal expansion (CTE)
Definition
The amount by which a material changes its dimesnions when teh temperature dhanges, a material with a low cte tends to retain its dimesnions when the temperature is changed.
Term
covalent bond
Definition
the bond formed between tewo atoms wehn the atoms share their valence electrons, a relatively strong primary bond.
Term
crystalline materials
Definition
materials in which atoms are arranged in a periodic fashion exhibiting a long-range order
Term
ductility
Definition
the ability of materials to be stretched or bent without breaking
Term
electronegativity
Definition
the trelative tendancy of an atom to accept an electron and become an anion, strongly electronegative atoms readily accept electrons
Term
interatomic spacing
Definition
the equilibrium spacing between teh centers of two atoms.
Term
ionic bond
Definition
the bond formed between two different atom species when one atom (the cation) donates its valence electrons to teh second atom (the anion), an electrostatic attraction binds the two ions together (relatively strong primary bond)
Term
macrostructure
Definition
structures of a material at the macroscopic level (~>1000-10,000 nm), features include things such as porosity, coatings, internal and external microcracks, etc
Term
metallic bond
Definition
the electrostatic attraction between teh valence electrons and the positively charged ionic cores
Term
microstructure
Definition
structure of amaterial at a length scale of ~10 - 1000 nm, includes features such as grain size, grain orientation, defects, etc
Term
modulus of elasticity
Definition
the slope of the stress strain curve in the elastic region(E), also known as Young's modulus
Term
polarized molecules
Definition
molecules that have developed a dipole moment by virtue of an internal or external electric field
Term
primary bonds
Definition
strong bonds between adjacent atoms resulting form the transfer or sharing of outer orbital electrons
Term
valence
Definition
the number of electrons in an atom that participate in bonding or chemical reactions, usually teh number of electrons in teh outer s and p energy levels
Term
van der Waals bond
Definition
secondary bond developed between atoms and molecules as a result of interactions between dipoles that are induced or permanent
Term
allotropy
Definition
the characterisitic of an element being able to exist in more than one crystal structure depending on temperature and pressure
Term
amorphous material
Definition
materials including glass that have no long-range order, or crystal structure
Term
anisotropic
Definition
having different properties in different directions
Term
Bravais lattices
Definition
fourteen possible lattices that can be created using lattice points (show location of atoms)
Term
close-packed directions
Definition
directions in a crystal along which atoms are in contact
Term
coordination number
Definition
the number of nearest neighbors to an atom in its atomic arrangement 9speaks to how efficiently packed a unit cell is)
Term
crystal structure
Definition
the arrangement of atoms in a material into a regular repeatable lattic
Term
crystal systems
Definition
the generic size and shape of a unit cell, include cubic, tetragonal, orthrombic, hexagonal, monoclinic, rhombohedral and triclinic
Term
crystalline materials
Definition
materials that have long range order (composed of many small grains or crystals)
Term
defect
Definition
a microstructural reature representing a disruption in teh periodic arrangment of atoms/ions in a crystalline material.
Term
directions of form
Definition
crystallographic directions that all have teh same cahracteristics although their sense is different, generic directions, denoted by < >
Term
glass-ceramics
Definition
a family of materials typically derived from molten inorganic glasses and processed into crystalline materials with very fine grain size and improved mechanical proeprties
Term
glasses
Definition
solid, non-crystalline materials that have only short range atomic order (amorphous)
Term
grain
Definition
small crystal in a polycrystalline material
Term
grain boundaries
Definition
regions between grains of a polycrystalline material
Term
interstitial sites
Definition
locations between teh normal atoms or ions in a crystal into which anothre usually different atom or ion is placed, typically teh sie of the interstitial location is smaller than the atom or ion that is to be introduced
Term
isotropic
Definition
having the same properties in all directions
Term
lattice
Definition
a collection of points that divide space into smaller equally sized segments
Term
lattice parameters
Definition
the lengths of sides of teh unit cell and teh angles between those sides, describe the size and shape of the unit cell
Term
linear density
Definition
the number of lattice points per unit length along a direction
Term
miller indices
Definition
shorthand notation to describe crystallographic planes and directions
Term
packing factor
Definition
the fraction of a direction or plane that is actually covered by atoms or ions, speaks to how efficiently packed a unit cell is in a direction or on a plane
Term
planar density
Definition
the number of atoms per unit area whose centers lie on the plane
Term
planes of form
Definition
crystallographic planes taht all have the same cahracteristics even though theri orientations are different; denoted by { }
Term
polycrystalline material
Definition
material composed of many grains
Term
polymorphism
Definition
compounds exhibiting more than one type of crystal structure 9similar to allotropic)
Term
repeat distance
Definition
the distance from one lattice point to the adjacent lattice point along a direction
Term
short range order
Definition
the regular and predictable arrangement of atoms over shrot distances usually one or two atom spacings only
Term
stacking sequence
Definition
the sequence in which close-packed planes are stacked, if teh stacking sequence is ABABABAB a HCP structure is produced, if a stacking sequence of ABCABCABC then an FCC structure is produced
Term
unit cell
Definition
a subdividion of teh lattice that still retains teh overall cahracteristics of the entire lattice
Term
Burgers vector
Definition
the direction and distance that a dislocation moves in each step, aka slip vector
Term
critical resolved shear stress
Definition
the shear stress required to cause a dislocation to move and cause slip
Term
cross-slip
Definition
a change in the slip system of a dislocation
Term
dislocation
Definition
a line imperfection in a crystalline material, movement of dislocations helps explain how a metallic material deforms, interference with the movement of these helpse explain how metallic materials are strengthened
Term
edge dislocation
Definition
dislocation that is made up of an extra "half plane" of atoms, burgers vector is perpendicular to dislocation line
Term
elastic deformation
Definition
deformation that is fully recovered when the stress causing it is removed, results from the bonds stretching
Term
Frenkel defect
Definition
a pair of pinte defects produced when an ion moves to create an interstitial site leaving behind a vacancy
Term
grain boundary
Definition
a surface defect representing the boudnary between two grains, the crystal has a different oriention on either side of the grain
Term
interstitial defect
Definition
point defect produced when an atom is placed into teh crystal at a site that is not normally a lattice point
Term
line defects
Definition
defects such as dislocations in which atoms or ions are missing in a row (1-D)
Term
mixed dislocation
Definition
a dislocation that contains partly edge components and partly screw components
Term
Peierls-Nabarro Stress
Definition
The shear stress, which depends on the Burgers vector and teh interplanar spacing , required to cause a dislocation to move
Term
plastic deformation
Definition
permanent deformation of a material
Term
point defects
Definition
imperfections such as vacancies that are located typically at one or a few sites in a crystal.
Term
Schmid's law
Definition
The relationship between shear stress , teh applied stress, and teh orientation of the slip system
Term
Schottky defect
Definition
A point defect iinionically bonded materials, a stoichiometric number of cation and anion vacancies
Term
screw dislocation
Definition
a dislocation produced by skewining a crystal so that one atomic plane produces a spiral ramp about dislocations
Term
slip
Definition
deformation of a metallic material by movement of dislocations through the crystal
Term
slip direction
Definition
direction in the crystal in which the dislocation moves
Term
slip plane
Definition
the plane swept out by the dislocation line during slip, normally the slip plane is a close packed plane if one exists in the crystal structure
Term
slip system
Definition
combination of a slip direction and slip plane
Term
small angle grain boundary
Definition
surface or planar defect made up of an array of dislocations cuasing a small misorientation of teh crystal across teh surface of the imperfection
Term
stacking fault
Definition
a surface defect in an fcc materal caused by the improper stacking sequence of close-packed planes
Term
substitutional defect
Definition
a point defect produced wehn an atom is removed from a reular lattice point and replaced with a different atom usually having a different size
Term
surface defect
Definition
imperfections such as grain boundaries that form a 2D plane within the crystal
Term
tilt boundary
Definition
small angle graoun boundary composed of an array of edge dislocations
Term
twin boundary
Definition
a surface defect across which there is a mirror image misorientation of teh crystal structure
Term
twist boundary
Definition
small angel grain boudnary made up of an array of screw dislocations
Term
vacancy
Definition
point defect where an atom is missing from its regular cyrstallographic site
Supporting users have an ad free experience!