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Biochem Block Two
Carbohydrate Chemistry
9
Biochemistry
Graduate
09/27/2012

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Term
Reducing Sugars
Definition

Saccharides containing a free aldehyde

group

-can be detected by their ability to reduce Cu2+ or Fe3+ (such as inBenedict’s solution) to yield colored products. 

Term
Glycogen
Definition

A branched polysaccharide of glucose having both

α(1-4) and α(1-6) linkages.
-A branched structure allows for the compact storage of large amounts of glucose as an energy reserve; however, the mixed linkages mean that two

different enzymes are required to release the glucose for metabolism

Term
α-amylase
Definition

An endosaccharidase, attacking internal α(1-4) glycosidic

bonds that are not at branches.
-Products are maltose, maltotriose, and α-limit dextrin.

Term
Amylose
Definition
a linear polymer having α(1-4) linkages
-plants store glucose as starch, of which amylose is one form.   
Term
Amylopectin
Definition
a branched polymer that includes α(1-4) and α(1-6) linkages.
-plants store glucose as starch, of which this is one form.   
Term
Cellulose
Definition

Similar to amylose

in being a linear polymer of glucose residues, but they are linked by β(1-4) glycosidic bonds. This makes it rigid, due to H-bonds that form between the monosaccharide units, and indigestible

Term
Maltose
Definition
Derives from the hydrolysis of starch and is a reducing disaccharide composed of two glucose units in α(1-4) linkage
Term
Lactose
Definition
A disaccharide composed of galactose and glucose linked by an α(1-4) glycosidic bond.
-Lactose is a reducing sugar since the anomeric carbon of the glucose residue is free to exist in equilibrium with the open form while the galactosyl residue is locked into a ring.
Term
Sucrose
Definition

A disaccharide of glucose and fructose linked by an

α(1-2) glycosidic bond.
-both anomeric carbons contribute to this linkage, accounting for the observation that sucrose is a non-reducing sugar.

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