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What are the two states of energy? |
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energy of an object in motion |
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The study of energy and its transformations |
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When discussing thermodynamics, the object under study is called |
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What are the three kinds of systems? |
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isolated system closed system open system |
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matter and energy cannot be exchanged |
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energy can get in and out, matter can’t |
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matter and energy can get in and out |
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All living systems must be what system? |
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All living systems must be an open system Why? |
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Nutrient has to come in, waste has to come out, exchange materials, or it will die |
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First law of thermodynamics states: |
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Energy can transformed from one form to another, or transferred from one location to another, but can’t be created or destroyed |
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Second law of thermodynamics states: |
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The total disorder (entropy) of a system and its surroundings always increases |
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Define spontaneous reaction. |
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Chemical or physical reaction that will occur without an input of energy |
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the portion of a system’s energy that is available to do work |
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What is the equation used to calculate change in free energy? |
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is the change in enthalpy (potential energy in its system) |
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is the absolute temp in degrees Kelvin (K) |
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Exergonic reactions will do what to energy? |
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Endergonic reactions will do what to energy? |
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Reactions will be spontaneous if |
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Definition
the products have less potential energy than the reactants |
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Change in Entropy Reactions will be spontaneous when |
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the products are less ordered than the reactants |
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For a reaction to be spontaneous, change in free energy must be |
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Definition
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Definition
energy is released by the breakdown of complex molecules to simpler compounds (spontaneous) |
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energy is used to build complicated molecules from simpler ones |
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Most biological reactions have a |
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Therefore must have ? to provide the needed energy to make the reactions go forward. |
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How does ATP provide energy? |
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Definition
Removal of one or two phosphate groups |
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How much energy is released during the hydrolysis of ATP? |
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Definition
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During energy coupling, what happens to the terminal phosphate group when ATP is being hydrolyzed? |
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Definition
Transferred to a reactant molecule involved in an endergonic reaction |
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addition of the phosphate group to the reactant is called |
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Definition
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Even when a reaction is spontaneous, the reaction will not start unless a small amount of ? is added. |
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The most common biological catalysts to make a reaction go faster are |
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How do enzymes increase the rate of reactions? |
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Definition
Lowering the activating energy of the reaction |
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By looking at the name of an enzyme, how can one determine that it is an enzyme? |
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Definition
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The reactant the enzyme acts on is called |
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Definition
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small pocket or groove in the enzyme molecule |
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What goes into the active site? |
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Definition
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A nonprtein group that binds to the enzyme |
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metallic ions, zinc, ir, copper, magnesium, manganese |
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What are coenzymes? Examples of coenzymes? |
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Definition
Small organic molecule, vitamins |
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What are the different factors that can affect enzyme activity? |
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Definition
1. concentration of substrate 2. inhibitors 3. regulation of enzymes 4. pH 5. temperature |
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What are the two different kinds of inhibitors? |
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Definition
competitive inhibition non competitive inhibititor |
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non competitive inhibititor |
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bind at location other than the active site |
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What are the two ways to regulate enzyme activity? |
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Definition
Allosteric Feedback inhibition |
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Definition
enzyme activity is controlled by the regulatory molecule to the allosteric site, a location on the enzyme outside the active site |
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Definition
excess accumulation of a product often inhibits the enzymatic reaction producing it |
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