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Ketone/Aldehyde + Alcohol = |
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Cyclic Hemiacetal Formation |
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double bond to oxygen is broken..H+ catalyst is added to the new single bond oxygen..New bond is formed and H of alcohol is removed |
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OH is added above the aldehyde/ketone carbon..remaining portion is added below |
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2 alcohols + aldehyde/ketone = |
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alcohol is added from the water molecule to the carbon with the most double bonds (markovinoviks rule) |
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2 Hydrogens are removed to create a double bond - can be from any two things (ie. two from 1 carbon or 1 from oxygen 1 from carbon) |
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Oxaidation of alcohol catalyst |
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Oxidation of Thiols creates.. |
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Oxidation of Thiol formation |
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I2 is used to combine two thiols |
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reduction of aldehydes and ketones formation |
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carbon oxygen double bond is broken to create an alcohol |
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based on how many carbons are attached to the carbon of origin |
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Acidic Amino Acids @ pH 7 |
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Basic Amino Acids @ pH 14 |
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Acidic Amino Acids @ pH 14 |
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Acidic Amino Acids @ pH 0 |
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1 degree alcohol is oxidized to create |
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an aldehyde is oxidized to create |
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2 degree alcohol is oxidized to create |
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3 degree alcohol is oxidized to create |
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B Keto acids are decarcoxylated (heat) to form |
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a keto acids are decarboxylated (pyruvate/decarboylase) to form |
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add AL to the ending (ie. methanal) |
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add ONE to the ending (ie. propanone) |
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fischer projections are based on the.. |
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one or more alcohols are replaced |
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regular glucose is deoxified |
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1 or more Hydrogens are replaced with NH2's |
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regular to alcohol sugars |
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aldehyde end is reduced to form an alcohol end |
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Haworth Projection is a cyclic sugar molecule focused on the 5th carbon (1 carbon = first H-OH) |
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OH's on the right are placed |
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OH's on the left are placed |
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bond between 2 monosaccharides |
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carbon 1 in a cyclic monosaccharide |
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2 D glucopyranose molecules with a glycosidic bond at 1-4 |
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4 types of amino acid sidechains |
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non polar, polar acidic, polar basic, polar neutral |
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nonpolar amino acid sidechains |
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polar acidic amino acid sidechain |
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polar basic amino acid sidechain |
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hydrocarbon and amino acids |
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polar neutral amino acid sidechains |
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polar groups capable of a hydrogen bond (alcohol, phenols, amides) |
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carboxylic acids react with an amine to create |
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ammonium salts are heated to create |
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