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Atomic Structure
Unit 1
37
Chemistry
12th Grade
09/17/2012

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Cards

Term
In 1913, who improved Rutherford's model of the atom?
Definition
Niel Bohr
Term
Who's J.J Thompson?
Definition
  • In the late 1890's he used the cathode ray gun to identify the first subatomic particle - the electron
  • "Chocolate chip cookie" or "plum pudding" model - negatively charged electrons are distributed throughout a uniform positive charge 
Term
Who is Robert Millikan?
Definition
In 1909 he experimentally determined the charge and mass of an electron using an oil drop.
Term
Ernest Rutherford
Definition
  • In 1911 he performed the "gold foil experiment" with radioactive particles to prove the existence of the nucleus
  • He established that the nucleus was small, dense, and positively charged. Assumed that electrons were outside the nucleus. 
Term
James Chadwick
Definition
In 1932 he determined that the nucleus also contained neutrons.
Term
Niels Bohr
Definition
  • He proposed a "new" atomic structure, placing electrons in specific paths around the nucleus, using the solar system as a model
  • This model only works for simple atoms 
Term
Quantum Mechanical Model
Definition
  • Electrons do not move about the atom's nucleus in a definite path like planets around the Sun
  • A probable location of an electron can be determined based on its energy
  • Energy levels are divided into 5 sublevels called orbitals
  • Electrons move randomly in electron clouds called orbitals
Term
Democritus
Definition
  • Greek Philosopher
  • 1st person to propose the idea that matter was not infinitely divisible
  • He believed that matter was made up of tiny individual particles called atomos, from which the English word atom was derived.
  • He believed that atomos could not be created, destroyed or further divided.
  • Matter is composed of empty space through which atomos move
  • Atomos are soild, homogeneous, indestructible and indivisible
  • Different kinds of atomos have different sizes and shapes
  • The differing properties of matter are due to the size, shape and movement of atomos
  • Apparent changes in matter result from changes in groupings of atomos and not from changes in the atomos themselves. 
  • His ideas were not based on science. He did not have the benefit of being able to conduct controlled experiments to test if his ideas were valid.
Term
Aristotle
Definition
  • Influential Greek philosopher
  • Rejected the concept of the atom
  • Rejected the atomic "theory" because it did not agree with his own ideas on nature. One of his major critiscims concerned the idea that atoms moved through empty space. He did not believe that the "nothingness" of empty space could exist 
Term
Alchemists
Definition
  • They searched for the Philosopher's Stone, which had the ability to transform base materials like copper or lead, into valuable substances, like gold.
  • They also searched for the Elixir of Life, which when drunk by a particular person, would grant him immortality. 
Term
John Dalton
Definition
  • All matter is composed of extremely small particles called atoms
  • All atoms of a given element are identical, having the same mass, size and chemical properties. Atoms of a specific element are different from those of any other element
  • Atoms cannot be created, divided into smaller particles or destroyed
  • Different atoms combine to form compounds
  • In a chemical reaction, atoms are separated, combined or rearranged 
Term
Light behaves like
Definition
Both a particle and a wave
Term
Who created the full form of Quantum Mechanics?
Definition
Werner Heisenberg and Edwin Schroginger
Term

Who wrote an equation that treated the electron as a wave?

And afterwards created wavefunctions called "orbitals"

Definition
Edwin Schroginger
Term
What is the uncertainty principle that Edwin Schroginger created?
Definition
At any one time, it is impossible to calculate both the momentum and the location of an electron in an atom; it is only possible to calculate the probability of finding an electron within a given space.
Term
The energy needed to remove electrons from an atom is called
Definition
Ionization energy
Term
Light behaves like
Definition
Both a particle and a wave
Term
Who has the lowest frequency?
Definition
Radios
Term
Who has the highest frequency?
Definition
Gamma-rays
Term
This type of emission maps the dust between stars
Definition
Infrared
Term

True and False

Gas in space emits radio waves

Definition
True
Term
This type of emission can come form radioactive materials.
Definition
Gamma-rays
Term

True or False

The photons that make up radio waves travel at the same speed as teh photons that make up visible light.

Definition
True
Term
The electromagnetic spectrum can be expressed in terms of what?
Definition
Energy, wavelength, or frequency
Term

True or False

Low energy photons act like waves. High energy photons act like particles.

Definition
True
Term
Which of the following aspects of electromagnetic radiation best explains why electromagnetic radiation is both useful and harmful to humans?
Definition
Electromagnetic radiation is energy and can interact with matter.
Term
As the frequency of the radiation increases so does the energy in the type of radiation. Which form of radiation has the highest frequency and therefore most energy?
Definition
Gamma ray waves
Term
Put in order from long Wavelength to short wavelength
Definition
Radio, Microwaves, Infrared, Visible, Ultraviolet, X-rays, Gamma-rays
Term
Put in order High Frequency to Low Frequency
Definition
Gamma-rays, X-rays, Ultraviolet, visible, Infrared, Microwaves, Radio
Term
Put in order Low Energy to High Energy
Definition
Radio, Microwaves, Infrared, Visible, Ultraviolet, X-rays, Gamma-rays
Term
All of the electrons in an atom reside in the lowest energy orbitals possible, the most stable arrangement is called
Definition
Ground-state electron configuration
Term
The Aufbau Principle
Definition
  • Each electron occupies the lowest energy orbital
    • Electrons are Lazy
  • All orbits related to an energy level are of equal energy
    • The three 2p orbitals are the same energy level
    •  
Term
Hund's Rule
Definition
  • Single electrons with the same spin must occupy each equal-energy orbital before additional electrons with opposite spins can occupy the same orbitals
    • Electrons are unfriendly
       

 

Term
Pauli Exclusion Principle
Definition
  • A maximum of two electrons may occupy a single orbital, but if the electrons have opposite spins
    • Spin - Electrons have an associated "spin," either one way or the other, like a top
    • These spins are called "spin up" and "spin down" 
Term
Atomic Radius
Definition

Is simply the distance from the nucleus to the outermost electron.

As half the distance betwen the nuclei of two bonded atoms of the smae element(covalent bond)

Term
What's the trend in Atomic Radius?
Definition
  • As a group decrease, the outermost electron is in a higher energy level which is further from the nucleus so the radius increases.
  • Across a period, electrons are being added to the same energy level, but the number of protons in the nucleus increases, this attracts the energy level closer to the nucleus and the atomic radius decreases across a period. 
Term
What's the trend of Ionic Radius?
Definition
  • An element increases in size down a group as the number of electron shells increase.
  • Across a period, the ionic radius decreases from Group 1 to Group 3 
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