Term
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Definition
- A chemical reaction which evolves heat.
- A chemical reaction which absorbs heat.
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Term
In a thermochemical equation, what happens to ΔH when the moles of reactants double? |
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Definition
Enthalpy is derctly proportional to mass. Therefore, when the moles double so does ΔH. |
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Term
Reverse Reaction
What is the reverse reaction of
C + O2 → CO2? |
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Definition
Products becoming reactants
C + O2 → CO2
(Forward reaction)
CO2 → C + O2
(Reverse reaction) |
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Term
How are ΔH for a forward and ΔH for a reverse reaction related? |
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Definition
ΔH forward is equal in magnitude but opposite in sign to ΔH reverse? |
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Term
- Hess's Law
- Molar heat of formation
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Definition
- ΔH for a reaction is the same regardless of the path travelled from reactants to products.
- The molar heat of formation of a compound is equal to ΔH when 1mole of compound is formed from its elements at 1 atm. and 25º C.
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Term
Write the general equation to calculate ΔH for a chemical reaction. |
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Definition
ΔH =
Σ(ΔHf—Products) — Σ(ΔHf—Reactants)
ΔH =
Heat of formation of reactants or products |
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Term
- what is the heat of formation of an element in its most stable state?
- Calorimeter
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Definition
- Zero
- A device of heat liberated or absorbed in a chemical reaction or physical change.
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Term
Specific Heat
Give value for liquid water in calories and joules |
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Definition
The amount of heat required to raise one gram of substance 1º C.
Water: 1 calorie/gram- ºC or 4.18 joules/gram- ºC
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Term
How many calories to raise 100 grams of water from 20° to 30° celsius? |
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Definition
ΔH = mCpΔT
Heat = (1 Cal./g- °C)
(10°C)(100g)
Heat = 1000 Cal. |
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Term
Write an equation to calculate energy change when a fixed mass of substance changes temperature. |
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Definition
ΔH = mCpΔT
ΔT = temperature change
Cp = specific heat
ΔH = heat absorbed or given off |
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Term
- Enthalpy
- Enthalpy Change
(State the equation) |
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Definition
- The heat content of a system.
- The difference in heat content between the products and the reactants.
ΔH = ΣHProducts-ΣHreactants |
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Term
Exothermic Reaction:
ΔH is ____1_____.
(positive or negative)
Enthalpy is ___2____.
(increased or decreased) |
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Definition
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Term
Endothermic Reacton:
ΔH is ____1____.
(Positive or Negative)
Enthalpy is ____2_____.
(incraesed or decreased)
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Definition
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Term
List in the order of increasing enthalpy:
Solid, Gas, liquid |
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Definition
- Solid (least enthalpy)
- Liquid
- Gas (most enthalpy)
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Term
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Definition
A balanced chemical equatin which includes the enthalpy change.
H2(g)+1/2O2(g) → H2O(1)
ΔH= -285kJ |
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