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AP BIO chapters 3
chemistry of life
120
Biology
12th Grade
10/22/2008

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Term
What does the polarity of water molecules result in?
Definition
Hydrogen bonding
Term
What are the bonds called that hold atoms in water molecules?
Definition
Polar Convalent
Term
What type of charge does the oxygen region have? The hydrogen region?
Definition
Oxygen-negative
Hydrogen-Positive
Term
What types of bonds are two water molecules held together by?
Definition
Hydrogen Bonding
Term
How many bonds can one water molecule form?
Definition
4
Term
Cohesion is the attraction of...
Definition
Like molecules
Term
Is hydrogen bonding strong or weak?
Definition
Weak
Term
How long do hydrogen bonds last?
Definition
A few trillionths of a second
Term
How often do water molecules form bonds with new partners?
Definition
Constantly
Term
What are two examples of cohesion?
Definition
1. Transport of water in plants against gravity
2. Transpiration through leaves- tugs water up veings of stalk then to the leaves- great tensile strength
Term
How long did life spend evolving in water?
Definition
Over three billion years
Term
What percentage of cells are made up of water?
Definition
70-95%
Term
Which is more electronegative, oxygen or hyrogen?
Definition
Oxygen- which is why the electron spends more time closer to the oxygen atom
Term
What is the shape of a water molecule?
Definition
Wide V
Term
What type of molecule is the water molecule and what does that mean?
Definition
It is a polar molecule- the opposite ends of the molecule have opposite charges
Term
What type of attractions exist between water molecules?
Definition
Electrical
Term
When water is in its liquid form, how strong are its hydrogen bonds?
Definition
1/20th as strong as convalent bonds
Term
What is adhesion?
Definition
The attraction of unlike molecules
Term
Give two examples of adhesion
Definition
1. Water attraction to soil particles
2. water attraction to the sides of xylem wallas (counteracts the pull of gravity and prevents the walls from breaking)
Term
Is it the tendency of a liquid to maximize or minimize surface tension?
Definition
Minimize
Term
Surface tension is the result of what force?
Definition
Strong cohesion
Term
Surface tension is the result of water molecules being more attracted to _______ vs. _______
Definition
each other than to air molecules
Term
Surface tension acts like an ___________ ________.
Definition
Elastic skin
Term
Surface tension confines moelcules in an area that has the least what?
Definition
Surface area
Term
What shape do molecules resist because of surface tension?
Definition
Water droplets
Term
Water striding above the rim glass is an example of what?
Definition
Surface tension
Term
What allows bugs to walk on water?
Definition
Surface tension
Term
If water striders weighed more or had pointed legs what would happen to its ability to walk on water?
Definition
It would be unable tod o so because it would rupture the surface film (caused by surface tension)
Term
Compared to other liquids, does water have a greater or lesser surface tension?
Definition
Greater
Term
What allows people to skip rocks on a pond?
Definition
Surface tension
Term
How does water moderate the temperature on earth?
Definition
It absorbs heat from hot air, and releases stored heat into cooler air.
Term
What is heat?
Definition
The measure of the total kinetic energy due to the molecular motion of a body of matter.
Term
What is temperature?
Definition
The measure of the intensity of heat due to the average kinetic energy of molecules
Term
What is heat measured in? Temperature?
Definition
Heat- Calories Temperature-celsius
Term
Explain how heat and temperature are related using a swimmer and a pooling a the example.
Definition
Swimmer has a higher temperature, but the pool has more heat due to its great volume
Term
What is a calorie?
Definition
The amount of heat it takes to raise 1g of water 1c and vice versa.
Term
Why is water effective as a heat bank?
Definition
It can absorb or release a large amount of heat with only a slight change in its own temperature.
Term
When two objects are brough together, how does heat pass from one object to the other?
Definition
Heat passes from the warmer object to the cooler object until they are the same temp.
Term
What is specic heat?
Definition
The amount of heat that must be absorbed or released in order for 1g of a substance to change its temp by 1c
Term
How does water's specific heat compared to alochol's specific heat?
Definition
Water= 1 calorie
Alcohol= .6 calories
Term
When heat is absorbed what does it do to hydrogen bonds?
Definition
Breaks them
Term
When heat is released what does it do to hydrogen bonds?
Definition
Forms them.
Term
What are two reasons why it is important that water has a high specific heat?
Definition
1. Creates a stable ocean temperature that is favorable for marine life
2. Allows life to resist changes in their temperatures b/c bodies have a high composition of water
Term
Why can you burn your fingers on an iron pot handle, when the water in the pot is still luke warm?
Definition
Iron has a specific heat that is 10 times less than water. It only takes .1 Calorie to raise the temp. of iron.
Term
Why does a calorie of heat cause a relatively small change in the temperature of water?
Definition
Much of the heat energy is used to disrupt the hydrogen bonds, before the water molecules can begin moving faster.
Term
Why do coastal areas generally have a milder climate than inland regions?
Definition
High specific heat- it can absrob and store a huge amount of heat in the day time while only raising its temp a few degrees. The gradually cooling water can then warm the air.
Term
What happens to molecules that are moving fast enough to overcome their attraction to other molecules?
Definition
They can enter the air as a gas.
Term
What is heat of vaporization?
Definition
the quantity of heat a liquid must absorb for 1g to be converted into a gas
Term
Does water have a high or low heat of vaporization and why?
Definition
High- Hydrogen bonds must be broken before molecules can leave the liquid
Term
What is waters heat of vaporization and how does this compare with alcohol?
Definition
580 Calories of heat- nearly double the heat of vaporization of alcohol
Term
How does heat of vaporization moderate earth's climate? (4 steps)
Definition
1.Solar heat is absorbed by the seas 2.evaporation
3.moist tropical air circulates poleward
4.releases heat as it condensese to form rain.
Term
What happens to the surface of a liquid as the liquid evaporates?
Definition
It cools down
Term
What does evaporative cooling have to do with lakes and ponds?
Definition
It contributes to their stability
Term
What does evaporative cooling prevent in organisms?
Definition
It prevents them from overheating (sweat- animals, water from leaves of plants)
Term
Why does evaporative cooling occur?
Definition
The hottest molecules, those with the greatest kinetic energy, are the most likely to leave as a gas.
Term
Why does high humidity increse discomfort?
Definition
The high concentration of water vapor in the air inhibs evaporation of sweat from the body.
Term
Is water less dense as a solid or liquid? Why?
Definition
Solid because water expands as it solidifies due to hydrogen bonding.
Term
At temperatures above 4C how does water behave?
Definition
Like other liquids- expanding as it warms and contracting as it cools
Term
When does water begin to freeze?
Definition
OC- when its molecules are no longer moving fast enough to break the hydrogen bonds
Term
When water freezes what does it become locked into? How many partners are each molecule bonded to?
Definition
A crystalline lattice- 4
Term
How much lense dence is ice compared to liquid water at 4C? Why?
Definition
10% less desne because the hydrogen bonds are far enough apart
Term
What happens as ice begin to absorb heat, causing the temperature to rise? (3 steps)
Definition
1.hydrogen bonds are broken
2.crystalline collapses
3.Molecules are free to slip closer together
Term
When is water the densest?
Definition
4C- then begins to expand as the molecules move faster
Term
Why is the ability of ice to float so important?
Definition
If it sank all bodies of water would become frozen solid and during the summer only the upper inches would thaw
Term
What does floating ice due to the liquid below it?
Definition
it insulates the liquid water and prvents it from cooling.
Term
What is a solution?
Definition
Homogenous mixture of two or more substances
Term
What is a solute?
Definition
substance that is dissolved
Term
What is a solvent?
Definition
Dissolving agent
Term
What is an aqeuous solution?
Definition
One in which water is the solvent
Term
Why is water close to but not a universal solvent?
Definition
It if it were in could not be stored in any container, including our cells.
Term
Explain what NaCl is and how it is dissovled in water (4 steps and result).
Definition
NaCl= ionic compound
1. Na and Cl ions aer exposed to solvent
2. Ions and water molecules have a mutual affinity
-O attracted to Na cation
-H attracted to Cl anion
3. Water molecules surround ions and shield one from another
4. This forms a hydration shell
Result- homogenous mixture
Term
What are sugars?
Definition
Polar and water soluable
Term
Are proteins water soluable?
Definition
If ionic/polar regions are on the surface
Term
What are some examples of fluids that many polar molecules are dissolved in? (3)
Definition
Blood, plant sap, cytoplasm of cells
Term
Can hydrophilic be used to describe a substance even if it is not dissolved?
Definition
Yes- the molecules may be too large for example
Term
What is an example of a hydrophilic substance that absorbs water without disolving and how does it do so?
Definition
cotton- cellulos has regions of partial positive and negative charges- water adheres to the cellulose fibers
Term
What is present in the Xylem walls that makes them hydrophilic?
Definition
Cellulose
Term
What type of substance repel water?
Definition
non ionic and non polar substances
Term
Why is vegetable oil hydrophobic?
Definition
The bonds between C and H in vegetable oil are non polar bonds that do not share electrons equally
Term
Are cell membranes hydrophobic or hydrophilic? Why?
Definition
Hydrophobic- molecules related to oil are major ingredients of cell memebranes
Term
What is a mole?
Definition
The number of grams of a substance that equals its molecular weight in daltons and contains avagadro's number
Term
What is avagadros number?
Definition
The number of molecules in a mole 6.02 x 10^23
Term
What is molarity?
Definition
The number of moles of solute per liter or solution
Term
Why is measuring in moles convient for scientists working in the laboratory?
Definition
It allows them to combine substances in fixed ratios of molecules
Term
What happens when a water molecule dissociates?
Definition
The H atom shared by two water molecules shifts from one molecule to another, leaving its electron behind
Term
What is actually transferred when water dissociates?
Definition
A hydrogen Ion (since the hydrogen leaves its electron behind) which is a single proton with a charge of +1
Term
What happens to the molecule left behind when water dissociates?
Definition
It becomes an OH ion with a charge of -1 since it lost a proton
Term
What does the molecule that dissociates from water bind to and what does it form?
Definition
to the other water molecule making an hydronium ion (H30)+
Term
What is the equation for the dissociation of water
Definition
H20 (double arrows) H+ + OH-
Term
What is pure water?
Definition
Water in which h+ and OH- are equal (onlye one molecule in every 554 million is dissociated)
Term
How do the concentration of water molecules compared to teh contration of H and OH ions compare when an equilibrium is achieved with the dissociation of water?
Definition
The concentration of water molecules greatly exceeds the number of ions
Term
What do changes in the concentration of H and OH do to cells?
Definition
They affects cells proteins
Term
What does an acid do?
Definition
Increase the H+ concentration in a solution
Term
What does a base do?
Definition
decrease the H+ concentration in a solution
Term
How do bases do "what they do" (3 ways)
Definition
1. some directly accept H+ (ex: NH3 ammonia vs. NH4 ammonium)
2.dissociate to form OH ions which comebine with H in solution to form water
3. more OH then H
2.
Term
What is a weak acid/ weak base?
Definition
acids and bases that do not dissociate completely; the reactions are reversible
Term
How do you find the PH of a number?
Definition
-log [H+]
Term
A number that is above 7 on the PH scale is a ____________. A number that is below 7 on the PH scale is a _________.
Definition
Acid- More H
Base- More OH
Term
What does each PH unit represent?
Definition
A tenfold difference in H and OH concentration (ex: a PH of 6 vs a PH of 8 =10 x 10)
Term
What range are most biological fluids found in?
Definition
6-8
Term
What is the product in any solution of the H and OH concentrations?
Definition
10^-14
Term
What happens to PH has H increases?
Definition
It declines
Term
What is the internal PH of most living cells?
Definition
7
Term
What do buffers do?
Definition
Allow biolgoical fluids to resist changes in PH when acids/bases are introduced
Term
What is the PH of human blood and when is it deadly?
Definition
PH= 7.4. If it drops to 7 or raises to 7.8 it is deadly
Term
What do buffers do when H ions are in excess?
Definition
It accepts them
Term
What do buffers do when H ions in a solution are depleted?
Definition
It donates them
Term
What acts as a buffer to blood?
Definition
Carbonic acid (H2CO3)
Term
What does carbonic acid dissociate to yield?
Definition
Bicarbonate ion (HCO3-) and Hydrogen ion
Term
What happens if the PH of blood drops?
Definition
Bicarbonate ion acts as a base and removes H+
Term
What happens if the PH of blood raises?
Definition
Carbonic acid dissociates replenishing H
Term
What is a weak acid and base pair called?
Definition
A buffer
Term
Acid precipitation is precipitation with a PH lower than...
Definition
5.6
Term
What two compounds cause acid precipitation?
Definition
Sulfur oxides and nitrogen oxides
Term
What thing causes acid precipiation?
Definition
1. burning of fossil fuels- electrical power plants are the biggest users
Term
What do tall smokestacks do?
Definition
reduce local pollution but wind carries it to other places
Term
When is the effects of acid rain most pronounced? Why?
Definition
the spring (when the snow melts) b/c all acid accumulates in bodies of water at the same time
Term
When does the acid surge effect fish?
Definition
It effects them when they are reproducing
Term
What does acid precipitation do to the soil?
Definition
Affects solubility of soil minerals
Term
What does acid rain do to Ca, Mg, and Al? And what as this caused?
Definition
It washes away Ca and Mg.
It increases the solubility of Al which is a toxic.
It has casues a decline in European forests and some in North America.
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