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3369B - chapter 2
Engineering materials with a focus on cement and asphalt
28
Civil Engineering
Undergraduate 3
02/03/2013

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Term
Supplementary Cementing Materials (SCMs) contributes to properties of hardened concrete through:
Definition
-Hydraulic Activity
-Pozzolanic Activity
-Both
Term
Pozzolans
Definition
Siliceous or alumino-siliceous, finely divided, reacts with hydation products
ei. Silica Fume, Fly Ash
Term
Natural Pozzolans
Definition
Natural Material
May be calcined (rice husks) or not (volcanic Ash)
Term
(cement) C3S,C2S,C3A,C4AF + Water --> hydration products (CSH, CH) + Heat

What are CSH and CH?
Definition
CSH - calcium silicate hydrat, is the binder or glue

CH - calcium hydroxide, no contribution to strength
Term
What will adding silica fume do?
Definition
increase the reaction with S(silicate) with CH to make CSH.
Term
3 effects of SCMs
Definition
1) Enhancement of mechanical properties and durability
2) refinement of porosity
3) densification of aggregate-cement paste interface
Term
1) Enhancement of mechanical properties and durability or Pozzolanic reaction
Definition
increase the reaction with S(silicate) with CH to make CSH.
Term
2) Refinement of Porosity or physical filler effect
Definition
small particles get in between cement grains to reduce size of voids and permeability (note that # of voids may increase)
Term
3) Densification of Aggregate cement paste transition zone
Definition
Transition zone between cement paste and aggregate is the weakest and most permeable location. Fine pozzolans play role in transition zone through physical and chemical effects
Term
5 characteristics of silica fume
Definition
smoke-by-product
High silica content
particle size less than 1 micron
Highly reactive pozzolan
surface area 13,000 to 30,000 m^2/kg
Term
Pozzolanic activity measurement
Definition
Strength activity index = (A/B) *100
A= compressive strength of blended cement cubes
B= compressive strength of pure cement cubes
Term
silica fume effects on voids and permeability
Definition
voids increase, void size decrease, permeability decrease
Also Cohesive and less prone to segregation
Term
Silica fume effects on chloride diffusion
Definition
reduces chloride diffusion and corrosion, increases durability
Term
In order to get increase in durability of adding silica fume you must...
Definition
prevent drying shrinkage cracks to achieve gains in durability of silica fume concrete
Term
3 facts about fly ash
Definition
-by product of coal burning
-made of spherical particles
-less effective filler than silica fume
Term
2 types of fly ash
Definition
Class F , Class C
Term
Class F Fly ash (four characteristics)
Definition
Low calcium oxide
Calcination of bituminous coal
pozzolanic properties
increases sulfate ressistance
Term
Class C fly ash (four characteristics)
Definition
High calcium oxide
calcination of subbituminous coal of lignite
pozzolanic + cementous properties
does not effect sulfate ressistance
Term
Finer fly ash has...
Definition
higher pozzolanic activity
Term
Fly ash setting time
Definition
moderate or severely extended depending on properties of fly ash, temp and mixture properties
Finer fly ash - shorter setting time
Higher Cao content - Shorter setting time
Term
Fly ash on workability and strength
Definition
Workability - increases
Strength gain - slower in early phases but final strength is usually higher
Term
Fly ash required to prevent expansion damage due to ..... may be greater than amount necessary for ...
Definition
Alkali-aggregate reaction
strength and workability
Term
How does heat of hydration cause cracks?
Definition
On massive concrete elements heat gradient between middle of element and outside can cause cracks
Term
How does fly ash prevent heat of hydration?
Definition
Fly ash reduces core temperature, reduces heat differential
Term
5 characteristics of Granulated Blast Furnace Slag (GBFS)
Definition
Smoother particles
density is lower than concrete, replacement by weight leads to higher paste volume and better workability
at low temperature setting time is increase (slower hydration)
used in low heat of hydration cements
Term
GBFS strength developments
Definition
starts slow but is faster and better at later stages
Term
3 characteristics of GBFS in Cement
Definition
improves fire resistance
lower permeability
expansion due to alkali aggregate reaction lowered as slag increases
Term
2 types of natural pozzolans
Definition
1)Raw volcanic ash
2) calcined (rice husk)
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