Term
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Definition
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Term
Saccharides =
sugar ends in - |
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Definition
a sugar that is a smal CHO.
-ose |
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Term
| Example of naming a 5 and 6 C sugar |
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Definition
pentose=ribose
Hexose- glucose, fructose |
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Term
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Definition
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Term
| Glyceraldehyde is -- where dihydroxyacetone is not-- |
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Definition
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Term
| Fischer projection of glyceraldehyde |
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Definition
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Term
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Definition
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Term
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Definition
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Term
Glucose-
# of C and OH
Aldehyde or Ketone?
Numbering starts on- |
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Definition
Aldehyde
6C
5OH
starts with C on Aldehyde |
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Term
Fructose
aldehyde or ketone?
#C
how numbering starts? |
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Definition
Ketone
6C
Numbering starts with ketone where the aldehyde would be |
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Term
Determining D or L
ex: glucose/fructose |
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Definition
| Go to the furthest C from the aldehyde and compare it to glyceraldehyde to find if D or L. This is the chiral carbon so in glucose or fructose it would be C5 not C6 bc 6 isnt chiral |
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Term
| Aldehydes and Ketones react with-- to make hemiacetals or hemiketals which can react with -- to make an acetal which creats a -- at -- which produces -- |
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Definition
alcohol
another alcohol
New chiral center at carbonyl carbon
produces glycosidic bond |
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Term
| When is the chiral carbon introduced? |
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Definition
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Term
| NucleoSides are the dehydration prodct of -- |
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Definition
pyrimidine or purine with the sugar (deoxy or ribose)
Do not have phosphate! |
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Term
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Definition
| adding a phosphate group to the nucleoside |
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Term
| Phosphate groups bind at #C? |
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Definition
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Term
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Definition
Phosporyl= -PO3H -2
Phosphate= HO-PO3H +2 |
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Term
| Hydrolysis of ATP in terms of which phosphate is removed. Why? |
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Definition
| Gamma is furthers P from the sugar. Beta is 2nd. These are highly exorgenic and is coupled to endergonic rxns in the cell. They are anhydride bonds. Alpha is the closest P. It is an ester bond which yeilds less energy than gamma /beta P. |
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Term
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Definition
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Term
| What is a high energy bond? |
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Definition
| a bond with high group transfer potential. Pi would rather be transfered to a different "acceptor" molecule. It would rather be somewhere else |
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