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303 exam3 lec. 1
n/a
25
Biochemistry
Undergraduate 3
11/05/2013

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Term
General oxidation-reduction eqn:
Definition
AH2 + B → A + BH2
Term
Of this rxn: AH2 + B → A + BH2
what is the reducing agent and what does it become?
Definition
AH2 is a reducing agent and becomes oxidized
Term
Of this rxn: AH2 + B → A + BH2
What is the Oxidizing agent and what does it become?
Definition
B is an oxidizing agent and becomes reduced
Term
Oxidizing agents -- electrons
Definition
Oxidizing agents accept electrons (2 vowels):
Term
Reducing agents -- electrons
Definition
Reducing agents donate electrons (2 consonants):
Term
redox rxns must have # of substrates and # of products
Definition
Must be two substrates and 2 products.
Term
classic oxidizing agent=
Definition
O2
Term
redox rxns often releasee-
Definition
a lot of energy
Term
Oxidation of carbon
-- is completely reduced vs -- which is most oxidized
Definition
Methane is completely reduced.
CO2 is most oxidized.
Term
Pyridine nucleotides
Definition
NAD+, NADH, NADP+, NADPH
Term
NAD = NAD+ =
Definition
Nicotinamide adenine dinucleotide
Term
NAD:
What makes it a nucleotide?
What accepts electrons?
How many electrons does the oxidizing agent accept?
The reduced form=
Definition
Phosphate group on 5’ C makes it a nucleotide. Oxidizing agent accepts 2 e-. The pyramine group accepts the e-. The reduced form is NADH and will be a 2e- donor.
Term
NADP 2' C
Definition
the 2' OH is esterified with phosphate
Term
Vitamins=
Definition
organic compounds required in small amounts in the diet
Term
Water soluble vitamins=
Definition
B2(riboflavin), niacin (B3), Pantothenic acid, C= ascorbic acid
Term
Vitamins vs Minerals=
Definition
minerals are inorganic (C,P,Mg)
Term
Vit. C is a good -- agent
Definition
reducing agent
Term
Niacin/B3 deficiency=
Definition
pellagra
Term
Vit C deficiency-
Definition
scurvy or scorbutis
Term
Where is pellagra?
Definition
where corn not treated with lime bc corn deficient in both niacin and tryptophan (precursor for niacin)
Term
4 D symptoms of pellagra?
Definition
diarrhea
• dermatitis- big blotches
• dementia-
• death
Term
Riboflavin B2 improtant for -- nucleotides
Definition
Flavin nucleotides (FAD, FADH2, FMN, FMNH2)
Term
fat soluble vitamins-
Definition
ADEK
Term
vit. A goof for-
Definition
vision, embryonic development, cell growth, differentiation, apoptosis
Term
vit D good for-
E-
K-
Definition
D: bone formation (not a "real" vitamin)
• E: reducing agent
• K: blood clotting
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