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Chem Test 3
SPAGHET!
25
Chemistry
Undergraduate 1
04/20/2010

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Term
2 E Groups
2 Bonding Groups
0 Lone Pairs
Definition
E Geometry: Linear

Molecular Geometry: Linear

Bond Angle: 180
Term
3 E Groups
2 Bonding Groups
1 Lone Pair
Definition
E Geometry: Trigonal Planar

Molecular Geometry: Bent

Bond Angle: 117.5
Term
3 E Groups
3 Bonding Groups
0 Lone Pairs
Definition
E Geometry: Trigonal Planar

Molecular Geometry: Trigonal Planar

Bond Angle: 120
Term
4 E Groups
4 Bonding Groups
0 Lone Pairs
Definition
E Geometry: Tetrahedral

Molecular Geometry: Tetrahedral

Bond Angle: 109.5
Term
4 E Groups
3 Bonding Groups
1 Lone Pair
Definition
E Geometry: Tetrahedral

Molecular Geometry: Trigonal Pyramidal

Bond Angle: 107
Term
4 E Groups
2 Bonding Groups
2 Lone Pairs
Definition
E Geometry: Tetrahedral

Molecular Geometry: Bent

Bond Angle: 104.5
Term
5 E Groups
5 Bonding Groups
0 Lone Pairs
Definition
E Geometry: Trigonal Bipyramid

Molecular Geometry: Trigonal Bipyramid

Bond Angle: 120 Equatorial, 90 Axial
Term
5 E Groups
4 Bonding Groups
1 Lone Pair
Definition
E Geometry: Trigonal Bipyramid

Molecular Geometry: Seesaw

Bond Angle < 90
Term
5 E Groups
3 Bonding Groups
2 Lone Pairs
Definition
E Geometry: Trigonal Bipyramid

Molecular Geometry: T-shaped

Bond Angle: < 90
Term
5 E Groups
2 Bonding Groups
3 Lone Pairs
Definition
E Geometry: Trigonal Bipyramid

Molecular Geometry: Linear

Bond Angle: 180
Term
6 E Groups
6 Bonding Groups
0 Lone Pairs
Definition
E Geometry: Octahedral

Molecular Geometry: Octahedral

Bond Angle: 90
Term
6 E Groups
5 Bonding Groups
1 Lone Pair
Definition
E Geometry: Octahedral

Molecular Geometry: Square Pyramidal

Bond Angle < 90
Term
6 E Groups
4 Bonding Groups
2 Lone Pairs
Definition
E Geometry: Octahedral

Molecular Geometry: Square Planar

Bond Angle: 90
Term
Lattice Energy
Definition
Energy Made from an Ionic Bond, the higher the differences in charge the higher the energy. AlN is higher energy than NaCl.
Term
Paramagnetic
Definition
Has unpaired electrons.
Term
Diamagnetic
Definition
Has paired electrons.
Term
Formula for the Energy of a photon
Definition
Ephoton = hv

hv = hc/lambda(wavelength)

h= planks constant
v= frequency
c= speed of light
Term
What are the three quantum numbers and what does each one determine?
Definition
N: The energy level determined by period
L: N - 1 If n = 2 then L = 1 if n = 1 then L = 0
MsubL: Representative of the orbitals of L
L0 = S orbital = 0
L1 = P orbital = -1, 0, +1
L2 = D orbital = -2, -1, 0, +1, +2
L3 = F orbital = -3, -2, -1, 0, + 1, + 2, + 3
Term
What is a node?
Definition
A node is a section inbetween orbitals where electrons are not found because electrons jump between energy levels.
S Orbitals have spherical nodes
P orbitals have planes for nodes
Term
What is the formula for Z effective?
Definition
Zeff = Z - S

Where z = # of protons
and s = # of NON-valence electrons
Term
A fully filled valence shell is referred to as a...
Definition
Octet

Except for H and He which are duets
Term
Ms
Definition
Electron Spin -1/2 if diagram is pointing up and +1/2 if pointing down.
Term
A molecule with a permanent dipole moment is called a...
Definition
Polar Molecule.
Term
The atoms that can form less than an octet (exceptions).
Definition
Be, Al, Ga
Term
The best (major contributors) have...
Definition
the smallest or no formal charges on their individual atoms, and negative charges on the most electronegative atoms
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